File name: Pandora2s1_GreenbeltMD_20221018_L2Fit_fout2c9d20220412p1-8.txt File generation date: 20250301T104644.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v9d20220412.txt Level 1 file used: Pandora2s1_GreenbeltMD_20221018_L1_smca1c9d20220412p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20221018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1182 305.2592 305.4003 305.5413 305.6824 305.8234 305.9644 306.1054 306.2464 306.3874 306.5284 306.6693 306.8103 306.9512 307.0921 307.2330 307.3739 307.5148 307.6557 307.7966 307.9374 308.0783 308.2191 308.3600 308.5008 308.6416 308.7824 308.9231 309.0639 309.2047 309.3454 309.4862 309.6269 309.7676 309.9083 310.0490 310.1897 310.3303 310.4710 310.6116 310.7523 310.8929 311.0335 311.1741 311.3147 311.4553 311.5958 311.7364 311.8769 312.0175 312.1580 312.2985 312.4390 312.5795 312.7200 312.8604 313.0009 313.1413 313.2817 313.4222 313.5626 313.7030 313.8434 313.9837 314.1241 314.2644 314.4048 314.5451 314.6854 314.8257 314.9660 315.1063 315.2466 315.3868 315.5271 315.6673 315.8076 315.9478 316.0880 316.2282 316.3683 316.5085 316.6487 316.7888 316.9290 317.0691 317.2092 317.3493 317.4894 317.6295 317.7695 317.9096 318.0496 318.1897 318.3297 318.4697 318.6097 318.7497 318.8896 319.0296 319.1696 319.3095 319.4494 319.5893 319.7292 319.8691 320.0090 320.1489 320.2887 320.4286 320.5684 320.7083 320.8481 320.9879 321.1277 321.2674 321.4072 321.5470 321.6867 321.8264 321.9662 322.1059 322.2456 322.3852 322.5249 322.6646 322.8042 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7815 323.9210 324.0606 324.2001 324.3396 324.4791 324.6186 324.7581 324.8976 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221018T115016.3Z 8326.493245 266 1 49.85 2 85.14 106.66 14.85 181.94 0.00 1 0.00 1 0 17 6.718e-01 4.229e-02 5.662e-01 4.281e-02 9.750634e-01 2.512033e-02 1.091691e-02 -6.000000e+00 3.876823e-01 225.95 -2.00 3.47 -2.00 322.45 0.00e+00 8.882398e-03 1.261042e-02 4.007205e-03 -6.000000e+00 1.778818e-02 284.89 -2.00 20.00 -2.00 321.98 0.00e+00 10.011 0.018 302.00 328.00 3 -9.8647e-02 9.6639e-02 1.1207e-01 -6.0000e+00 9.6511e-01 1.8817e+00 1.2008e-01 5.1174e-02 -6.0000e+00 1.0546e+00 -1.9984e+00 8.1682e-02 2.8732e-02 -6.0000e+00 6.2598e-01 7.0660e-01 4.2140e-02 1.2071e-02 -6.0000e+00 2.6810e-01 9.6985e-06 -2.1280e-04 1.1475e-03 2.0516e-04 -6.0000e+00 1.8351e-02 3.6878e-02 -9.6508e-05 12 8 8 10 0 0 22.57 21.74 0.77 0.03688 0.03528 43 8 1 5 0 1159.150 24.75 20.06 21.74 11.02 14.5 901.82 -28512 900000 22277 -11787 -30870 11485 -21591 114270 900000 -97481 175797 -43018 -26901 -56624 -54222 -37015 900000 -10480 900000 122380 87791 1286 900000 99312 -37009 -108275 -818 31573 -79485 235129 254330 47978 17074 900000 44175 73373 122568 900000 17790 187080 -13855 23434 50772 55829 900000 -24017 56321 -12986 236743 -58225 106079 -3943 30116 25234 343534 13474 130807 47359 -2323 -14952 34397 16351 52312 125453 -9519 42221 15591 120104 40497 14288 28059 89153 10385 35739 471 23983 13512 -67 -14106 -4270 4979 19077 8784 12681 20482 -10579 8741 -7587 32226 -16457 582 19881 7982 -2588 548 -3548 -1695 -7974 967 -2955 -6894 -4035 -9529 -2770 251 2800 -4475 5713 -2186 -2973 -2117 2897 1455 -1257 -3869 -3603 -282 -831 3466 1527 5118 -1196 6175 320 1647 1526 -962 -2063 1865 -149 315 700 -531 680 603 -3 248 857 -1241 1690 -2805 -1165 -1683 900000 928 -491 -1287 479 -900 4762 900000 -5078 7327 -1793 -1121 -3933 -4331 -2700 900000 -675 900000 5100 3659 54 900000 4139 -2103 -11897 -34 1316 -5722 9800 10600 2000 841 900000 1841 3058 5108 900000 1011 7797 -1207 1421 2308 2327 900000 -2184 2347 -1132 9867 -9265 4421 -433 2510 2295 14318 1378 5452 3050 -229 -1643 2476 1611 4162 5229 -1515 3999 2008 5916 5063 2544 4465 7431 1731 4062 66 2453 1587 -10 -3100 -1121 1390 5168 2782 4069 6402 -4673 3242 -3289 8999 -6927 194 5386 2595 -1089 270 -2174 -1208 -6813 770 -2303 -4971 -2472 -5957 -1732 161 1855 -3487 4548 -2205 -3519 -2753 3731 1898 -1634 -5015 -4731 -377 -1185 4882 2132 6484 -1545 7206 384 1908 1730 -1195 -3078 3164 -295 683 1633 -1355 1857 1743 -10 743 2540 -3557 4338 -6944 -2699 SS 20221018T120128.5Z 8326.501024 269 1 50.13 2 83.06 108.49 15.12 191.59 0.00 1 0.00 1 0 25 6.719e-01 1.318e-02 3.350e-01 6.456e-03 8.496143e-01 3.690917e-03 9.232841e-03 -6.000000e+00 3.786913e-01 225.95 -2.00 3.47 -2.00 322.25 0.00e+00 4.582799e-03 2.351655e-03 1.264360e-03 -6.000000e+00 1.757030e-02 284.89 -2.00 20.00 -2.00 321.79 0.00e+00 7.582 0.008 302.00 328.00 3 1.5642e-01 1.5694e-02 8.8307e-02 -6.0000e+00 9.3541e-01 5.3020e-01 2.4228e-02 5.0136e-02 -6.0000e+00 1.0173e+00 -6.5963e-01 2.5162e-02 2.7156e-02 -6.0000e+00 6.0640e-01 2.5155e-01 1.1155e-02 1.0526e-02 -6.0000e+00 2.6237e-01 1.1559e-04 -1.0877e-03 1.7935e-04 1.3718e-04 -6.0000e+00 1.7691e-02 3.6130e-02 -9.2764e-05 12 8 8 10 0 0 -9.72 21.68 0.31 0.03613 0.02796 194 37 1 5 0 258.380 24.75 20.06 21.68 11.55 14.5 906.30 -218913 -214629 900000 -272802 900000 -255451 -38948 -223575 -181712 -233224 -106412 -150452 -190364 -11594 136586 -18821 -93444 10939 -43418 16842 -77865 244642 -72986 -62174 -99463 58873 -88807 -39448 -88914 -25487 -47867 -42926 -33341 -9152 -18264 -28805 15277 -29118 48017 2944 44425 14529 34692 -18465 43578 -1852 12853 -3336 27413 17668 14213 16570 12897 37616 14356 11187 5521 15581 5567 14503 3914 7274 9285 17275 6273 11987 5960 7489 10021 8249 8984 1576 9869 1401 7907 -2062 4728 -4594 2277 -1014 3129 -1796 680 1009 763 2422 318 3104 301 3615 -2108 -272 -4121 -749 -3408 -672 -1518 113 -1008 -1109 -1409 -2576 -1973 -1391 -2350 -2409 -920 -1796 70 -711 448 -190 322 -1354 309 -89 247 -276 583 866 240 1625 208 2133 880 392 224 939 -154 622 -5 35 33 57 -27 -171 364 128 -17 -635 112 -936 -2254 -2333 900000 -4682 900000 -3507 -245 -2686 -1559 -3469 -670 -1377 -3485 -73 859 -118 -1390 69 -447 106 -1114 1539 -1086 -889 -2162 370 -1727 -451 -1780 -335 -986 -1007 -801 -168 -345 -643 253 -916 852 94 1017 474 953 -866 1122 -77 485 -158 1035 912 868 1095 974 2391 1202 1000 521 1275 483 1159 379 787 1151 2185 888 1607 889 1206 1835 1728 1967 369 1993 279 1304 -348 762 -922 521 -288 1000 -679 267 422 341 1119 155 1475 143 1547 -897 -111 -1823 -366 -2037 -463 -1240 103 -943 -984 -1128 -1845 -1363 -1027 -1860 -2014 -823 -1803 79 -932 637 -280 468 -1922 415 -121 350 -418 908 1322 351 2244 283 2743 1115 484 290 1398 -269 1218 -11 81 81 151 -77 -491 1058 372 -47 -1655 268 -2169 SS 20221018T121201.5Z 8326.508351 272 1 49.77 2 81.13 110.25 15.69 200.22 0.00 1 0.00 1 0 17 5.758e-01 7.429e-03 1.303e-01 2.276e-03 7.263592e-01 1.231098e-03 8.051526e-03 -6.000000e+00 3.229290e-01 225.95 -2.00 3.47 -2.00 321.65 0.00e+00 3.013600e-03 6.900555e-04 1.570562e-03 -6.000000e+00 1.449707e-02 284.88 -2.00 20.00 -2.00 321.13 0.00e+00 6.134 0.004 302.00 328.00 3 1.3061e-01 4.6529e-03 7.1753e-02 -6.0000e+00 7.9875e-01 1.6028e-01 6.9936e-03 4.0077e-02 -6.0000e+00 8.6842e-01 -1.9258e-01 7.4219e-03 2.2339e-02 -6.0000e+00 5.1855e-01 6.8756e-02 3.3954e-03 7.8977e-03 -6.0000e+00 2.2387e-01 5.4202e-04 -9.0925e-04 6.2084e-05 1.0018e-04 -6.0000e+00 1.5016e-02 3.5479e-02 -9.1291e-05 11 8 0 10 0 0 -0.75 21.86 0.24 0.03548 0.02865 456 88 1 5 0 109.130 24.86 19.83 21.86 12.24 14.5 910.92 -246804 -140464 -209883 -172447 -246849 -167185 -200426 -133198 -167858 -148124 -110897 -128389 -94527 -108727 -62948 -94748 -28118 -85896 -20778 -68648 -9932 -66099 -26353 -54763 -24050 -68716 -30184 -38921 -41088 -8162 -22270 -6600 -17072 293 -30262 -1903 -18343 -5633 -5883 1514 -4229 5318 -475 4982 3928 1614 4317 -1495 9360 638 7727 2604 9103 3347 6665 1384 2978 -721 2541 2700 3303 5009 6560 5115 2868 3638 1447 4894 2274 4562 2024 2402 1736 1262 -1074 -1532 -2454 -1905 -339 -830 -631 -1600 -1682 -1034 214 -520 244 359 957 -153 246 -718 -866 -327 -170 -180 258 247 -388 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