File name: Pandora2s1_GreenbeltMD_20221008_L2Fit_fout2c9d20220412p1-8.txt File generation date: 20250301T104651.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20221008_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20221008 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1182 305.2592 305.4003 305.5413 305.6824 305.8234 305.9644 306.1054 306.2464 306.3874 306.5284 306.6693 306.8103 306.9512 307.0921 307.2330 307.3739 307.5148 307.6557 307.7966 307.9374 308.0783 308.2191 308.3600 308.5008 308.6416 308.7824 308.9231 309.0639 309.2047 309.3454 309.4862 309.6269 309.7676 309.9083 310.0490 310.1897 310.3303 310.4710 310.6116 310.7523 310.8929 311.0335 311.1741 311.3147 311.4553 311.5958 311.7364 311.8769 312.0175 312.1580 312.2985 312.4390 312.5795 312.7200 312.8604 313.0009 313.1413 313.2817 313.4222 313.5626 313.7030 313.8434 313.9837 314.1241 314.2644 314.4048 314.5451 314.6854 314.8257 314.9660 315.1063 315.2466 315.3868 315.5271 315.6673 315.8076 315.9478 316.0880 316.2282 316.3683 316.5085 316.6487 316.7888 316.9290 317.0691 317.2092 317.3493 317.4894 317.6295 317.7695 317.9096 318.0496 318.1897 318.3297 318.4697 318.6097 318.7497 318.8896 319.0296 319.1696 319.3095 319.4494 319.5893 319.7292 319.8691 320.0090 320.1489 320.2887 320.4286 320.5684 320.7083 320.8481 320.9879 321.1277 321.2674 321.4072 321.5470 321.6867 321.8264 321.9662 322.1059 322.2456 322.3852 322.5249 322.6646 322.8042 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7815 323.9210 324.0606 324.2001 324.3396 324.4791 324.6186 324.7581 324.8976 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221008T114038.4Z 8316.486556 213 1 49.65 2 84.98 101.87 113.91 283.59 0.00 1 0.00 1 0 17 6.310e-01 6.069e-02 4.500e-01 4.743e-02 1.016779e+00 2.838299e-02 1.149194e-02 -6.000000e+00 3.784709e-01 226.92 -2.00 3.47 -2.00 322.12 0.00e+00 -2.133599e-02 1.014397e-02 4.727624e-03 -6.000000e+00 1.843009e-02 286.06 -2.00 20.00 -2.00 321.53 0.00e+00 9.774 0.016 302.00 328.00 3 3.1725e-01 9.5942e-02 1.1943e-01 -6.0000e+00 9.2979e-01 2.1313e+00 1.1431e-01 8.8130e-02 -6.0000e+00 1.0081e+00 -2.4119e+00 6.6407e-02 2.5994e-02 -6.0000e+00 6.0517e-01 8.8606e-01 3.7810e-02 2.0225e-02 -6.0000e+00 2.6439e-01 7.9402e-06 1.0281e-03 1.2814e-03 2.1240e-04 -6.0000e+00 1.7754e-02 3.1312e-02 6.4314e-05 12 8 8 10 0 0 10.59 22.01 0.89 0.03131 0.03904 34 7 1 5 0 1460.080 24.96 19.97 22.01 14.47 14.6 923.99 59180 900000 54064 900000 -41423 900000 -19631 900000 -42903 227141 139824 145279 89350 900000 288058 117267 97867 32038 24050 -36759 181388 -12568 -5393 43387 900000 -18709 900000 -30793 900000 113794 142927 23288 67160 56302 -68515 900000 -61191 46468 42227 900000 28801 102499 42737 900000 -36290 900000 900000 153939 180607 -24271 74707 5652 192106 -12059 8060 -26805 900000 -12892 36661 -22502 900000 -1807 27470 46127 18328 31593 -38207 32058 13298 20590 5098 94457 -7464 36173 -15107 143674 -38019 24799 -5834 60498 17372 6131 49129 2838 3163 2844 23247 -4223 21083 -18176 19812 -15595 5065 3675 1316 1224 10869 2440 -3588 -6010 127 -2384 -12234 2399 -15668 5867 -10101 9604 -2035 10689 -6243 5682 743 -182 1102 1230 1386 -10555 6438 -2894 7351 -6513 13296 856 12611 -10705 2126 2472 1169 1871 -1826 -1826 -3531 127 271 2470 -798 4165 -2101 1692 -1362 -1822 6366 900000 4569 900000 -5729 900000 -2413 900000 -7582 10471 6446 6698 4462 900000 13280 5406 4888 3223 2217 -6162 8362 -1422 -633 3455 900000 -2666 900000 -3355 900000 5246 6589 1757 3378 2832 -10624 900000 -10002 3116 3539 900000 3138 5155 3582 900000 -5475 900000 900000 7097 8326 -3458 4383 711 8856 -2072 1182 -5729 900000 -2107 3227 -3301 900000 -242 3108 4640 2381 3575 -9127 4165 2396 3797 1132 8313 -1658 4548 -2723 6624 -7967 3118 -1198 8367 3931 1922 10645 1034 1210 1127 7609 -1791 6609 -7793 5480 -6111 1728 1474 643 705 6665 1822 -2894 -4682 83 -1407 -7727 1404 -11629 3705 -8149 7173 -1998 10791 -8318 7047 973 -234 1357 1526 1795 -16252 8608 -4122 8879 -8648 14098 998 12791 -13374 2490 3419 1935 3511 -3931 -4251 -9051 339 768 6968 -2350 11579 -5860 4166 -3171 -4041 SS 20221008T115148.2Z 8316.494308 216 1 50.28 2 82.86 103.68 115.89 285.57 0.00 1 0.00 1 0 17 6.583e-01 1.349e-02 3.520e-01 7.464e-03 8.514541e-01 4.253853e-03 9.280946e-03 -6.000000e+00 3.707559e-01 226.92 -2.00 3.47 -2.00 322.27 0.00e+00 4.039406e-03 2.743192e-03 1.856942e-03 -6.000000e+00 1.665923e-02 286.06 -2.00 20.00 -2.00 321.80 0.00e+00 7.401 0.007 302.00 328.00 3 5.5277e-01 1.8364e-02 8.6823e-02 -6.0000e+00 9.1875e-01 5.1665e-01 2.8269e-02 4.9356e-02 -6.0000e+00 9.9779e-01 -6.9011e-01 2.8845e-02 2.7574e-02 -6.0000e+00 5.9574e-01 2.6897e-01 1.2729e-02 1.0165e-02 -6.0000e+00 2.5708e-01 9.3065e-05 -8.7063e-04 2.0631e-04 1.4064e-04 -6.0000e+00 1.7171e-02 3.2900e-02 -4.6517e-05 12 8 8 10 0 0 8.57 22.03 0.34 0.03290 0.02636 161 31 1 5 0 312.270 24.96 19.97 22.03 14.70 14.6 926.15 -75590 -198244 -176317 -210844 -127871 -263496 -193648 -204401 -126811 -219879 -190450 -196194 -124574 -126978 -99156 -53692 -78187 -26432 -70052 -77688 -125604 72164 -76515 109733 -113377 -62320 -69522 8387 -98643 -65299 -69237 -2854 1279 -34063 23560 -19551 -11490 17611 40906 13435 41363 18010 49664 7494 41165 -16220 22101 24924 25495 11600 6737 35291 15206 16106 11609 21191 6907 20616 4135 19615 12078 27962 15989 23664 11309 5103 7164 14305 6653 11817 7785 4304 12825 -2186 5872 -1987 6179 -1806 1588 -3931 -296 -727 1201 -991 5 -286 738 1710 1677 639 -1812 993 -4225 -2218 -1317 -365 -346 214 -1873 -989 -1104 -2252 -1097 -2494 -1196 -3704 -979 -784 175 -156 733 -560 209 -579 -939 16 450 -598 366 330 1136 1740 525 999 853 910 450 960 -683 801 -110 -52 -201 -110 67 62 545 204 -187 191 -532 -1191 -550 -1967 -1400 -2092 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321.15 0.00e+00 5.984 0.004 302.00 328.00 3 4.0328e-01 5.1705e-03 7.0801e-02 -6.0000e+00 8.4645e-01 1.6775e-01 7.7027e-03 4.0489e-02 -6.0000e+00 9.1930e-01 -2.2749e-01 8.0436e-03 2.2986e-02 -6.0000e+00 5.4888e-01 8.3854e-02 3.6750e-03 8.5780e-03 -6.0000e+00 2.3684e-01 4.7324e-04 -8.1975e-04 6.7740e-05 1.1400e-04 -6.0000e+00 1.5821e-02 3.2885e-02 -7.4128e-05 11 8 0 10 0 0 3.48 22.18 0.23 0.03288 0.02672 407 78 1 5 0 122.500 24.96 20.06 22.18 15.09 14.6 928.41 -185438 -247838 -174509 -226489 -162937 -222164 -208563 -210801 -182704 -133362 -179783 -59426 -140451 -58318 -74575 -28721 -88833 16668 -90324 -21673 -64299 -38599 -40026 -44405 -31944 -46390 -19038 -48073 -21268 -53882 -4252 -29681 9286 -26115 -4768 -24271 3800 -13843 9313 328 4531 10424 1305 6529 -804 9582 -3440 8955 1058 8859 4607 10028 5367 6940 4412 7174 1402 842 1154 3429 4699 3698 7509 2648 6794 388 3321 2191 5911 2573 4623 1667 2776 -31 197 -1766 -1866 -1785 -1266 992 -1393 -121 -2566 -6 -1226 686 -71 1420 95 748 -146 -606 -961 -1040 -697 -951 717 -167 -46 -744 -825 -1579 -390 -1769 -1545 -1481 -569 -484 320 497 274 402 131 -181 -226 255 -269 1 1 293 302 875 336 873 34 168 414 305 250 1 29 -294 -10 -271 97 -218 509 60 7 -123 -181 -567 -1182 -3323 -1151 -2290 -824 -2149 -1971 -2317 -1687 -792 -1857 -235 -1667 -397 -754 -215 -1367 99 -1668 -210 -947 -450 -519 -654 -442 -775 -239 -782 -281 -1196 -78 -840 202 -796 -112 -745 103 -549 360 16 232 537 77 369 -50 558 -238 580 80 690 427 975 602 827 564 928 194 113 151 444 657 599 1354 549 1344 81 695 504 1525 774 1443 537 838 -9 50 -419 -445 -473 -402 366 -612 -59 -1359 -3 -734 425 -46 909 60 438 -81 -323 -525 -637 -499 -799 690 -181 -51 -783 -785 -1351 -322 -1598 -1480 -1493 -612 -571 423 742 444 662 211 -279 -333 373 -414 1 1 495 489 1354 507 1256 48 227 575 484 453 2 59 -618 -22 -653 246 -569 1340 158 17 -294 -407 -1223 SS 20221008T121239.4Z 8316.508789 224 1 49.34 2 78.96 107.14 119.54 289.42 0.00 1 0.00 1 0 25 3.631e-01 5.912e-03 6.245e-02 1.195e-03 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