File name: Pandora71s1_GreenbeltMD_20251009_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20251010T050732.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20251009_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20251009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20251009T111738.6Z 9413.470586 201 1 51.19 2 89.61 98.64 58.96 273.33 0.00 1 0.00 1 0 120 1.785e-02 1.752e-02 4.301e-04 4.270e-04 1.382119e+04 2.763428e+01 7.513984e+02 -6.000000e+00 9.208595e+02 285.95 -2.00 20.00 -2.00 505.51 0.00e+00 6.571467e-03 1.164601e-05 1.613532e-04 -6.000000e+00 4.885515e-04 285.95 -2.00 20.00 -2.00 501.31 0.00e+00 1.079780e+00 7.504950e-03 7.928073e-02 -6.000000e+00 3.367487e-01 226.82 -2.00 3.47 -2.00 502.78 0.00e+00 19.836 0.138 489.00 513.00 1 2.0825e+00 5.7738e-04 3.4942e-02 -6.0000e+00 2.5760e-02 -6.4012e-02 1.3677e-04 1.9836e-03 -6.0000e+00 6.8108e-03 1.2486e-02 9.6861e-02 2.8152e-05 7.4545e-05 -6.0000e+00 1.2129e-03 -6.3117e-03 2.2856e-04 12 13 9 12 5 5 24.48 50.00 5.36 -0.00631 0.66555 197 22 1 2 0 258.163 20.09 50.00 12.58 27.25 27.50 12.0 956.79 3061 3269 3099 1675 1183 1511 7 -1321 -1388 -1480 -1475 -383 1786 1201 -73 694 243 390 1932 1776 1952 2678 1215 -3590 -3101 -2562 -3137 -565 2760 1390 -70 -65 -894 -1694 -1544 -561 -419 798 1331 1903 1677 1498 1422 857 -1853 -2927 -4118 -4267 -2137 -494 689 406 564 -439 31 624 1401 1430 1390 836 7 -314 -85 -1457 -2748 -1720 -1176 -705 1015 912 -815 -1616 -1703 -2038 -2639 -1233 -1241 -2132 -510 -109 -54 -1014 -1468 -1465 -871 88 2561 3758 2568 2352 1673 547 -282 -2787 -4186 -4583 -3599 -1007 1640 761 -26 -996 -2923 -2085 -353 432 232 864 1230 592 1682 3203 3351 1826 1337 247 -1065 -118 1537 474 953 1751 794 1301 2915 -46 -1188 -598 -2086 -2768 -181 55 -297 449 1111 559 1015 1486 1938 2057 1581 -38 -2081 -2711 -2353 -1450 109 1293 822 -259 -336 2851 2929 2782 1497 1097 1390 6 -1204 -1265 -1291 -1302 -343 1634 1122 -68 651 230 369 1842 1627 1873 2557 1159 -3368 -2849 -2370 -2955 -516 2605 1339 -67 -62 -852 -1614 -1476 -543 -411 792 1278 1844 1626 1443 1355 848 -1813 -2822 -3966 -4124 -2097 -478 682 408 570 -444 31 635 1435 1468 1426 851 7 -313 -85 -1443 -2700 -1687 -1163 -702 1017 920 -816 -1590 -1663 -1982 -2569 -1201 -1223 -2113 -507 -110 -52 -981 -1412 -1466 -872 84 2480 3667 2477 2299 1597 510 -259 -2569 -3854 -4266 -3433 -991 1607 768 -27 -1010 -2959 -2104 -361 432 235 882 1263 611 1743 3363 3571 1947 1410 257 -1098 -121 1592 499 1004 1853 844 1376 3090 -49 -1245 -625 -2207 -2941 -195 59 -319 487 1224 622 1133 1666 2169 2301 1761 -42 -2281 -2963 -2590 -1620 124 1434 922 -290 -376 SQ 20251009T112146.7Z 9413.473457 207 1 53.98 2 88.82 99.29 59.73 273.94 0.00 1 0.00 1 0 106 1.559e-02 1.536e-02 2.249e-04 2.241e-04 1.005226e+04 1.399217e+01 5.515247e+02 -6.000000e+00 8.046472e+02 285.95 -2.00 20.00 -2.00 505.44 0.00e+00 4.264809e-03 6.108633e-06 4.815410e-05 -6.000000e+00 4.268796e-04 285.95 -2.00 20.00 -2.00 501.08 0.00e+00 1.237927e+00 3.943884e-03 6.374722e-02 -6.000000e+00 2.942164e-01 226.82 -2.00 3.47 -2.00 502.60 0.00e+00 18.154 0.105 489.00 513.00 1 1.1421e+00 3.0342e-04 3.0146e-02 -6.0000e+00 2.2507e-02 -3.6314e-02 7.2673e-05 1.7234e-03 -6.0000e+00 5.9499e-03 4.1368e-02 9.6008e-02 1.5049e-05 4.9854e-05 -6.0000e+00 1.0599e-03 1.3331e-02 1.1585e-04 12 13 9 12 4 4 30.99 50.00 3.01 0.01333 0.67929 617 66 1 2 0 87.135 20.02 50.00 12.48 27.25 27.50 12.1 957.25 2098 2380 2317 1053 728 1106 -274 -1582 -1574 -1694 -1634 -661 1560 834 -249 600 145 229 1695 1557 1671 2474 1263 -3356 -2615 -2229 -2863 -439 2735 1249 73 215 -604 -1293 -1322 -375 -400 765 1301 1759 1578 1463 1431 993 -1459 -2373 -3568 -3928 -1961 -463 559 320 444 -482 -95 397 1151 1214 1326 820 41 -86 49 -1208 -2398 -1433 -824 -540 1186 1078 -562 -1253 -1295 -1700 -2305 -926 -977 -1939 -352 6 49 -819 -1123 -1145 -760 -57 2170 3311 2228 2101 1807 705 -177 -2382 -3510 -3855 -3041 -631 1847 936 243 -577 -2567 -1913 -476 226 62 604 905 370 1362 2599 2780 1350 1206 182 -1087 -255 1255 171 656 1307 558 1120 2650 55 -1085 -634 -2101 -2808 -456 -100 -441 220 716 276 736 1300 1738 2059 1670 178 -1800 -2399 -2094 -1329 126 1189 871 -227 -293 2016 2315 2163 1020 695 1047 -258 -1480 -1470 -1595 -1555 -612 1477 809 -242 582 142 224 1666 1541 1647 2423 1233 -3216 -2445 -2100 -2745 -428 2651 1238 72 210 -588 -1254 -1285 -368 -398 768 1320 1730 1550 1482 1432 982 -1422 -2271 -3404 -3761 -1906 -447 553 321 448 -485 -96 401 1171 1236 1347 825 41 -84 48 -1178 -2315 -1381 -801 -529 1170 1070 -554 -1210 -1240 -1622 -2205 -888 -949 -1895 -345 6 49 -818 -1118 -1138 -756 -57 2186 3240 2243 2056 1729 660 -163 -2278 -3349 -3574 -2887 -617 1810 941 245 -580 -2569 -1904 -481 232 65 612 922 379 1399 2698 2916 1414 1245 186 -1099 -256 1276 176 676 1352 577 1152 2733 57 -1105 -642 -2150 -2882 -475 -107 -462 233 768 299 798 1416 1893 2238 1806 190 -1906 -2527 -2217 -1428 137 1319 942 -253 -325 SQ 20251009T112544.2Z 9413.476206 213 1 28.27 2 88.06 99.92 60.46 274.52 0.00 1 0.00 1 0 106 1.465e-02 1.447e-02 2.093e-04 2.088e-04 7.546695e+03 1.266072e+01 4.112054e+02 -6.000000e+00 7.558693e+02 285.95 -2.00 20.00 -2.00 505.41 0.00e+00 3.176617e-03 5.655577e-06 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