File name: Pandora238s1_Granada_20230315_L2Fit_fwvt1c4d20221202p1-8.txt File generation date: 20250305T234202.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Daniel Perez Ramirez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v1d20220614.txt Instrument calibration file used: Pandora238s1_CF_v4d20221202.txt Level 1 file used: Pandora238s1_Granada_20230315_L1_smca1c4d20221202p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20230315 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Full Cal on 1.8, based on clearance with ND and sens updated First and last pixel inside fitting window: 1624 1774 Nominal wavelengths inside fitting window [nm]: 492.0527 492.1733 492.2939 492.4145 492.5351 492.6557 492.7762 492.8967 493.0173 493.1378 493.2582 493.3787 493.4991 493.6196 493.7400 493.8604 493.9807 494.1011 494.2214 494.3418 494.4621 494.5824 494.7026 494.8229 494.9431 495.0633 495.1835 495.3037 495.4239 495.5440 495.6642 495.7843 495.9044 496.0245 496.1445 496.2646 496.3846 496.5046 496.6246 496.7446 496.8645 496.9845 497.1044 497.2243 497.3442 497.4641 497.5839 497.7038 497.8236 497.9434 498.0632 498.1830 498.3027 498.4224 498.5422 498.6619 498.7815 498.9012 499.0208 499.1405 499.2601 499.3797 499.4993 499.6188 499.7384 499.8579 499.9774 500.0969 500.2164 500.3358 500.4552 500.5747 500.6941 500.8134 500.9328 501.0522 501.1715 501.2908 501.4101 501.5294 501.6487 501.7679 501.8871 502.0063 502.1255 502.2447 502.3639 502.4830 502.6021 502.7212 502.8403 502.9594 503.0784 503.1975 503.3165 503.4355 503.5545 503.6734 503.7924 503.9113 504.0302 504.1491 504.2680 504.3869 504.5057 504.6245 504.7433 504.8621 504.9809 505.0997 505.2184 505.3371 505.4558 505.5745 505.6932 505.8118 505.9304 506.0491 506.1677 506.2862 506.4048 506.5233 506.6419 506.7604 506.8789 506.9973 507.1158 507.2342 507.3527 507.4711 507.5894 507.7078 507.8262 507.9445 508.0628 508.1811 508.2994 508.4177 508.5359 508.6541 508.7723 508.8905 509.0087 509.1269 509.2450 509.3631 509.4812 509.5993 509.7174 509.8354 509.9535 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230315T070306.7Z 8474.293827 226 1 5.94 2 83.47 97.78 66.01 187.95 0.00 1 0.00 1 0 15 2.907e-03 2.900e-03 1.247e-04 1.244e-04 4.315874e+03 7.223387e+00 3.112273e+02 -6.000000e+00 1.481674e+02 276.03 -2.00 20.00 -2.00 505.28 0.00e+00 1.723075e-03 3.284540e-06 9.930929e-05 -6.000000e+00 7.829603e-05 276.03 -2.00 20.00 -2.00 500.45 0.00e+00 7.025807e-01 2.390093e-03 3.517081e-02 -6.000000e+00 5.585538e-02 226.22 -2.00 3.42 -2.00 502.04 0.00e+00 7.994 0.008 489.00 513.00 1 9.9061e-02 1.8224e-04 1.1256e-02 -6.0000e+00 4.2600e-03 1.3313e-03 4.7581e-05 9.8680e-04 -6.0000e+00 1.1235e-03 5.7146e-01 5.1699e-04 8.9442e-06 4.1276e-05 -6.0000e+00 2.1694e-04 1.8911e-03 2.7043e-05 10 0 0 10 0 0 -17.55 20.42 1.72 0.00189 0.00548 1243 137 1 4 0 4.424 24.50 14.99 20.42 15.66 4.2 902.32 -717 -348 35 315 131 183 545 878 700 227 82 -5 -91 5 145 -70 -56 14 117 215 -17 55 30 119 244 273 54 -175 61 -296 -271 -276 -637 -332 84 -61 -331 -79 -144 105 53 -25 -137 206 350 355 294 482 561 180 -249 -639 -548 -571 -378 -68 -63 3 259 302 101 249 259 41 97 -47 9 -403 -375 -343 -400 -149 -197 -233 -234 21 -183 -350 -386 -251 -489 -457 -393 -357 -230 -108 -278 -298 -48 103 126 147 316 354 179 206 30 -237 -503 -408 -509 -131 -435 -293 -191 -158 -209 -37 -219 103 7 130 419 340 303 206 336 494 575 229 103 23 -33 161 305 273 249 208 382 378 27 6 119 364 -102 -315 -26 106 163 117 145 145 181 73 -103 -19 -8 -59 -243 -301 -389 -700 -342 34 319 136 192 569 925 737 236 84 -5 -94 5 145 -71 -57 14 124 223 -19 58 31 123 256 287 57 -184 64 -301 -274 -274 -639 -345 90 -65 -349 -83 -148 106 54 -26 -143 217 363 371 305 507 581 183 -251 -629 -532 -555 -378 -69 -64 3 265 306 102 254 268 43 100 -47 9 -407 -376 -336 -386 -146 -195 -232 -231 21 -181 -340 -372 -239 -466 -444 -385 -348 -223 -106 -274 -291 -47 100 124 145 312 355 176 204 29 -225 -476 -376 -467 -121 -414 -284 -189 -158 -206 -36 -214 100 7 129 418 336 302 206 338 502 583 228 101 23 -33 158 297 264 241 203 370 365 26 6 114 346 -97 -298 -25 104 160 117 144 143 181 73 -104 -19 -8 -59 -235 -288 -375 SQ 20230315T070312.7Z 8474.293897 226 2 5.94 2 83.45 97.80 66.01 187.97 0.00 1 0.00 1 0 15 2.942e-03 2.938e-03 1.241e-04 1.239e-04 4.347646e+03 7.181814e+00 3.134632e+02 -6.000000e+00 1.499816e+02 276.03 -2.00 20.00 -2.00 505.28 0.00e+00 1.727077e-03 3.270992e-06 9.934106e-05 -6.000000e+00 7.925470e-05 276.03 -2.00 20.00 -2.00 500.46 0.00e+00 6.882830e-01 2.377823e-03 3.533170e-02 -6.000000e+00 5.653941e-02 226.22 -2.00 3.42 -2.00 502.05 0.00e+00 7.974 0.008 489.00 513.00 1 9.5653e-02 1.8126e-04 1.1235e-02 -6.0000e+00 4.3122e-03 1.5360e-03 4.7334e-05 9.8926e-04 -6.0000e+00 1.1372e-03 5.7545e-01 5.1997e-04 8.9393e-06 4.2012e-05 -6.0000e+00 2.1960e-04 2.0681e-03 2.5801e-05 10 0 0 10 0 0 -13.67 20.42 1.72 0.00207 0.00567 1243 137 1 4 0 4.424 24.50 14.99 20.42 15.66 4.2 902.32 -737 -335 26 318 122 181 538 913 735 227 57 17 -77 8 129 -64 -83 28 143 224 -5 14 39 109 233 249 52 -174 82 -291 -273 -290 -627 -315 64 -62 -331 -79 -141 88 34 -32 -96 230 351 341 288 473 592 141 -299 -651 -560 -590 -389 -60 -53 15 296 309 137 257 247 25 91 -12 -27 -429 -341 -309 -358 -159 -188 -261 -212 18 -170 -400 -393 -233 -493 -470 -396 -409 -228 -105 -305 -296 -90 97 165 173 330 374 174 172 66 -240 -535 -399 -497 -143 -425 -296 -195 -217 -190 -25 -237 118 27 138 440 353 316 233 312 460 567 256 105 14 -8 202 326 281 264 173 384 318 7 29 125 356 -102 -321 -72 136 152 76 177 147 156 74 -106 18 16 -68 -245 -286 -386 -721 -330 26 323 126 186 564 964 775 236 58 17 -79 8 129 -65 -85 29 151 233 -5 15 41 114 246 263 55 -182 84 -288 -277 -289 -630 -319 66 -65 -350 -83 -145 90 35 -34 -100 237 365 357 300 486 614 144 -301 -643 -545 -575 -390 -61 -54 16 304 313 139 263 256 26 94 -12 -27 -424 -342 -304 -347 -156 -187 -260 -210 17 -169 -390 -379 -223 -471 -459 -389 -400 -221 -104 -301 -290 -88 95 162 171 327 376 171 171 65 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902.32 -741 -355 31 308 142 178 549 902 723 202 58 26 -75 3 155 -37 -98 21 138 218 -8 -18 24 126 232 253 39 -167 98 -317 -258 -328 -638 -306 59 -48 -327 -71 -164 101 64 -3 -76 210 346 350 302 473 568 167 -296 -600 -541 -600 -382 -35 -37 2 287 284 84 247 232 36 90 -55 -20 -443 -341 -310 -389 -160 -212 -263 -224 -3 -154 -383 -372 -226 -491 -456 -382 -387 -250 -85 -286 -307 -83 76 121 126 367 379 184 220 43 -228 -509 -400 -533 -162 -442 -298 -181 -206 -182 -50 -214 104 34 163 411 359 312 221 310 461 615 254 90 34 -12 184 356 273 237 178 385 320 27 7 140 366 -81 -332 -12 115 133 85 195 160 152 81 -108 -9 -7 -43 -249 -317 -399 -727 -341 31 314 147 183 576 956 765 211 60 27 -77 3 156 -37 -100 21 143 227 -9 -19 25 131 245 267 41 -176 101 -316 -255 -327 -643 -311 61 -50 -338 -74 -170 103 65 -3 -79 217 361 368 315 488 576 171 -292 -593 -527 -587 -375 -36 -37 2 295 290 86 254 241 37 92 -56 -20 -439 -343 -306 -378 -157 -211 -256 -222 -3 -149 -374 -360 -216 -471 -446 -376 -380 -243 -84 -283 -302 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