File name: Pandora2s1_GreenbeltMD_20221007_L2Fit_fout2c9d20220412p1-8.txt File generation date: 20250301T104748.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20221007_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20221007 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1182 305.2592 305.4003 305.5413 305.6824 305.8234 305.9644 306.1054 306.2464 306.3874 306.5284 306.6693 306.8103 306.9512 307.0921 307.2330 307.3739 307.5148 307.6557 307.7966 307.9374 308.0783 308.2191 308.3600 308.5008 308.6416 308.7824 308.9231 309.0639 309.2047 309.3454 309.4862 309.6269 309.7676 309.9083 310.0490 310.1897 310.3303 310.4710 310.6116 310.7523 310.8929 311.0335 311.1741 311.3147 311.4553 311.5958 311.7364 311.8769 312.0175 312.1580 312.2985 312.4390 312.5795 312.7200 312.8604 313.0009 313.1413 313.2817 313.4222 313.5626 313.7030 313.8434 313.9837 314.1241 314.2644 314.4048 314.5451 314.6854 314.8257 314.9660 315.1063 315.2466 315.3868 315.5271 315.6673 315.8076 315.9478 316.0880 316.2282 316.3683 316.5085 316.6487 316.7888 316.9290 317.0691 317.2092 317.3493 317.4894 317.6295 317.7695 317.9096 318.0496 318.1897 318.3297 318.4697 318.6097 318.7497 318.8896 319.0296 319.1696 319.3095 319.4494 319.5893 319.7292 319.8691 320.0090 320.1489 320.2887 320.4286 320.5684 320.7083 320.8481 320.9879 321.1277 321.2674 321.4072 321.5470 321.6867 321.8264 321.9662 322.1059 322.2456 322.3852 322.5249 322.6646 322.8042 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7815 323.9210 324.0606 324.2001 324.3396 324.4791 324.6186 324.7581 324.8976 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221007T113952.1Z 8315.486019 170 1 50.13 2 84.93 101.41 126.49 286.74 0.00 1 0.00 1 0 17 6.487e-01 7.032e-02 5.587e-01 6.813e-02 1.020422e+00 4.057235e-02 1.142818e-02 -6.000000e+00 3.776201e-01 227.03 -2.00 3.47 -2.00 322.00 0.00e+00 -2.228637e-03 1.634404e-02 5.052978e-03 -6.000000e+00 1.906417e-02 286.18 -2.00 20.00 -2.00 321.42 0.00e+00 9.710 0.016 302.00 328.00 3 4.6925e-01 1.3943e-01 1.1349e-01 -6.0000e+00 9.4498e-01 2.3257e+00 1.6755e-01 6.4723e-02 -6.0000e+00 1.0359e+00 -2.1555e+00 1.0370e-01 2.8043e-02 -6.0000e+00 6.0725e-01 7.1243e-01 5.5427e-02 8.1924e-03 -6.0000e+00 2.5852e-01 5.4403e-06 -6.0038e-04 1.7343e-03 1.0649e-04 -6.0000e+00 1.7893e-02 2.7248e-02 -6.1962e-05 12 8 8 10 0 0 -44.86 22.61 0.89 0.02725 0.02274 23 4 1 5 0 2179.260 25.39 19.99 22.61 19.40 14.9 958.45 80746 900000 44248 -17854 -16894 233643 39485 900000 5120 -87314 900000 84155 900000 85322 9889 160467 900000 231255 55382 900000 44229 -69413 900000 272855 76468 900000 45534 900000 -67116 -111426 5388 900000 38583 900000 85532 153990 -16512 38833 31839 41387 10364 900000 61198 123458 77955 -38500 -38585 103164 72169 71367 900000 79720 900000 5981 -20314 57796 32758 97813 -3895 8005 16695 -38897 271661 -26648 -18128 83317 29152 81535 31773 5136 10078 11379 30383 162281 -17104 -5349 14966 4810 -28873 20899 -1669 2602 -4933 1192 -7165 11788 8261 14650 9889 3281 -8583 -13654 48045 -4294 6887 16424 -4996 2156 561 9287 -17956 -4756 -12138 -404 -4886 2815 -815 -5121 7325 7009 9128 -2174 -4341 -4004 4142 2934 5149 -3220 -2535 379 -1509 -52 -1124 9957 6210 9111 -13351 2784 -8140 6117 -1057 2990 -255 -1080 -1580 2081 -1102 339 211 854 -3134 3479 5349 900000 2931 -1577 -1212 15478 2616 900000 339 -11568 900000 5575 900000 5652 928 10630 900000 15320 3669 900000 2930 -11113 900000 18075 5066 900000 3016 900000 -8488 -25499 454 900000 2788 900000 5666 10201 -1790 2806 2876 3739 1311 900000 4423 8179 5164 -6492 -6506 6834 4781 4728 900000 5761 900000 1009 -4527 5917 4143 6480 -586 1012 2011 -9136 17996 -6901 -4258 7025 4389 7856 5740 1330 2549 2741 5489 10750 -3708 -934 2163 869 -8868 4657 -543 909 -1961 467 -3193 4472 3283 5382 3633 1185 -3256 -5879 11776 -2048 3513 9031 -4005 1814 491 7014 -15821 -3182 -8282 -260 -3463 1940 -632 -4647 6842 7662 10885 -3039 -6211 -5544 5103 3674 6584 -4714 -3796 534 -2029 -65 -1385 10620 6706 9295 -17954 3763 -14559 10860 -2234 6556 -624 -2883 -4489 5804 -3204 968 571 2111 -7391 7237 SS 20221007T115115.2Z 8315.493925 173 1 50.32 2 82.77 103.26 128.48 289.01 0.00 1 0.00 1 0 17 5.187e-01 1.797e-02 3.877e-01 9.733e-03 8.494977e-01 5.538534e-03 9.393981e-03 -6.000000e+00 2.925286e-01 227.03 -2.00 3.47 -2.00 322.26 0.00e+00 4.535793e-03 3.522389e-03 2.743290e-03 -6.000000e+00 1.313139e-02 286.18 -2.00 20.00 -2.00 321.79 0.00e+00 7.323 0.007 302.00 328.00 3 9.8131e-01 2.3636e-02 8.6307e-02 -6.0000e+00 7.2506e-01 6.9929e-01 3.4144e-02 4.8700e-02 -6.0000e+00 7.8711e-01 -9.4879e-01 3.2305e-02 2.6895e-02 -6.0000e+00 4.6993e-01 3.7182e-01 1.4458e-02 9.5223e-03 -6.0000e+00 2.0299e-01 6.3278e-05 -1.0354e-03 2.7023e-04 1.4685e-04 -6.0000e+00 1.3527e-02 2.6176e-02 -3.9724e-05 12 8 8 10 0 0 -10.58 22.52 0.36 0.02618 0.01839 116 22 1 5 0 433.780 25.39 20.00 22.52 19.62 14.9 961.02 -166328 -136572 -109918 54932 -107332 -259164 -130624 -114491 -29664 -161963 27887 -187099 -43735 -59680 -24250 -37647 -8921 -21303 154849 -65005 -44683 -46710 -85899 -52805 23478 42794 -25726 -108355 -79945 14606 -45971 162378 -23640 5554 -20050 49932 -6749 35979 12930 21221 16437 14455 60323 9870 57304 25070 40184 17685 15364 16169 51507 13671 38377 38509 35695 24506 27386 29686 13436 23120 -5114 28619 16989 16127 14360 13025 5370 14845 15350 19079 16320 9645 13591 5431 11339 -44 6150 -4551 125 -386 3306 -258 1049 -1410 599 105 1877 3466 2699 2064 -2687 -2408 -6012 -5154 -4054 -2305 -728 -202 -2503 -1583 -1762 -2032 -3027 -3282 -2367 -3646 -2158 -570 -684 -653 1005 -511 -254 -1131 483 -1218 514 82 449 820 1720 1543 933 1975 952 1428 927 813 265 491 304 359 -240 -196 250 71 361 89 -164 -409 -694 -1052 -2631 -1728 -1043 521 -1019 -9167 -1352 -1087 -282 -2655 265 -5165 -415 -772 -272 -552 -108 -312 1469 -1514 -810 -846 -2446 -1139 243 406 -422 -3833 -2207 189 -1348 1541 -734 125 -536 689 -186 776 424 732 638 599 1613 434 1582 973 1387 809 769 893 2266 967 2318 2492 2464 2140 2313 2338 1186 1843 -582 2662 2064 2189 1990 1817 841 2296 2739 3694 3423 2151 2734 1072 1862 -7 986 -911 29 -108 1048 -96 410 -601 267 49 896 1638 1250 899 -1150 -999 -2676 -2583 -2389 -1582 -579 -181 -2366 -1412 -1421 -1452 -2100 -2445 -1862 -3065 -1938 -560 -772 -848 1415 -756 -372 -1612 651 -1673 726 124 704 1267 2507 2160 1274 2578 1221 1767 1194 1210 462 966 657 827 -595 -525 708 206 1061 264 -466 -1081 -1707 -2465 SS 20221007T120153.2Z 8315.501310 176 1 50.00 2 80.77 105.00 130.30 291.21 0.00 1 0.00 1 0 25 6.236e-01 8.795e-03 1.701e-01 3.125e-03 7.298795e-01 1.700747e-03 8.201371e-03 -6.000000e+00 3.516643e-01 227.03 -2.00 3.47 -2.00 321.71 0.00e+00 3.910969e-03 9.749296e-04 2.692819e-03 -6.000000e+00 1.578853e-02 286.18 -2.00 20.00 -2.00 321.18 0.00e+00 5.920 0.004 302.00 328.00 3 8.5297e-01 6.5621e-03 7.0948e-02 -6.0000e+00 8.7163e-01 1.4921e-01 9.8339e-03 4.2267e-02 -6.0000e+00 9.4625e-01 -2.2683e-01 1.0258e-02 2.3763e-02 -6.0000e+00 5.6495e-01 8.4258e-02 4.6699e-03 8.0708e-03 -6.0000e+00 2.4401e-01 3.2371e-04 -8.0482e-04 8.5810e-05 1.1730e-04 -6.0000e+00 1.6264e-02 2.6319e-02 -6.3602e-05 11 9 0 11 8 0 19.06 22.62 0.26 0.02632 0.02027 297 57 1 5 0 168.340 25.39 19.98 22.62 20.15 14.9 964.46 -237964 -158997 -242218 -159470 -232193 -180420 -226361 -130287 -204840 -194268 -171743 -120223 -140894 -109223 -62792 -92602 -55031 -77909 21347 -57098 -25901 -70945 46454 -56492 -7730 -55299 -31783 -46240 -42854 -14793 -25945 3673 -14889 -3927 -33908 -4665 -29926 -9518 -7502 9828 -6741 8841 144 4797 6442 390 3884 5 10980 5131 8720 4390 7923 6772 5331 2443 6022 2407 5765 1653 5038 5615 5093 7037 4915 6074 1331 3961 2209 4979 1442 4304 1315 1956 -242 -1345 -2055 -1441 -900 -595 -439 -1944 -1077 -1096 128 -121 1064 503 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