File name: Pandora71s1_GreenbeltMD_20251113_L2Fit_fwvt1c1d20220202p1-8.txt File generation date: 20251114T045808.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 71 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora71_OF_v7d20201007.txt Instrument calibration file used: Pandora71s1_CF_v1d20220202.txt Level 1 file used: Pandora71s1_GreenbeltMD_20251113_L1_smca1c1d20220202p1-8.txt Full location name: Goddard Space Flight Center Short location name: GreenbeltMD Country of location: USA Location latitude [deg]: 38.9926 Location longitude [deg]: -76.8396 Location altitude [m]: 90 Local noon date: 20251113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1657 1807 Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3171 492.4375 492.5580 492.6784 492.7988 492.9191 493.0395 493.1598 493.2802 493.4005 493.5208 493.6410 493.7613 493.8815 494.0017 494.1219 494.2421 494.3623 494.4825 494.6026 494.7227 494.8428 494.9629 495.0830 495.2030 495.3231 495.4431 495.5631 495.6831 495.8030 495.9230 496.0429 496.1628 496.2827 496.4026 496.5225 496.6423 496.7621 496.8820 497.0018 497.1215 497.2413 497.3610 497.4808 497.6005 497.7202 497.8399 497.9595 498.0792 498.1988 498.3184 498.4380 498.5576 498.6771 498.7967 498.9162 499.0357 499.1552 499.2746 499.3941 499.5135 499.6330 499.7524 499.8717 499.9911 500.1105 500.2298 500.3491 500.4684 500.5877 500.7070 500.8262 500.9455 501.0647 501.1839 501.3030 501.4222 501.5414 501.6605 501.7796 501.8987 502.0178 502.1368 502.2559 502.3749 502.4939 502.6129 502.7319 502.8508 502.9698 503.0887 503.2076 503.3265 503.4453 503.5642 503.6830 503.8018 503.9206 504.0394 504.1582 504.2769 504.3957 504.5144 504.6331 504.7517 504.8704 504.9890 505.1077 505.2263 505.3449 505.4635 505.5820 505.7005 505.8191 505.9376 506.0561 506.1745 506.2930 506.4114 506.5298 506.6482 506.7666 506.8850 507.0033 507.1217 507.2400 507.3583 507.4765 507.5948 507.7130 507.8313 507.9495 508.0677 508.1858 508.3040 508.4221 508.5402 508.6584 508.7764 508.8945 509.0126 509.1306 509.2486 509.3666 509.4846 509.6025 509.7205 509.8384 509.9563 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20251113T115714.3Z 9448.498082 220 1 53.84 2 89.26 114.22 29.67 173.51 0.00 1 0.00 1 0 99 1.583e-02 1.559e-02 9.770e-04 9.734e-04 1.034944e+04 5.994718e+01 5.772321e+02 -6.000000e+00 8.038093e+02 281.77 -2.00 20.00 -2.00 505.45 0.00e+00 4.320262e-03 2.619679e-05 5.516609e-05 -6.000000e+00 4.289565e-04 281.77 -2.00 20.00 -2.00 501.11 0.00e+00 1.397672e+00 1.712057e-02 7.095853e-02 -6.000000e+00 2.981533e-01 223.77 -2.00 3.47 -2.00 502.62 0.00e+00 19.288 0.126 489.00 513.00 1 3.8152e+00 1.3149e-03 3.3121e-02 -6.0000e+00 2.2783e-02 -3.0312e-02 3.1520e-04 1.9021e-03 -6.0000e+00 6.0218e-03 2.4039e-03 9.4288e-02 6.5378e-05 5.1974e-05 -6.0000e+00 1.0761e-03 2.7450e-02 7.0779e-05 12 13 9 12 4 4 31.34 50.59 3.41 0.02745 0.68147 37 4 1 2 0 1454.694 19.99 50.59 11.44 27.00 27.00 12.5 979.84 2184 2464 2340 1193 744 993 -197 -1583 -1430 -1647 -1738 -854 1685 854 -404 628 65 63 1649 1728 1601 2309 1414 -3461 -2834 -2317 -3009 -654 2826 1605 375 236 -687 -1262 -1473 -157 -396 837 1105 1795 1464 1600 1421 960 -1523 -2386 -3404 -3897 -2031 -725 611 444 443 -575 -143 520 1208 1242 1361 725 123 -296 101 -1185 -2414 -1392 -929 -676 1287 1091 -492 -1262 -1154 -1770 -2329 -993 -677 -1867 -520 -129 29 -705 -1200 -1330 -956 -241 2057 3318 2514 1988 1686 784 -103 -2407 -3434 -3960 -3155 -808 1900 956 361 -544 -2459 -1777 -474 283 44 590 1079 445 1271 2623 2888 1380 1198 233 -1004 -406 1285 99 672 1284 678 954 2788 163 -809 -623 -2012 -2968 -436 -40 -512 243 870 168 744 1195 1707 2076 1822 180 -1857 -2335 -2275 -1255 31 1197 929 -308 -355 2095 2394 2280 1156 710 941 -186 -1482 -1334 -1549 -1655 -826 1578 821 -390 604 63 61 1606 1692 1566 2246 1369 -3299 -2633 -2165 -2865 -633 2822 1560 363 226 -659 -1204 -1410 -151 -387 826 1105 1807 1474 1594 1400 936 -1466 -2250 -3193 -3670 -1941 -716 618 455 457 -567 -147 537 1199 1235 1350 715 125 -299 101 -1182 -2385 -1370 -923 -677 1295 1058 -496 -1247 -1128 -1728 -2276 -972 -670 -1861 -497 -125 28 -686 -1164 -1289 -927 -235 2016 3280 2458 1895 1645 747 -97 -2254 -3200 -3732 -3043 -767 1873 970 367 -551 -2485 -1783 -483 294 44 598 1099 457 1307 2725 3035 1450 1242 239 -1018 -410 1310 102 694 1331 704 986 2880 170 -825 -633 -2067 -3062 -455 -43 -559 256 929 182 804 1299 1855 2250 1964 193 -1965 -2454 -2408 -1344 34 1325 1038 -343 -394 SQ 20251113T120130.4Z 9448.501047 226 1 54.25 2 88.51 114.90 29.61 175.60 0.00 1 0.00 1 0 113 1.493e-02 1.472e-02 5.562e-04 5.546e-04 8.589497e+03 3.369288e+01 4.548679e+02 -6.000000e+00 7.575845e+02 281.77 -2.00 20.00 -2.00 505.42 0.00e+00 3.362854e-03 1.488423e-05 2.100605e-05 -6.000000e+00 4.044242e-04 281.77 -2.00 20.00 -2.00 501.00 0.00e+00 1.438334e+00 9.773143e-03 5.956104e-02 -6.000000e+00 2.812344e-01 223.77 -2.00 3.47 -2.00 502.53 0.00e+00 17.438 0.093 489.00 513.00 1 3.0482e+00 7.5066e-04 2.8367e-02 -6.0000e+00 2.1487e-02 -2.2528e-02 1.8078e-04 1.6360e-03 -6.0000e+00 5.6841e-03 6.7896e-03 9.4972e-02 3.7578e-05 3.9936e-05 -6.0000e+00 1.0144e-03 3.8726e-02 -4.0831e-05 12 13 9 12 4 4 21.82 50.55 2.45 0.03873 0.69749 92 10 1 2 0 589.234 19.90 50.55 11.45 27.00 27.25 12.4 979.89 2032 2132 2037 914 511 1004 -241 -1747 -1586 -1779 -1687 -751 1382 870 -394 532 207 151 1552 1462 1602 2318 1412 -3337 -2481 -2093 -2728 -416 2770 1321 122 292 -426 -1117 -1217 -250 -355 754 1201 1705 1474 1528 1506 1058 -1336 -2267 -3359 -3720 -1938 -405 529 369 537 -417 -81 276 1218 1190 1441 771 64 -90 217 -1043 -2205 -1474 -739 -564 1242 1156 -370 -1151 -1224 -1514 -2187 -950 -752 -1919 -383 46 -53 -823 -1017 -1140 -781 -270 1845 3137 2098 1889 1690 852 -147 -2239 -3300 -3616 -2947 -642 2032 931 424 -387 -2292 -1751 -450 360 139 518 912 387 1304 2379 2554 1215 1108 175 -1025 -385 1200 67 474 1289 470 845 2685 120 -943 -665 -2002 -2904 -611 -46 -406 88 575 133 574 1147 1641 2115 1812 378 -1656 -2255 -2058 -1256 83 1142 875 -66 -273 1949 2075 1987 886 488 950 -228 -1635 -1478 -1671 -1601 -725 1363 841 -383 515 202 147 1520 1440 1570 2258 1369 -3182 -2399 -2038 -2591 -401 2766 1350 124 293 -427 -1114 -1215 -251 -347 744 1199 1714 1480 1517 1477 1026 -1329 -2209 -3257 -3613 -1910 -395 530 375 547 -425 -82 282 1250 1223 1474 784 65 -89 213 -1023 -2139 -1428 -721 -555 1230 1154 -366 -1117 -1177 -1450 -2100 -916 -733 -1884 -376 46 -53 -827 -1017 -1141 -782 -261 1799 3085 2049 1867 1635 805 -136 -2073 -3044 -3366 -2808 -630 1989 938 427 -388 -2287 -1735 -452 368 144 522 923 394 1329 2449 2658 1260 1133 177 -1027 -398 1207 69 482 1315 481 859 2728 123 -947 -663 -2017 -2933 -626 -48 -434 95 607 141 612 1227 1757 2257 1925 398 -1784 -2412 -2212 -1319 88 1238 958 -72 -296 SQ 20251113T120640.3Z 9448.504633 233 1 54.32 2 87.60 115.73 29.58 178.14 0.00 1 0.00 1 0 92 1.405e-02 1.387e-02 8.371e-04 8.356e-04 6.569304e+03 4.984836e+01 3.876771e+02 -6.000000e+00 7.135055e+02 281.77 -2.00 20.00 -2.00 505.40 0.00e+00 2.612424e-03 2.244022e-05 3.088835e-05 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