File name: Pandora199s1_Fukuoka_20220921_L2Fit_fout2c22d20220804p1-8.txt File generation date: 20260324T130509.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Hisahiro Takashima Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 199 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora199_OF_v3d20210122.txt Instrument calibration file used: Pandora199s1_CF_v22d20220804.txt Level 1 file used: Pandora199s1_Fukuoka_20220921_L1_smca1c22d20220804p1-8.txt.bz2 Full location name: Fukuoka University Short location name: Fukuoka Country of location: Japan Location latitude [deg]: 33.5491 Location longitude [deg]: 130.3660 Location altitude [m]: 55 Local noon date: 20220921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 2ndVP in Sept22 based on Session2 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1157 305.2567 305.3977 305.5387 305.6798 305.8208 305.9617 306.1027 306.2437 306.3846 306.5256 306.6665 306.8075 306.9484 307.0893 307.2302 307.3710 307.5119 307.6528 307.7936 307.9345 308.0753 308.2161 308.3569 308.4977 308.6385 308.7793 308.9200 309.0608 309.2015 309.3422 309.4830 309.6237 309.7644 309.9051 310.0457 310.1864 310.3270 310.4677 310.6083 310.7489 310.8895 311.0301 311.1707 311.3113 311.4519 311.5924 311.7330 311.8735 312.0140 312.1545 312.2950 312.4355 312.5760 312.7165 312.8569 312.9974 313.1378 313.2782 313.4186 313.5590 313.6994 313.8398 313.9802 314.1205 314.2609 314.4012 314.5415 314.6818 314.8221 314.9624 315.1027 315.2430 315.3832 315.5235 315.6637 315.8039 315.9441 316.0843 316.2245 316.3647 316.5049 316.6450 316.7852 316.9253 317.0654 317.2055 317.3456 317.4857 317.6258 317.7659 317.9059 318.0460 318.1860 318.3260 318.4660 318.6060 318.7460 318.8860 319.0259 319.1659 319.3058 319.4458 319.5857 319.7256 319.8655 320.0054 320.1452 320.2851 320.4250 320.5648 320.7046 320.8444 320.9842 321.1240 321.2638 321.4036 321.5434 321.6831 321.8228 321.9626 322.1023 322.2420 322.3817 322.5214 322.6610 322.8007 322.9403 323.0800 323.2196 323.3592 323.4988 323.6384 323.7780 323.9175 324.0571 324.1966 324.3362 324.4757 324.6152 324.7547 324.8942 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220920T223305.7Z 8298.939649 229 1 48.72 2 72.71 100.87 16.65 118.07 0.00 1 0.00 1 0 17 1.123e-01 1.040e-02 7.460e-02 6.206e-03 3.972602e-01 3.336463e-03 4.692997e-03 -6.000000e+00 6.825346e-02 228.75 -2.00 3.34 -2.00 319.78 0.00e+00 -1.518793e-04 1.004490e-03 2.109691e-03 -6.000000e+00 3.138425e-03 291.34 -2.00 20.00 -2.00 318.94 0.00e+00 3.315 0.000 302.00 328.00 3 4.5170e+00 9.7491e-03 3.9609e-02 -6.0000e+00 1.6929e-01 6.8726e-02 1.1632e-02 2.4510e-02 -6.0000e+00 1.8271e-01 -4.4474e-02 8.4792e-03 1.0243e-02 -6.0000e+00 1.0936e-01 8.9809e-03 4.3427e-03 3.1965e-03 -6.0000e+00 4.6633e-02 1.3371e-04 -1.8270e-04 2.0512e-04 3.5215e-05 -6.0000e+00 3.5115e-03 -1.2777e-03 -8.7603e-06 12 8 8 10 0 0 99.90 16.05 0.42 -0.00128 -0.00265 22 6 1 5 0 2214.050 19.75 15.00 16.05 24.42 25.7 948.30 31071 -38791 -23675 -42044 -5850 -45725 -15219 -37969 -5671 -57627 -11277 -43598 -20219 -35569 4849 -6445 -1384 -8555 -1232 2304 -3105 13215 -10754 9168 -9380 506 -7899 1497 -8355 -8995 -5043 -2490 -6622 -224 -9296 8549 -753 3074 2962 2120 835 -1877 3533 2915 6221 354 4680 1258 1821 -982 1492 5639 2457 1803 1259 335 357 988 -276 311 155 4246 770 2931 -658 -1042 1241 1396 2027 2208 1667 -379 3441 -979 -624 -2902 -1543 -2978 -2346 -2880 -437 -2637 -2193 -1277 853 1119 783 808 61 524 -384 186 -1897 -440 -422 -450 -666 -42 -659 -448 -1395 -1951 -1805 -387 -1239 -698 -775 -136 1511 825 1256 -107 817 7 -491 371 419 307 434 68 362 1057 745 989 -383 -282 -117 735 -165 -311 -239 -449 -242 -321 -548 368 995 378 -169 60 -492 -917 457 -1241 -655 -1326 -121 -1423 -382 -1346 -172 -2864 -399 -2186 -1007 -2260 255 -420 -92 -649 -91 170 -247 910 -986 738 -965 48 -805 134 -809 -913 -542 -290 -860 -28 -1229 979 -107 501 574 472 205 -497 909 762 1581 95 1202 335 491 -286 457 1793 862 671 490 135 146 397 -111 126 66 1889 385 1504 -346 -523 592 690 1100 1328 1077 -255 2181 -612 -356 -1541 -827 -1652 -1427 -1850 -308 -2086 -1846 -1133 791 1099 805 840 63 509 -349 155 -1562 -370 -389 -467 -774 -53 -856 -561 -1633 -2136 -1943 -431 -1483 -877 -1026 -190 2234 1319 2090 -181 1313 11 -705 514 594 459 688 111 591 1667 1139 1446 -543 -414 -171 1031 -254 -517 -417 -814 -456 -638 -1155 798 2189 845 -373 129 -1007 -1825 SS 20220920T230039.2Z 8298.958787 245 1 48.18 2 67.12 105.16 12.12 135.04 0.00 1 0.00 1 0 25 4.065e-02 8.079e-03 2.810e-02 4.419e-03 3.154635e-01 2.351810e-03 3.682434e-03 -6.000000e+00 2.471561e-02 228.75 -2.00 3.34 -2.00 318.85 0.00e+00 1.290326e-03 5.318180e-04 8.570861e-04 -6.000000e+00 1.136314e-03 291.34 -2.00 20.00 -2.00 317.96 0.00e+00 2.551 0.000 302.00 328.00 3 4.8546e+00 6.4992e-03 2.9924e-02 -6.0000e+00 6.1302e-02 7.0042e-02 7.4899e-03 1.6212e-02 -6.0000e+00 6.6156e-02 -2.1392e-02 4.9288e-03 7.9051e-03 -6.0000e+00 3.9598e-02 -2.6917e-03 2.5346e-03 2.1908e-03 -6.0000e+00 1.6890e-02 2.1892e-04 -4.3202e-04 1.4521e-04 2.8897e-05 -6.0000e+00 1.2711e-03 -2.3624e-03 2.0549e-05 11 9 0 11 8 0 99.98 16.06 0.77 -0.00236 -0.00561 27 7 1 5 0 1784.220 19.75 15.00 16.06 25.01 25.6 951.69 -15571 -14390 -5802 4875 -17160 -20227 -8138 -13054 -10608 6262 -4439 -9687 -5970 -10459 412 3053 -1087 3160 -2974 397 -5941 7157 -3663 -2373 1416 454 -4110 -3301 -3946 -2149 -5129 -446 -1979 -4203 -3088 -2327 -2512 1334 159 581 1826 181 610 418 1990 2610 2352 -300 722 338 445 2232 382 69 1487 1696 -42 180 -1013 1077 957 2851 2226 1940 383 -29 -1345 2169 746 1186 677 1101 -675 42 -298 -2750 -2022 -1830 -1885 -2257 -1487 -1958 -2033 -473 -72 408 149 712 610 445 -24 -534 -767 -574 -328 281 557 -87 -155 -495 -1691 -851 -688 -801 -1305 -1136 -470 161 1020 775 1063 389 703 -109 -258 214 155 -141 -222 -476 627 1318 372 134 203 -238 485 -110 218 375 -333 -63 -88 -420 -325 402 458 57 419 -370 -177 -1027 -827 -811 -300 214 -875 -1053 -403 -755 -648 335 -273 -678 -461 -980 39 310 -122 357 -373 50 -802 934 -549 -371 224 74 -683 -521 -609 -333 -886 -80 -384 -835 -592 -454 -549 331 47 193 649 69 235 163 766 995 887 -115 275 133 187 987 182 34 757 880 -22 95 -533 562 526 1662 1406 1275 250 -18 -805 1282 490 858 525 870 -532 32 -204 -1746 -1190 -1080 -1210 -1639 -1197 -1726 -1909 -464 -75 449 172 828 697 483 -24 -497 -680 -518 -321 303 666 -113 -207 -642 -2061 -960 -765 -937 -1636 -1498 -645 232 1551 1257 1781 653 1119 -163 -360 289 214 -205 -345 -770 1006 2054 565 195 282 -316 630 -150 318 584 -546 -106 -153 -771 -628 801 935 118 855 -737 -338 -1919 SS 20220920T231559.7Z 8298.969441 250 1 12.04 2 64.06 107.69 10.22 149.80 0.00 1 0.00 1 0 17 2.998e-02 7.780e-03 1.579e-02 3.940e-03 2.844067e-01 2.087217e-03 3.261189e-03 -6.000000e+00 1.822930e-02 228.75 -2.00 3.34 -2.00 317.97 0.00e+00 3.169207e-04 3.687232e-04 4.317022e-04 -6.000000e+00 8.380815e-04 291.34 -2.00 20.00 -2.00 317.08 0.00e+00 2.272 0.000 302.00 328.00 3 4.3752e+00 5.5944e-03 2.6610e-02 -6.0000e+00 4.5214e-02 3.7230e-02 6.3335e-03 1.4226e-02 -6.0000e+00 4.8793e-02 -1.5053e-02 3.8936e-03 6.8629e-03 -6.0000e+00 2.9206e-02 -3.1719e-03 1.9546e-03 1.8961e-03 -6.0000e+00 1.2458e-02 4.9396e-04 -2.0603e-04 1.2670e-04 2.4216e-05 -6.0000e+00 9.3745e-04 -2.5601e-03 2.4118e-05 12 9 1 12 1 1 99.96 16.06 0.80 -0.00256 -0.00411 9 10 1 5 0 1186.750 19.75 15.00 16.06 25.61 25.8 956.10 -9796 558 -13434 3798 -12948 -11039 -13210 -318 -6788 -8912 -1247 -7938 3608 -3541 3455 -2475 2263 -78 1842 -1943 4706 1550 3829 -2589 2235 -2713 -981 -2265 -1227 -1563 -9 599 -3705 761 -5107 -912 -3590 129 -424 851 -218 1078 416 1131 508 25 1094 144 1080 -297 2800 -97 2353 1555 2846 1028 704 -779 918 598 1238 2620 1040 529 -351 -670 372 465 -173 1545 -371 409 -413 -339 -1229 -1517 -1488 -1733 -2560 -1006 -1066 -2407 -1734 -166 20 -100 1129 -181 823 259 -257 -806 49 -92 394 550 140 -30 -254 -22 -1640 -19 -561 352 -1630 -397 -551 105 31 691 624 -19 80 87 325 142 693 580 141 -492 886 784 961 169 346 -31 280 -124 -80 104 -3 -139 -195 -60 -547 157 -2 294 -473 312 -503 -465 -851 47 -1280 286 -1075 -891 -1172 -28 -681 -945 -126 -915 419 -506 518 -426 391 -14 347 -391 899 308 769 -586 506 -656 -227 -506 -262 -339 -2 147 -1002 197 -1362 -239 -1083 44 -172 385 -108 498 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