File name: Pandora71s1_GreenbeltMD_20251006_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20251007T050257.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20251006_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20251006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20251006T112005.1Z 9410.472282 210 1 54.09 2 88.58 98.01 101.07 282.14 0.00 1 0.00 1 0 99 1.664e-02 1.634e-02 2.989e-04 2.977e-04 1.881765e+04 2.020069e+01 7.100799e+02 -6.000000e+00 8.598575e+02 286.30 -2.00 20.00 -2.00 505.47 0.00e+00 3.536036e-03 8.124265e-06 3.963136e-05 -6.000000e+00 4.558808e-04 286.30 -2.00 20.00 -2.00 501.07 0.00e+00 1.460879e+00 5.270659e-03 1.066721e-01 -6.000000e+00 3.138976e-01 227.13 -2.00 3.47 -2.00 502.59 0.00e+00 17.538 0.095 489.00 513.00 1 1.7664e+00 4.0544e-04 2.9259e-02 -6.0000e+00 2.4017e-02 -4.5814e-02 9.6317e-05 1.9301e-03 -6.0000e+00 6.3455e-03 2.3629e-02 9.6898e-02 1.8885e-05 5.6874e-05 -6.0000e+00 1.1309e-03 1.1019e-02 1.5774e-04 12 13 9 12 4 4 90.80 50.56 3.11 0.01102 0.68315 352 38 1 2 0 153.308 20.02 50.56 18.86 28.00 28.25 12.5 981.60 2632 2776 2519 1125 974 1282 -302 -1541 -1467 -1535 -1500 -366 1784 770 -266 539 -51 270 1702 1445 1617 2478 724 -3711 -2655 -2259 -2931 17 2803 952 -115 42 -767 -1497 -1345 -396 -364 798 1362 1769 1479 1411 1298 716 -1807 -2520 -3632 -3770 -1664 -154 748 432 416 -563 -8 472 1242 1171 1243 556 -172 -287 -43 -1539 -2521 -1515 -993 -427 1265 946 -827 -1260 -1469 -1796 -2416 -914 -1058 -1977 -209 133 33 -853 -1272 -1154 -314 879 3375 4246 2678 2653 1718 622 246 -2526 -4158 -4453 -3439 -916 1636 714 137 -959 -2909 -1892 -168 411 -165 291 541 -341 1099 2819 2939 1507 988 -90 -1377 -242 1496 409 999 1820 611 1219 2790 -536 -1394 -457 -2149 -2507 266 -180 -457 519 977 525 1043 1379 1701 1919 1557 -2 -1795 -2378 -2065 -1283 275 1211 755 -225 -422 2505 2675 2436 1082 922 1206 -284 -1435 -1365 -1440 -1423 -353 1688 746 -259 523 -50 264 1672 1429 1591 2424 706 -3551 -2481 -2129 -2814 17 2833 944 -114 41 -746 -1452 -1307 -388 -361 798 1376 1801 1502 1420 1292 703 -1750 -2494 -3579 -3580 -1605 -153 761 429 432 -562 -8 472 1249 1179 1248 554 -169 -289 -43 -1541 -2500 -1501 -991 -429 1232 926 -834 -1244 -1438 -1747 -2351 -889 -1042 -1963 -208 130 33 -834 -1235 -1111 -313 844 3251 4093 2633 2501 1568 574 224 -2320 -3830 -3999 -3190 -887 1597 721 140 -978 -2955 -1908 -172 412 -166 293 547 -346 1117 2916 3098 1590 1028 -92 -1387 -241 1503 417 1019 1864 628 1245 2856 -552 -1408 -460 -2201 -2580 279 -187 -479 550 1055 573 1146 1520 1871 2102 1698 -2 -1930 -2556 -2234 -1406 295 1323 833 -248 -465 SQ 20251006T112526.4Z 9410.475999 217 1 28.31 2 87.55 98.86 102.03 283.01 0.00 1 0.00 1 0 92 1.530e-02 1.508e-02 2.268e-04 2.264e-04 1.468766e+04 1.491933e+01 5.908139e+02 -6.000000e+00 7.914075e+02 286.30 -2.00 20.00 -2.00 505.39 0.00e+00 2.470872e-03 6.146687e-06 4.269965e-05 -6.000000e+00 4.202404e-04 286.30 -2.00 20.00 -2.00 500.80 0.00e+00 1.335243e+00 4.046466e-03 8.930077e-02 -6.000000e+00 2.920738e-01 227.13 -2.00 3.47 -2.00 502.36 0.00e+00 14.841 0.057 489.00 513.00 1 9.9594e-01 3.1095e-04 2.3408e-02 -6.0000e+00 2.2292e-02 -2.4539e-02 7.5630e-05 1.5662e-03 -6.0000e+00 5.9827e-03 7.6579e-02 9.4781e-02 1.4709e-05 4.7099e-05 -6.0000e+00 1.0465e-03 1.5578e-02 2.0064e-04 12 13 9 12 4 4 98.56 50.55 1.85 0.01558 0.67302 575 62 1 2 0 48.874 19.98 50.55 19.13 27.75 28.25 12.5 982.40 1934 2140 2010 717 600 1013 -437 -1700 -1475 -1659 -1570 -596 1618 610 -397 555 -58 213 1631 1340 1577 2471 968 -3456 -2436 -1965 -2769 -19 2841 1117 -22 211 -588 -1249 -1172 -390 -338 825 1293 1716 1493 1402 1435 952 -1506 -2248 -3384 -3606 -1563 -213 680 313 410 -561 -129 410 1162 1115 1232 651 -45 -169 66 -1357 -2385 -1371 -842 -385 1366 1036 -586 -1103 -1209 -1579 -2212 -829 -885 -1869 -191 138 139 -696 -1008 -1006 -362 523 2866 3747 2381 2414 1798 757 188 -2260 -3615 -3944 -3056 -595 1847 812 273 -650 -2658 -1831 -307 277 -82 248 477 -253 965 2499 2690 1252 923 -114 -1331 -251 1417 154 729 1471 442 1057 2705 -338 -1231 -466 -2162 -2548 29 -116 -533 276 698 248 774 1195 1591 1891 1531 71 -1687 -2240 -1927 -1258 224 1110 730 -272 900000 1914 2144 2018 716 589 987 -424 -1635 -1414 -1603 -1533 -593 1583 612 -399 556 -58 214 1649 1362 1594 2478 967 -3384 -2325 -1888 -2711 -19 2823 1133 -22 210 -584 -1233 -1158 -389 -340 836 1324 1768 1533 1425 1439 942 -1466 -2223 -3329 -3556 -1508 -212 694 313 425 -561 -133 410 1170 1123 1237 648 -46 -170 66 -1348 -2345 -1345 -832 -383 1369 1046 -585 -1078 -1170 -1520 -2132 -801 -864 -1840 -189 138 135 -677 -976 -1003 -361 504 2773 3637 2354 2298 1663 706 172 -2081 -3331 -3688 -2838 -574 1800 816 275 -655 -2666 -1822 -310 274 -82 249 478 -255 973 2555 2788 1296 942 -114 -1319 -254 1401 155 730 1477 444 1056 2703 -340 -1212 -472 -2149 -2541 29 -121 -563 284 733 263 823 1276 1695 2007 1616 75 -1746 -2311 -1998 -1322 239 1203 772 -297 900000 SQ 20251006T112555.0Z 9410.476330 217 2 28.31 2 87.46 98.93 102.12 283.09 0.00 1 0.00 1 0 92 1.516e-02 1.497e-02 2.140e-04 2.136e-04 1.443919e+04 1.401643e+01 5.572616e+02 -6.000000e+00 7.835842e+02 286.30 -2.00 20.00 -2.00 505.41 0.00e+00 2.348536e-03 5.794800e-06 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