File name: Pandora238s1_Granada_20230619_L2Fit_fout2c9d20230607p1-8.txt File generation date: 20250305T233256.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v9d20230607.txt Level 1 file used: Pandora238s1_Granada_20230619_L1_smca1c9d20230607p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20230619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 9 to update SO2 and HCHO First and last pixel inside fitting window: 202 343 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2456 305.3866 305.5275 305.6685 305.8095 305.9504 306.0914 306.2323 306.3732 306.5141 306.6550 306.7958 306.9367 307.0775 307.2184 307.3592 307.5000 307.6408 307.7816 307.9223 308.0631 308.2039 308.3446 308.4853 308.6260 308.7667 308.9074 309.0481 309.1887 309.3294 309.4700 309.6106 309.7512 309.8918 310.0324 310.1730 310.3136 310.4541 310.5946 310.7352 310.8757 311.0162 311.1566 311.2971 311.4376 311.5780 311.7185 311.8589 311.9993 312.1397 312.2801 312.4205 312.5608 312.7012 312.8415 312.9818 313.1221 313.2624 313.4027 313.5430 313.6833 313.8235 313.9637 314.1040 314.2442 314.3844 314.5246 314.6647 314.8049 314.9450 315.0852 315.2253 315.3654 315.5055 315.6456 315.7857 315.9258 316.0658 316.2058 316.3459 316.4859 316.6259 316.7659 316.9059 317.0458 317.1858 317.3257 317.4656 317.6056 317.7455 317.8853 318.0252 318.1651 318.3049 318.4448 318.5846 318.7244 318.8642 319.0040 319.1438 319.2836 319.4233 319.5631 319.7028 319.8425 319.9822 320.1219 320.2616 320.4013 320.5409 320.6806 320.8202 320.9598 321.0994 321.2390 321.3786 321.5182 321.6577 321.7973 321.9368 322.0763 322.2158 322.3553 322.4948 322.6343 322.7737 322.9132 323.0526 323.1920 323.3315 323.4709 323.6102 323.7496 323.8890 324.0283 324.1677 324.3070 324.4463 324.5856 324.7249 324.8642 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230619T073701.6Z 8570.317379 160 1 16.71 2 60.39 81.79 70.10 70.33 0.00 1 0.00 1 0 17 1.170e-02 6.208e-03 6.251e-03 2.045e-03 2.872805e-01 1.018681e-03 3.383260e-03 -6.000000e+00 6.477699e-03 232.27 -2.00 3.42 -2.00 316.96 0.00e+00 2.902378e-04 1.344631e-04 8.064192e-05 -6.000000e+00 2.839915e-04 285.74 -2.00 20.00 -2.00 316.21 0.00e+00 2.015 0.000 302.00 328.00 3 3.2464e+00 2.6894e-03 2.3926e-02 -6.0000e+00 1.6293e-02 4.9099e-02 3.0035e-03 1.4753e-02 -6.0000e+00 1.7592e-02 -1.4062e-02 1.8142e-03 7.1749e-03 -6.0000e+00 1.0445e-02 -1.2365e-03 9.1896e-04 1.9928e-03 -6.0000e+00 4.5775e-03 2.1758e-03 -5.8997e-05 4.7101e-05 1.6156e-05 -6.0000e+00 2.4671e-04 -3.6943e-03 0.0000e+00 12 1 1 12 1 1 99.93 21.24 0.96 -0.00369 -0.00414 47 18 1 5 0 326.507 25.00 15.00 21.24 25.95 4.3 969.11 1799 -288 -2384 -5426 -6316 -2109 -1459 -132 -2823 -1673 -2417 -283 -1681 -207 -303 408 546 466 401 943 1557 -184 1331 313 100 339 405 404 -1297 1677 837 2275 1532 61 -2982 -1105 -2225 -1796 -1471 -1010 -1093 -782 -748 -45 -85 -94 -100 -86 -867 392 642 702 466 163 8 929 1105 954 950 -45 1081 991 1324 713 -359 380 -173 -131 921 1000 320 86 -91 8 673 447 -108 -414 -111 -743 -1224 -1400 -1849 -1306 -680 -644 -615 66 279 -49 836 910 176 99 337 102 496 177 -66 -479 179 -61 -787 443 -1525 -911 -757 -527 -172 434 640 481 -1 661 160 319 59 492 34 -106 -545 114 166 -257 769 679 801 962 180 198 61 -98 -309 677 -73 -394 127 -151 -229 -733 -13 -155 186 -32 -283 -637 -637 -211 -157 -16 -394 -242 -327 -40 -286 -39 -67 99 132 121 107 261 436 -50 382 97 32 114 135 121 -364 471 265 739 575 23 -994 -382 -878 -749 -753 -555 -633 -465 -464 -27 -52 -58 -59 -50 -542 244 404 467 326 123 6 716 877 737 717 -34 850 787 1140 670 -325 299 -145 -105 760 964 307 86 -88 7 607 384 -86 -315 -94 -673 -1234 -1480 -2024 -1484 -786 -790 -791 80 342 -60 982 990 174 97 368 115 622 237 -92 -627 233 -72 -939 536 -1948 -1175 -1035 -755 -241 660 961 764 -1 912 214 405 77 673 48 -159 -813 166 237 -366 1029 880 1013 1215 249 272 90 -145 -469 1005 -117 -635 213 -254 -379 -1223 -22 -240 SS 20230619T074043.3Z 8570.319946 163 1 2.24 2 59.66 82.29 69.43 70.77 0.00 1 0.00 1 0 17 1.040e-02 6.837e-03 6.290e-03 2.944e-03 2.821336e-01 1.471004e-03 3.317088e-03 -6.000000e+00 5.754880e-03 232.27 -2.00 3.42 -2.00 316.22 0.00e+00 3.640007e-04 1.622556e-04 4.850715e-05 -6.000000e+00 2.522538e-04 285.74 -2.00 20.00 -2.00 315.50 0.00e+00 1.972 0.000 302.00 328.00 3 1.6258e+00 3.8477e-03 2.3393e-02 -6.0000e+00 1.4475e-02 4.3330e-02 4.2787e-03 1.4397e-02 -6.0000e+00 1.5628e-02 -1.7455e-02 2.4989e-03 6.9955e-03 -6.0000e+00 9.2789e-03 3.6108e-05 1.2143e-03 1.9594e-03 -6.0000e+00 4.0673e-03 1.1583e-02 -1.7421e-05 6.6855e-05 1.6744e-05 -6.0000e+00 2.1895e-04 -4.8167e-03 0.0000e+00 12 9 1 12 1 1 -65.28 21.23 0.94 -0.00482 -0.00495 14 73 1 5 0 81.241 25.00 15.00 21.23 26.58 4.3 974.48 -2812 12 597 -1894 -3157 -2586 -2409 -2337 -654 -364 -3004 905 -951 -2177 -833 737 1142 1627 1433 935 1311 838 676 1143 149 1466 747 -1243 1155 1001 762 772 1300 129 -3109 -1333 -1382 -1777 -2057 -1044 -756 -852 -769 -78 478 287 -730 57 -1019 350 711 -205 1688 598 470 1235 602 1122 819 112 427 772 1033 870 -807 316 -63 -895 795 955 621 -61 -70 191 767 -334 58 -781 458 -1121 -1079 -1312 -2449 -867 -950 -1237 -418 95 665 28 629 362 575 288 603 177 693 431 -91 -146 255 41 -538 458 -1113 -643 -626 -801 -537 22 580 104 262 615 320 181 31 833 -159 -434 -643 67 361 -79 948 611 808 1173 150 46 -183 -6 -397 608 -324 -343 528 -376 -275 -723 -150 108 -505 2 114 -325 -505 -424 -426 -437 -134 -78 -612 189 -240 -581 -257 246 380 536 487 333 473 288 251 449 61 625 318 -485 434 387 308 324 584 59 -1321 -586 -644 -911 -1231 -689 -498 -578 -544 -54 330 199 -494 40 -699 238 507 -149 1261 486 369 977 494 891 668 92 348 655 951 833 -750 278 -54 -743 697 937 624 -62 -71 188 706 -297 50 -639 395 -1035 -1059 -1399 -2723 -954 -1104 -1482 -521 117 842 33 721 401 593 297 663 208 839 556 -121 -189 321 49 -622 556 -1416 -827 -828 -1078 -750 32 864 155 378 844 425 230 41 1095 -223 -634 -927 94 513 -109 1265 793 991 1475 201 64 -261 -9 -582 893 -503 -545 826 -608 -438 -1130 -228 161 SS 20230619T080430.4Z 8570.336463 176 1 53.98 2 54.95 85.56 65.06 73.64 0.00 1 0.00 1 0 17 2.413e-02 8.178e-03 2.053e-02 5.216e-03 2.536833e-01 2.577125e-03 3.004570e-03 -6.000000e+00 1.335536e-02 232.27 -2.00 3.42 -2.00 317.79 0.00e+00 2.934484e-04 4.211183e-04 7.999411e-05 -6.000000e+00 5.856931e-04 285.74 -2.00 20.00 -2.00 317.03 0.00e+00 1.736 0.000 302.00 328.00 3 5.0711e+00 6.8982e-03 2.0894e-02 -6.0000e+00 3.3592e-02 7.6057e-02 7.7793e-03 1.3151e-02 -6.0000e+00 3.6272e-02 -1.7194e-02 4.9053e-03 6.4221e-03 -6.0000e+00 2.1536e-02 -1.8336e-03 2.5510e-03 1.7926e-03 -6.0000e+00 9.4358e-03 4.7299e-04 -2.3490e-04 1.2287e-04 1.4526e-05 -6.0000e+00 5.0960e-04 -1.9033e-03 0.0000e+00 11 8 0 10 0 0 99.98 21.22 0.04 -0.00190 -0.00367 283 31 1 5 0 190.383 25.00 14.99 21.22 28.66 4.2 986.83 -3486 3372 -5342 -944 -6507 3416 -12236 -2908 -9690 456 -5364 -11316 -259 -902 1959 -3287 259 2786 6532 1318 -466 1859 1356 4978 -606 -1958 3193 -4892 13 1028 3434 1491 695 1247 -1294 563 -1225 -4982 -592 -1332 -271 459 88 -524 -1467 -989 -777 195 -1717 -199 352 416 965 2007 -1375 2040 889 1201 1744 -63 864 1208 2283 864 712 -319 561 -1169 1287 449 1198 782 -440 -417 564 -304 -1392 -1301 -284 -2415 -1685 -1985 -2775 -2405 -281 -791 20 842 624 769 194 1290 265 376 867 698 230 342 -168 462 -198 -509 -1350 -316 -1461 -487 -537 -304 -71 455 713 19 248 257 -27 341 -294 316 -3 9 -707 -8 696 -441 1274 419 363 717 439 252 -324 -122 -29 676 156 -189 234 -75 -498 -546 -220 -204 -319 301 -541 -80 -492 241 -1085 -268 -1063 47 -583 -1377 -33 -130 318 -612 46 515 1193 264 -96 356 280 1050 -139 -479 793 -1180 3 219 789 360 193 342 -308 139 -346 -1698 -237 -629 -133 229 46 -270 -764 -512 -387 94 -820 -94 182 226 545 1202 -859 1246 617 741 1140 -42 594 901 1825 755 592 -234 395 -797 960 394 1107 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