File name: Pandora2s1_GreenbeltMD_20221009_L2Fit_fout2c9d20220412p1-8.txt File generation date: 20250301T104817.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20221009_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20221009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1182 305.2592 305.4003 305.5413 305.6824 305.8234 305.9644 306.1054 306.2464 306.3874 306.5284 306.6693 306.8103 306.9512 307.0921 307.2330 307.3739 307.5148 307.6557 307.7966 307.9374 308.0783 308.2191 308.3600 308.5008 308.6416 308.7824 308.9231 309.0639 309.2047 309.3454 309.4862 309.6269 309.7676 309.9083 310.0490 310.1897 310.3303 310.4710 310.6116 310.7523 310.8929 311.0335 311.1741 311.3147 311.4553 311.5958 311.7364 311.8769 312.0175 312.1580 312.2985 312.4390 312.5795 312.7200 312.8604 313.0009 313.1413 313.2817 313.4222 313.5626 313.7030 313.8434 313.9837 314.1241 314.2644 314.4048 314.5451 314.6854 314.8257 314.9660 315.1063 315.2466 315.3868 315.5271 315.6673 315.8076 315.9478 316.0880 316.2282 316.3683 316.5085 316.6487 316.7888 316.9290 317.0691 317.2092 317.3493 317.4894 317.6295 317.7695 317.9096 318.0496 318.1897 318.3297 318.4697 318.6097 318.7497 318.8896 319.0296 319.1696 319.3095 319.4494 319.5893 319.7292 319.8691 320.0090 320.1489 320.2887 320.4286 320.5684 320.7083 320.8481 320.9879 321.1277 321.2674 321.4072 321.5470 321.6867 321.8264 321.9662 322.1059 322.2456 322.3852 322.5249 322.6646 322.8042 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7815 323.9210 324.0606 324.2001 324.3396 324.4791 324.6186 324.7581 324.8976 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221009T114139.0Z 8317.487256 252 1 49.90 2 84.98 102.37 101.45 281.12 0.00 1 0.00 1 0 25 4.661e-01 4.409e-02 5.299e-01 4.839e-02 1.017761e+00 2.892423e-02 1.104910e-02 -6.000000e+00 2.702206e-01 226.82 -2.00 3.47 -2.00 322.44 0.00e+00 -3.285362e-03 1.419963e-02 4.000546e-03 -6.000000e+00 1.302374e-02 285.95 -2.00 20.00 -2.00 321.93 0.00e+00 9.776 0.016 302.00 328.00 3 2.2508e-01 1.1129e-01 1.1338e-01 -6.0000e+00 6.7122e-01 2.0087e+00 1.3724e-01 6.2972e-02 -6.0000e+00 7.3095e-01 -2.2049e+00 8.8043e-02 2.8893e-02 -6.0000e+00 4.3655e-01 7.9058e-01 4.5962e-02 8.6316e-03 -6.0000e+00 1.9078e-01 8.4419e-06 -1.8128e-03 1.2818e-03 1.1287e-04 -6.0000e+00 1.2459e-02 3.7313e-02 -1.6573e-04 12 8 8 10 0 0 99.18 21.68 0.78 0.03731 0.02369 39 7 1 5 0 1279.270 24.75 20.05 21.68 12.26 14.4 908.52 900000 900000 18604 10061 161097 -74586 900000 66633 900000 -82019 -41515 -26867 900000 -69816 -38961 -25335 110878 900000 900000 900000 193365 61651 121508 900000 53420 94998 -5014 160300 158217 -21149 -23939 398 28325 27550 116188 14976 -53656 -24848 11994 74787 -17960 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-1114 5317 -500 3953 5121 3532 5096 964 1048 3890 8278 -6473 4566 -3470 1275 -3964 198 -6612 2016 -1204 -8189 -5603 -2105 1996 1925 7719 -12202 4029 -732 5528 1263 -2583 3646 -2200 -9622 3777 1280 -7847 1338 -3090 -1770 9964 4772 2783 8332 -2377 -1842 -4056 1341 -132 -782 -2651 3794 5823 -380 1081 978 1199 -1238 3457 370 -1039 -9661 SS 20221009T115251.5Z 8317.495041 255 1 50.23 2 82.86 104.19 103.48 282.96 0.00 1 0.00 1 0 17 6.173e-01 1.377e-02 3.493e-01 7.064e-03 8.648360e-01 4.049746e-03 9.487883e-03 -6.000000e+00 3.473924e-01 226.82 -2.00 3.47 -2.00 322.29 0.00e+00 4.924545e-03 2.621080e-03 2.424587e-03 -6.000000e+00 1.590312e-02 285.95 -2.00 20.00 -2.00 321.83 0.00e+00 7.399 0.007 302.00 328.00 3 4.3637e-01 1.7461e-02 8.7308e-02 -6.0000e+00 8.6076e-01 5.7853e-01 2.6460e-02 4.9872e-02 -6.0000e+00 9.3512e-01 -7.5873e-01 2.6939e-02 2.7837e-02 -6.0000e+00 5.5830e-01 2.9186e-01 1.1964e-02 1.0008e-02 -6.0000e+00 2.4117e-01 1.0169e-04 -1.2011e-03 1.9456e-04 1.4801e-04 -6.0000e+00 1.6132e-02 3.5590e-02 -6.9571e-05 12 8 8 10 0 0 19.56 21.63 0.29 0.03559 0.02656 180 35 1 5 0 279.000 24.75 19.97 21.63 12.66 14.5 912.27 -113030 -117227 -193497 -162721 -162372 -200703 -205654 -143520 -227680 -133200 -234829 900000 -149814 75974 -113380 44136 -54696 -100654 -114411 -113446 -85588 -132248 -62145 -82409 -21607 -30659 -22875 -107397 54586 -38082 35449 -9178 -10661 -33611 42862 -17912 -30414 -1467 23293 76355 -1909 39757 24710 55687 -11835 75209 -11299 25418 -4441 27280 3985 20480 13053 21348 24519 10085 26464 10045 27262 11899 29314 7224 15942 4901 8790 9519 15700 7719 13013 8375 9863 9086 4169 5864 389 7076 -2035 4289 606 5252 67 970 -842 2522 -1310 1828 -129 1757 794 729 7 -1497 810 -3719 -2546 -2192 1167 -1722 -97 -2342 -1024 -2799 -2418 -2425 -2776 -2132 -2637 -550 -1272 240 36 454 -1081 766 -1159 573 -381 752 119 1070 1274 1122 830 1381 948 -247 1421 -12 529 214 588 -217 165 -428 -36 56 309 -106 31 -9 -803 -461 -778 -807 -2059 -1121 -1118 -1885 -2189 -988 -3564 -917 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302.00 328.00 3 3.6930e-01 5.1248e-03 7.1289e-02 -6.0000e+00 8.7461e-01 1.3755e-01 7.7659e-03 4.1829e-02 -6.0000e+00 9.5009e-01 -2.0323e-01 8.1814e-03 2.2892e-02 -6.0000e+00 5.6728e-01 7.4567e-02 3.7160e-03 7.2714e-03 -6.0000e+00 2.4471e-01 4.9416e-04 -6.7614e-04 6.6360e-05 9.6266e-05 -6.0000e+00 1.6363e-02 3.5269e-02 -7.4461e-05 11 8 0 10 0 0 4.55 21.75 0.26 0.03527 0.03019 433 83 1 5 0 114.970 24.86 19.97 21.75 13.30 14.5 916.86 -198275 -152921 -215035 -154842 -243526 -166855 -237698 -212922 -227577 -175822 -193579 -130918 -143569 -77101 -88831 -83394 -35406 -51192 -15837 -69213 -42688 -45261 -26375 -63764 -24608 -60561 -12442 -64679 -25137 -21524 -21485 -13844 -23939 -8188 -24804 -13044 -22030 2254 -2933 12246 -1793 6277 -3061 7303 462 1004 3905 2408 4749 -336 5702 3723 10439 2420 7466 3508 5877 3137 4822 1559 1387 4856 4660 5286 4016 3165 1559 3530 3125 3992 2609 3413 1842 2519 -324 -632 -3070 -669 -1280 -901 -296 -1264 -1363 -1304 -191 -267 709 425 865 134 916 -785 -721 -976 -593 -25 503 126 -407 -251 -1495 -1457 -1167 -1403 -1784 -1096 -1019 205 126 356 410 191 130 -101 40 -309 66 82 156 8 566 473 507 537 416 54 700 170 87 -72 -22 -173 -167 10 -171 47 366 63 -125 103 -299 -474 -1198 -660 -1763 -635 -2312 -792 -2615 -2113 -2946 -1441 -2088 -960 -1580 -566 -920 -954 -283 -530 -123 -956 -451 -508 -273 -1059 -297 -1097 -137 -1158 -320 -320 -433 -309 -670 -192 -659 -334 -727 72 -123 511 -94 323 -179 390 27 60 237 158 327 -27 499 369 1070 291 898 459 757 403 591 200 194 754 838 1034 790 623 323 784 813 1162 816 1059 550 683 -81 -145 -729 -173 -401 -335 -127 -614 -705 -721 -112 -165 449 272 533 78 493 -415 -391 -596 -423 -21 483 135 -447 -260 -1419 -1234 -966 -1256 -1703 -1094 -1095 240 167 532 662 315 210 -156 59 -455 101 133 265 13 909 731 759 772 580 73 970 270 158 -146 -45 -366 -376 25 -437 122 969 168 -319 247 -672 -1023 SS 20221009T121347.5Z 8317.509578 263 1 49.60 2 78.95 107.67 107.21 286.48 0.00 1 0.00 1 0 17 4.031e-01 5.701e-03 5.652e-02 1.214e-03 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