File name: Pandora238s1_Granada_20240810_L2Fit_fout2c14d20240721p1-8.txt File generation date: 20250305T233311.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Inmaculada Foyo Moreno Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 238 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora238_OF_v2d20220614.txt Instrument calibration file used: Pandora238s1_CF_v14d20240721.txt Level 1 file used: Pandora238s1_Granada_20240810_L1_smca1c14d20240721p1-8.txt Full location name: Andalusian Institute for Earth System Research (IISTA) - University of Granada Short location name: Granada Country of location: Spain Location latitude [deg]: 37.1640 Location longitude [deg]: -3.6050 Location altitude [m]: 680 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on 11 to update SO2 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.1097 305.2506 305.3914 305.5322 305.6730 305.8138 305.9546 306.0954 306.2362 306.3769 306.5177 306.6584 306.7991 306.9398 307.0805 307.2212 307.3619 307.5025 307.6432 307.7838 307.9244 308.0651 308.2057 308.3463 308.4868 308.6274 308.7680 308.9085 309.0490 309.1896 309.3301 309.4706 309.6111 309.7516 309.8920 310.0325 310.1729 310.3134 310.4538 310.5942 310.7346 310.8750 311.0154 311.1557 311.2961 311.4364 311.5767 311.7171 311.8574 311.9977 312.1379 312.2782 312.4185 312.5587 312.6990 312.8392 312.9794 313.1196 313.2598 313.4000 313.5402 313.6803 313.8205 313.9606 314.1007 314.2408 314.3809 314.5210 314.6611 314.8012 314.9412 315.0813 315.2213 315.3613 315.5013 315.6413 315.7813 315.9213 316.0612 316.2012 316.3411 316.4811 316.6210 316.7609 316.9008 317.0407 317.1805 317.3204 317.4602 317.6001 317.7399 317.8797 318.0195 318.1593 318.2991 318.4388 318.5786 318.7183 318.8581 318.9978 319.1375 319.2772 319.4169 319.5566 319.6962 319.8359 319.9755 320.1151 320.2547 320.3944 320.5339 320.6735 320.8131 320.9527 321.0922 321.2317 321.3713 321.5108 321.6503 321.7898 321.9292 322.0687 322.2081 322.3476 322.4870 322.6264 322.7658 322.9052 323.0446 323.1840 323.3234 323.4627 323.6020 323.7414 323.8807 324.0200 324.1593 324.2985 324.4378 324.5771 324.7163 324.8555 324.9948 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T060538.1Z 8988.253913 70 1 54.76 2 83.52 75.57 143.65 48.83 0.00 1 0.00 1 0 17 6.523e-01 3.369e-02 4.792e-01 2.504e-02 9.401987e-01 1.463370e-02 1.028041e-02 -6.000000e+00 3.719019e-01 231.20 -2.00 3.42 -2.00 322.30 0.00e+00 7.150287e-03 8.857931e-03 1.126321e-03 -6.000000e+00 1.879038e-02 288.57 -2.00 20.00 -2.00 321.84 0.00e+00 8.017 0.008 302.00 328.00 3 1.2388e+00 6.0863e-02 8.9405e-02 -6.0000e+00 9.3333e-01 1.2780e+00 7.9388e-02 5.1572e-02 -6.0000e+00 1.0202e+00 -1.6770e+00 6.1303e-02 2.4498e-02 -6.0000e+00 6.0153e-01 6.6323e-01 2.8908e-02 1.0160e-02 -6.0000e+00 2.6022e-01 3.2680e-05 -2.1715e-03 6.0164e-04 1.0232e-04 -6.0000e+00 1.4751e-02 -1.4167e-03 0.0000e+00 12 8 8 10 0 0 -13.75 21.78 1.36 -0.00142 -0.01773 38 4 1 5 0 1440.532 25.50 15.00 21.78 29.86 4.9 973.25 900000 -143248 113698 -110230 900000 900000 -149810 168651 900000 58065 19682 900000 90942 900000 900000 149326 42620 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900000 1870 -3877 900000 2758 2922 3273 5392 900000 3826 4265 3649 1446 3215 3596 3965 3563 4701 941 -1037 1962 4883 5044 4636 4436 3852 2007 4129 5544 1945 -3067 1100 -389 642 1161 1426 2540 -986 1980 -1 2571 2589 781 -2868 531 -1667 -3056 -6861 -1348 -2944 4949 -2573 -6390 714 -7576 109 -3449 -2565 1609 -4426 1701 -5526 1625 107 974 -1933 -369 993 -987 -1635 -3599 1921 2335 2092 4686 4321 1639 -2055 -36 -564 1668 836 -2199 4201 7116 2229 1330 -1656 -1750 -2589 1486 -3255 -456 2984 1486 -1080 -5402 SS 20240810T061603.8Z 8988.261155 73 1 54.12 2 81.50 77.09 142.14 52.07 0.00 1 0.00 1 0 17 6.290e-01 1.049e-02 3.526e-01 7.076e-03 7.969491e-01 3.932557e-03 8.580387e-03 -6.000000e+00 3.460136e-01 231.20 -2.00 3.42 -2.00 321.83 0.00e+00 6.384796e-03 2.315596e-03 1.116375e-03 -6.000000e+00 1.851756e-02 288.57 -2.00 20.00 -2.00 321.27 0.00e+00 6.368 0.004 302.00 328.00 3 1.1730e+00 1.5372e-02 7.2264e-02 -6.0000e+00 8.7005e-01 1.9080e-01 2.4740e-02 4.3722e-02 -6.0000e+00 9.5018e-01 -2.1634e-01 2.7023e-02 2.4196e-02 -6.0000e+00 5.6356e-01 7.1768e-02 1.2078e-02 1.1370e-02 -6.0000e+00 2.4316e-01 2.0373e-04 -4.5338e-04 1.6843e-04 8.0534e-05 -6.0000e+00 1.4170e-02 -8.3239e-04 0.0000e+00 12 8 8 10 0 0 -0.25 21.79 1.07 -0.00083 -0.00424 112 12 1 5 0 482.787 25.50 15.00 21.79 30.67 4.9 979.32 -187453 900000 -208645 900000 -270648 -176334 900000 -188019 -299020 900000 900000 -237034 -51208 900000 900000 5361 -162390 900000 61509 900000 900000 -167540 900000 63741 900000 -80759 100343 -79215 40475 -75287 145807 10778 -46933 -26301 -20255 14605 15112 -4407 -19093 2723 14379 25200 -1374 2618 41129 21727 23962 10799 12608 21425 19016 9135 10064 4992 2699 -6401 15829 -4531 2029 -2343 11500 17471 14016 -245 7419 -2007 452 1117 3785 1515 5753 4 192 899 4507 31 346 -1765 4622 -1537 1622 -514 -3213 1026 -591 -2277 -1385 -193 -1121 1319 2245 1548 -2265 -412 -1603 -70 397 32 59 -173 -547 412 -1862 -185 -727 -839 -581 -1392 -409 -102 1242 1020 368 381 -320 -468 -536 135 -641 -577 -254 905 146 134 756 1575 671 53 -13 -303 -592 -264 50 570 427 -139 402 -175 -165 -743 289 151 -362 -1290 900000 -1436 900000 -1863 -1214 900000 -1294 -3800 900000 900000 -2448 -353 900000 900000 37 -2795 900000 423 900000 900000 -3941 900000 439 900000 -1213 691 -1140 279 -1272 1004 121 -1175 -560 -355 192 227 -97 -609 85 441 741 -57 105 1158 775 870 528 651 1106 1191 704 845 495 286 -771 1591 -540 218 -260 1180 1936 1882 -45 1287 -362 85 214 821 400 1560 1 54 235 1005 6 70 -383 1149 -497 592 -226 -1551 498 -317 -1315 -828 -116 -680 736 1128 756 -1121 -217 -1017 -52 339 32 64 -182 -536 346 -1431 -150 -651 -765 -571 -1502 -485 -140 1725 1499 538 540 -429 -609 -729 191 -981 -905 -376 1261 199 175 1037 2112 849 69 -19 -526 -1161 -544 109 1319 1078 -338 1048 -440 -406 -1858 673 326 -762 SS 20240810T062949.7Z 8988.270714 78 1 54.00 2 78.82 79.07 140.05 56.05 0.00 1 0.00 1 0 17 3.617e-01 5.646e-03 2.242e-01 2.558e-03 6.488035e-01 1.296862e-03 7.123116e-03 -6.000000e+00 1.960268e-01 231.20 -2.00 3.42 -2.00 321.06 0.00e+00 3.539743e-03 6.149011e-04 1.663407e-03 -6.000000e+00 8.836633e-03 288.57 -2.00 20.00 -2.00 320.40 0.00e+00 4.976 0.002 302.00 328.00 3 9.5013e-01 4.4054e-03 5.7053e-02 -6.0000e+00 4.9097e-01 6.4378e-02 6.1643e-03 3.4171e-02 -6.0000e+00 5.3367e-01 -4.3478e-02 6.3799e-03 1.8459e-02 -6.0000e+00 3.1783e-01 1.4578e-03 3.0649e-03 6.4764e-03 -6.0000e+00 1.3615e-01 1.0080e-03 -3.6076e-04 5.9033e-05 5.4772e-05 -6.0000e+00 7.6193e-03 -9.7552e-04 0.0000e+00 10 0 0 10 0 0 -17.23 21.77 1.01 -0.00098 -0.00369 279 31 1 5 0 193.172 25.50 15.00 21.77 32.06 4.9 988.48 -148628 -63635 -86635 -163543 -133420 -52965 -99766 -35213 -83835 -62979 250109 13001 5524 -47364 -30895 -16843 -17954 -43540 -30271 -13468 5579 -23542 -15876 -40361 -8383 -25105 3312 -17121 -26326 -1893 -8872 -15753 -8131 -8614 -8727 -9092 -10457 9803 1744 -7145 4801 361 136 -4019 -402 -2232 -850 -2063 -2246 -3017 945 3165 3795 2039 864 1808 333 -1771 -1141 1689 2094 2226 2707 3678 856 1609 1029 -264 2156 2058 1040 432 100 -228 15 -243 -937 -2224 -471 -525 -1532 -1035 -1668 -599 -726 -276 -23 544 684 564 1136 106 -1347 -76 -130 -17 556 -262 213 -274 83 -81 -1164 -91 -1274 -948 -978 -683 -208 567 432 507 151 579 433 181 300 481 -311 -421 -241 314 333 -366 184 422 610 475 -19 -88 -332 -250 -556 342 -91 -346 595 -171 -230 -530 226 411 127 -884 -183 -349 -1287 -691 -143 -477 -102 -453 -301 624 35 22 -404 -289 -165 -194 -697 -453 -199 70 -379 -266 -952 -152 -581 59 -349 -579 -38 -243 -525 -308 -340 -301 -336 -451 413 100 -546 356 33 13 -408 -40 -236 -91 -233 -267 -387 136 491 637 387 173 371 72 -382 -237 337 441 530 735 1139 275 475 319 -83 767 869 476 207 46 -99 6 -83 -313 -763 -189 -254 -858 -672 -1154 -430 -517 -208 -18 433 544 423 844 76 -933 -55 -110 -15 563 -315 269 -331 93 -80 -1054 -88 -1371 -1034 -1146 -860 -284 879 676 824 240 956 666 269 462 774 -498 -701 -382 478 539 -567 271 608 815 704 -30 -153 -642 -504 -1179 759 -204 -815 1371 -418 -549 -1187 478 880 264 SS 20240810T063506.8Z 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