File name: Pandora2s1_GreenbeltMD_20230120_L2Fit_fout2c14d20221101p1-8.txt File generation date: 20250301T104539.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 2 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora2_OF_v1d20210816.txt Instrument calibration file used: Pandora2s1_CF_v14d20221101.txt Level 1 file used: Pandora2s1_GreenbeltMD_20230120_L1_smca1c14d20221101p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20230120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New VP starting 20221101 with March 2023 ref period First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0155 305.1566 305.2976 305.4387 305.5797 305.7207 305.8617 306.0027 306.1437 306.2847 306.4256 306.5666 306.7075 306.8485 306.9894 307.1303 307.2712 307.4121 307.5529 307.6938 307.8347 307.9755 308.1163 308.2571 308.3979 308.5387 308.6795 308.8203 308.9611 309.1018 309.2426 309.3833 309.5240 309.6647 309.8054 309.9461 310.0868 310.2274 310.3681 310.5087 310.6493 310.7900 310.9306 311.0712 311.2117 311.3523 311.4929 311.6334 311.7740 311.9145 312.0550 312.1955 312.3360 312.4765 312.6170 312.7574 312.8979 313.0383 313.1787 313.3192 313.4596 313.5999 313.7403 313.8807 314.0211 314.1614 314.3017 314.4421 314.5824 314.7227 314.8630 315.0033 315.1435 315.2838 315.4240 315.5643 315.7045 315.8447 315.9849 316.1251 316.2653 316.4054 316.5456 316.6857 316.8259 316.9660 317.1061 317.2462 317.3863 317.5264 317.6664 317.8065 317.9465 318.0865 318.2266 318.3666 318.5066 318.6466 318.7865 318.9265 319.0664 319.2064 319.3463 319.4862 319.6261 319.7660 319.9059 320.0458 320.1856 320.3255 320.4653 320.6052 320.7450 320.8848 321.0246 321.1643 321.3041 321.4439 321.5836 321.7233 321.8631 322.0028 322.1425 322.2822 322.4218 322.5615 322.7012 322.8408 322.9804 323.1201 323.2597 323.3993 323.5388 323.6784 323.8180 323.9575 324.0971 324.2366 324.3761 324.5156 324.6551 324.7946 324.9341 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230120T125528.6Z 8420.538526 60 1 50.41 2 85.19 120.80 80.01 139.46 0.00 1 0.00 1 0 17 5.861e-01 5.365e-02 5.776e-01 5.776e-02 1.057775e+00 3.653696e-02 1.145202e-02 -6.000000e+00 3.455081e-01 224.08 -2.00 3.47 -2.00 322.51 0.00e+00 -3.516729e-03 1.856641e-02 4.564164e-03 -6.000000e+00 2.344816e-02 276.45 -2.00 20.00 -2.00 322.11 0.00e+00 10.117 0.018 302.00 328.00 3 4.3967e-01 1.3771e-01 1.1662e-01 -6.0000e+00 8.4274e-01 1.9626e+00 1.5691e-01 5.8712e-02 -6.0000e+00 9.1850e-01 -2.1726e+00 1.0109e-01 2.7798e-02 -6.0000e+00 5.5128e-01 8.0741e-01 5.8054e-02 8.5520e-03 -6.0000e+00 2.4392e-01 4.7706e-06 -2.2672e-03 1.6121e-03 1.6778e-04 -6.0000e+00 1.6675e-02 6.9920e-03 -5.0918e-05 12 9 8 11 8 0 95.86 21.82 1.20 0.00699 -0.01005 35 7 1 5 0 1440.200 24.75 20.03 21.82 13.56 15.3 960.23 -53986 222912 -37251 900000 900000 -58073 900000 48379 -34028 900000 900000 900000 900000 900000 49031 900000 120091 -104141 -56954 32091 -21466 900000 61544 900000 900000 900000 -68156 900000 -62667 900000 -37734 141102 153842 -19045 41288 900000 69616 108031 72860 900000 -10364 900000 900000 259433 900000 900000 900000 900000 900000 -56066 106595 -10345 900000 74262 160965 38315 20133 -4383 900000 -51775 68459 -18401 99010 37573 18280 123105 34912 19061 -17090 46961 73108 55093 -22082 17285 44488 -7339 148815 -4936 4810 33731 71497 64417 28134 -5438 36980 12068 31430 -6081 -1080 11580 13647 -9237 -13139 14157 -25223 -14183 -502 276 1946 4620 -7115 -6011 -6564 -7502 -260 -4248 9931 -1987 3448 1149 1163 3026 -2759 -8237 2070 1959 4334 6127 -6607 -6529 6385 6541 -2701 4661 3783 1087 -1305 223 63 3794 -1295 -390 -1145 1410 -392 -1577 1822 665 1585 1433 -2494 2438 -5179 -3779 12483 -2260 900000 900000 -3252 900000 2709 -1906 900000 900000 900000 900000 900000 2746 900000 6725 -14094 -4784 1797 -1202 900000 3447 900000 900000 900000 -5205 900000 -3509 900000 -2113 7902 8615 -1164 2312 900000 3899 6050 4080 900000 -791 900000 900000 14529 900000 900000 900000 900000 900000 -6565 5969 -948 900000 4159 9014 2731 1742 -469 900000 -7380 3834 -1874 5545 2869 1861 6894 3022 2038 -2871 4782 6327 5890 -4947 2376 4077 -971 8334 -603 612 3950 6916 7871 5586 -1606 7531 3318 7360 -2105 -387 3502 3745 -3000 -4415 3885 -12006 -7307 -270 175 1373 3260 -5339 -3972 -3786 -4159 -143 -2569 5506 -1358 2530 1016 1212 3474 -3538 -11256 2492 2293 4999 7275 -9399 -9543 7938 7582 -3267 5090 4047 1168 -1403 251 85 5864 -2421 -803 -2578 3347 -1027 -4426 5020 1870 4386 3748 -6202 5270 -11370 SS 20230120T131531.3Z 8420.552446 66 1 50.65 2 81.90 124.19 77.67 143.09 0.00 1 0.00 1 0 17 7.694e-01 8.605e-03 2.373e-01 3.440e-03 8.154238e-01 1.888802e-03 8.777455e-03 -6.000000e+00 4.280126e-01 224.08 -2.00 3.47 -2.00 322.00 0.00e+00 3.858166e-03 1.061290e-03 1.550908e-03 -6.000000e+00 1.863356e-02 276.45 -2.00 20.00 -2.00 321.55 0.00e+00 6.652 0.005 302.00 328.00 3 3.6990e-01 7.0788e-03 7.8968e-02 -6.0000e+00 1.0573e+00 2.4409e-01 1.1539e-02 4.6712e-02 -6.0000e+00 1.1524e+00 -3.0450e-01 1.3372e-02 2.7121e-02 -6.0000e+00 6.8596e-01 1.1337e-01 6.0398e-03 1.0175e-02 -6.0000e+00 2.9290e-01 2.4145e-04 -7.2506e-04 9.4470e-05 1.3125e-04 -6.0000e+00 1.9883e-02 4.3662e-03 -1.6830e-05 11 8 0 10 0 0 17.36 21.63 0.29 0.00437 -0.00108 350 67 1 5 0 143.870 24.75 19.97 21.63 13.74 15.3 962.00 -310359 -198545 -270043 -184592 -267157 -256006 -235583 -237869 -210960 -214081 -234756 -212671 -155407 -102242 -80022 -85907 4375 -89346 -54087 -81390 -75071 -92323 -84162 -32053 -41468 -93704 -77710 -47656 -79289 -35975 -46799 -39905 -28166 7823 -19166 -21705 -31108 7557 -21767 3668 3689 10501 2573 -3194 -2590 6669 6442 2891 2652 6544 6739 3746 7747 6062 12479 4751 9469 1971 4522 2611 6854 4067 6676 7866 8151 6825 1668 4633 1826 3211 3979 5677 2538 3612 421 330 -1426 -2715 -1966 -2103 370 -286 42 -1868 -182 98 661 550 1054 797 381 -386 -731 -1749 -1101 -743 -297 760 -73 -302 -97 -923 -2174 -1002 -1897 -1429 -1854 -1089 -727 -43 557 228 210 125 -456 -470 404 17 17 410 583 383 953 257 494 264 73 578 489 79 248 37 -365 -132 -320 -114 -60 585 79 30 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321.08 0.00e+00 5.658 0.003 302.00 328.00 3 2.8689e-01 2.9890e-03 6.7056e-02 -6.0000e+00 7.0965e-01 1.1756e-01 4.5357e-03 3.8869e-02 -6.0000e+00 7.7349e-01 -1.2452e-01 5.1796e-03 2.2451e-02 -6.0000e+00 4.6042e-01 4.0327e-02 2.4250e-03 9.0977e-03 -6.0000e+00 1.9661e-01 7.2748e-04 -6.3490e-04 4.5077e-05 9.4201e-05 -6.0000e+00 1.3345e-02 4.0458e-03 -1.0624e-05 10 0 0 10 0 0 21.38 21.77 0.25 0.00405 -0.00073 636 122 1 5 0 79.070 24.75 20.06 21.77 14.28 15.4 966.49 -102084 -229356 -137617 -219545 -157547 -200422 -91918 -167713 -87243 -170540 -142113 -119402 -103940 -99823 -94415 -64944 -62619 -42999 -59779 -11303 -52163 -24733 -48104 -33639 -33821 -19323 -31666 -48242 -30370 -37028 -20436 -21667 -9855 -15246 -8859 -27711 -3423 -12191 1945 -5948 2062 -7045 1020 -2720 -391 2658 297 394 -2207 428 507 3596 1522 5783 2544 3380 967 2915 140 1375 1196 3156 3052 4819 4262 2513 2519 -309 2567 2498 2951 2343 1703 1029 865 -757 -1150 -2581 -1450 -691 -812 -486 -1748 -1452 -1232 -416 -245 700 810 971 678 245 -800 -977 -731 -533 -50 839 358 -191 -48 -977 -877 -664 -897 -1422 -825 -866 -106 212 449 330 76 133 -213 123 -92 257 -21 168 2 412 557 319 312 67 -249 560 347 111 125 -152 -255 -325 -151 -92 -36 370 240 -80 73 -282 -298 -208 -2072 -561 -2079 -735 -1372 -228 -1002 -267 -1342 -890 -661 -636 -785 -922 -596 -657 -420 -766 -96 -692 -249 -631 -421 -463 -245 -475 -843 -477 -665 -380 -503 -243 -450 -240 -870 -92 -418 71 -291 108 -439 63 -180 -26 175 21 29 -175 36 47 370 177 711 348 480 146 435 21 197 175 496 552 989 959 570 566 -74 650 737 975 822 600 345 265 -210 -297 -681 -422 -240 -336 -232 -943 -829 -749 -269 -166 485 564 654 427 145 -460 -576 -483 -411 -44 867 413 -224 -53 -982 -786 -584 -853 -1440 -874 -987 -132 297 642 509 119 202 -310 170 -127 370 -32 268 4 620 888 493 462 97 -345 800 567 189 234 -310 -547 -740 -369 -236 -94 985 642 -206 175 -636 -645 SS 20230120T133318.9Z 8420.564803 74 1 50.30 2 79.10 127.32 75.75 146.45 0.00 1 0.00 1 0 17 3.693e-01 5.259e-03 7.733e-02 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