File name: Pandora200s1_GrandForksND_20251019_L2Fit_fout2c3d20230515p1-8.txt File generation date: 20251020T062347.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mafany Ndiva Mongoh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 200 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora200_OF_v3d20210115.txt Instrument calibration file used: Pandora200s1_CF_v3d20230515.txt Level 1 file used: Pandora200s1_GrandForksND_20251019_L1_smca1c3d20230515p1-8.txt Full location name: University of North Dakota Grand Forks ND Short location name: GrandForksND Country of location: United States Location latitude [deg]: 47.9219 Location longitude [deg]: -97.0865 Location altitude [m]: 256 Local noon date: 20251019 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Anafld, based on Oob session 2." First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0016 305.1427 305.2839 305.4250 305.5662 305.7073 305.8484 305.9895 306.1306 306.2717 306.4128 306.5538 306.6949 306.8359 306.9770 307.1180 307.2590 307.4000 307.5410 307.6819 307.8229 307.9639 308.1048 308.2457 308.3866 308.5276 308.6685 308.8093 308.9502 309.0911 309.2319 309.3728 309.5136 309.6544 309.7952 309.9360 310.0768 310.2176 310.3583 310.4991 310.6398 310.7805 310.9213 311.0620 311.2027 311.3433 311.4840 311.6247 311.7653 311.9059 312.0466 312.1872 312.3278 312.4684 312.6090 312.7495 312.8901 313.0306 313.1712 313.3117 313.4522 313.5927 313.7332 313.8737 314.0141 314.1546 314.2950 314.4355 314.5759 314.7163 314.8567 314.9971 315.1374 315.2778 315.4182 315.5585 315.6988 315.8391 315.9794 316.1197 316.2600 316.4003 316.5405 316.6808 316.8210 316.9613 317.1015 317.2417 317.3819 317.5220 317.6622 317.8024 317.9425 318.0826 318.2228 318.3629 318.5030 318.6430 318.7831 318.9232 319.0632 319.2033 319.3433 319.4833 319.6233 319.7633 319.9033 320.0433 320.1832 320.3232 320.4631 320.6030 320.7429 320.8828 321.0227 321.1626 321.3025 321.4423 321.5822 321.7220 321.8618 322.0016 322.1414 322.2812 322.4210 322.5607 322.7005 322.8402 322.9799 323.1196 323.2593 323.3990 323.5387 323.6784 323.8180 323.9577 324.0973 324.2369 324.3765 324.5161 324.6557 324.7953 324.9348 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251019T133010.0Z 9423.562616 100 1 48.04 2 85.08 111.13 68.12 123.87 0.00 1 0.00 1 0 25 6.369e-01 5.614e-02 4.471e-01 4.985e-02 1.058986e+00 3.136592e-02 1.295280e-02 -6.000000e+00 4.141608e-01 224.41 -2.00 3.69 -2.00 322.04 0.00e+00 -1.882142e-02 1.053210e-02 7.427741e-04 -6.000000e+00 1.898647e-02 277.18 -2.00 20.00 -2.00 321.46 0.00e+00 9.950 0.020 302.00 328.00 3 -5.9019e-02 1.0029e-01 1.1308e-01 -6.0000e+00 1.0264e+00 2.3726e+00 1.1704e-01 6.3596e-02 -6.0000e+00 1.1213e+00 -2.3931e+00 6.8371e-02 2.7751e-02 -6.0000e+00 6.6313e-01 7.8994e-01 3.6920e-02 1.7383e-02 -6.0000e+00 2.6738e-01 1.0320e-05 -1.1072e-03 1.4804e-03 3.8603e-04 -6.0000e+00 2.3961e-02 7.6138e-05 0.0000e+00 12 8 8 10 0 0 33.03 18.39 0.72 0.00008 -0.00824 35 9 1 5 0 1372.230 21.79 15.00 18.39 7.25 30.6 870.54 87289 192367 83709 -1154 -27209 120821 2443 1380 -46257 129324 -16242 331901 -37788 81166 61880 900000 8338 900000 900000 271412 -3846 118311 53302 22809 112053 18737 900000 -27298 65983 -48299 900000 -29589 900000 -42655 63123 -42122 900000 -11148 112118 50002 9361 99087 35376 63551 -35080 9155 -48058 162839 25862 220496 -26011 115791 31898 900000 65890 13199 39651 -3036 40884 120007 4925 -38916 81577 -8718 56695 -5263 48946 -35167 34681 -32540 54028 5778 100168 -17668 30656 -2773 31963 41031 -5664 2645 10136 38712 -11496 31331 -19437 17387 -301 41733 -18806 49928 2425 15543 -2383 15608 -9561 5250 4509 -7941 10201 -1327 1769 -1099 6807 -19641 12620 2359 -3373 -7549 5130 -3444 1892 -4491 3800 4078 2944 2705 -3291 1307 93 -1043 -1340 3053 -4114 2352 -4964 5002 -3326 4878 -1787 1438 -2140 3360 -191 -173 -776 -1016 -323 -811 1981 -294 -1715 -336 3077 6355 9337 5417 -149 -3852 5864 217 128 -7297 6277 -2037 16109 -6572 4596 4505 900000 1079 900000 900000 13173 -451 5742 3528 2114 5439 1902 900000 -3734 3203 -7033 900000 -3917 900000 -6776 3342 -6133 900000 -1328 5442 4192 1280 5684 3746 4767 -6501 1010 -8906 7904 2282 10702 -4361 5620 3519 900000 5815 2038 4724 -536 4330 5825 652 -8071 5939 -1539 6054 -975 5939 -9465 5050 -10194 8391 1351 9724 -4677 4910 -552 4189 4979 -1210 603 2509 8267 -4109 8668 -8576 6076 -129 11748 -9493 12117 895 4828 -891 5227 -4687 2599 2626 -5974 6981 -1043 1296 -763 3998 -14395 6799 1477 -2390 -6119 4133 -3477 2067 -5777 4758 5186 3758 3427 -4456 1738 130 -1483 -1872 3912 -5411 2796 -6168 5536 -4052 5896 -2636 2387 -4207 6980 -451 -444 -2152 -2979 -967 -2461 5749 -834 -4604 -831 7123 SS 20251019T134133.2Z 9423.570524 103 1 48.10 2 83.32 113.32 66.63 126.41 0.00 1 0.00 1 0 17 4.718e-01 1.974e-02 3.532e-01 1.080e-02 9.104759e-01 6.617755e-03 1.037223e-02 -6.000000e+00 3.005415e-01 224.41 -2.00 3.69 -2.00 322.34 0.00e+00 1.258071e-02 4.056466e-03 2.453366e-03 -6.000000e+00 1.348193e-02 277.17 -2.00 20.00 -2.00 321.91 0.00e+00 7.831 0.010 302.00 328.00 3 2.5328e-01 2.6380e-02 9.6171e-02 -6.0000e+00 7.4069e-01 1.0542e+00 3.4503e-02 6.8257e-02 -6.0000e+00 8.0354e-01 -1.3629e+00 3.0288e-02 2.8643e-02 -6.0000e+00 4.7904e-01 5.4597e-01 1.3995e-02 1.5366e-02 -6.0000e+00 1.9645e-01 8.1416e-05 -1.5617e-03 3.4704e-04 2.9840e-04 -6.0000e+00 1.7479e-02 -3.5397e-04 0.0000e+00 12 9 8 11 8 0 18.83 18.39 0.27 -0.00035 -0.01209 123 30 1 5 0 390.990 21.79 14.99 18.39 7.46 30.6 872.59 -55762 -159803 -70893 -111574 -120900 -119427 -127424 -12434 -141270 70610 -56097 -119085 -138865 98821 -73008 48091 -8139 35907 20815 96920 -30803 -35240 -64580 34715 18780 -38516 -20339 -54807 6245 -76714 12967 10990 199295 35378 88500 21760 89524 -19334 77293 -15158 43779 12780 64115 6292 17843 52542 41032 50694 32145 61562 36664 54263 29551 47368 12505 52491 25406 44114 33411 17772 13517 11722 13433 24650 32857 19400 22436 15810 23326 12318 23838 13826 14674 6152 15010 -2832 2382 -428 3365 -1361 5921 2145 3034 -159 -212 2133 4376 3404 -362 1891 -737 -2809 -3602 -483 -4314 -4198 -3578 -2487 -244 -1795 -1192 -2975 -3216 -2790 -2494 -3316 -2479 -2367 -1138 -1331 105 -1621 390 -1405 -657 -2142 -495 -231 656 1054 1211 1962 2145 2604 1189 3055 16 1405 357 989 410 528 -152 300 -85 318 -142 346 607 145 -658 -794 -1964 -694 -6425 -1221 -2777 -3009 -2629 -2805 -131 -3381 743 -591 -2622 -4519 1041 -1957 506 -156 481 339 1021 -826 -945 -2225 475 297 -959 -450 -1521 105 -2937 259 266 2098 820 1211 573 1225 -855 1465 -814 1429 606 1890 338 864 1826 1642 1922 1557 2398 2007 2743 2085 2993 1172 3372 2140 3019 2463 1497 1210 1148 1443 2647 3529 2492 2882 2281 3389 2205 4116 2737 2843 1224 2497 -513 389 -74 627 -314 1502 653 1022 -60 -85 880 1838 1477 -163 808 -309 -1153 -1483 -204 -2139 -2445 -2441 -1935 -205 -1578 -1010 -2375 -2371 -1971 -1791 -2528 -2007 -2096 -1116 -1488 130 -2239 552 -2039 -931 -3038 -696 -335 978 1601 1819 2824 2957 3444 1543 3811 21 1905 551 1737 817 1159 -364 766 -232 909 -418 1022 1766 406 -1745 -1979 -4784 SS 20251019T135223.3Z 9423.578048 106 1 48.24 2 81.67 115.43 65.26 128.90 0.00 1 0.00 1 0 17 6.315e-01 1.251e-02 1.642e-01 3.962e-03 7.878666e-01 2.380391e-03 9.276286e-03 -6.000000e+00 4.022833e-01 224.41 -2.00 3.69 -2.00 321.96 0.00e+00 9.720434e-03 1.378954e-03 2.717435e-03 -6.000000e+00 1.804470e-02 277.17 -2.00 20.00 -2.00 321.51 0.00e+00 6.486 0.006 302.00 328.00 3 2.8132e-01 8.9733e-03 7.7537e-02 -6.0000e+00 9.9144e-01 4.3005e-01 1.2659e-02 4.7304e-02 -6.0000e+00 1.0755e+00 -5.3768e-01 1.2843e-02 2.7958e-02 -6.0000e+00 6.4119e-01 2.1338e-01 5.8724e-03 1.3481e-02 -6.0000e+00 2.6298e-01 3.3480e-04 -1.2289e-03 1.3338e-04 2.8183e-04 -6.0000e+00 2.3394e-02 -8.8162e-04 0.0000e+00 12 8 8 10 0 0 20.38 18.39 0.28 -0.00088 -0.01012 269 66 1 5 0 179.320 21.79 15.00 18.39 7.78 30.5 874.50 -239783 -193579 -206666 -199173 -190593 -39510 -219531 -206109 -215166 -199427 -171892 -160602 -135945 -131947 -78961 -99690 -11937 -87103 -44277 -76900 -13486 -52273 22365 -53180 -12343 -79169 -35251 -36445 -49415 -33836 -41739 -6294 -15163 6732 -24472 13793 -13082 26193 7633 19969 3697 12488 -2567 15375 10748 15411 2417 6175 10776 11158 17616 12686 17366 12296 21601 9545 13530 2851 16765 4864 17126 5434 16273 8450 13647 7986 9030 6526 6813 7513 4431 5400 2298 4791 -834 3507 -1997 2614 -2596 2227 -534 1026 -988 -1709 -1240 -156 -471 443 590 -319 -154 -1235 -144 -2572 -599 -1508 -311 -1113 221 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