File name: Pandora94s1_GuatemalaCity_L2_rfus5p1-8.txt File generation date: 20260625T061833.7Z Data description: Level 2 file (columns and more) Data file version: rfus5p1-8 Data product status: Formaldehyde data are official Local principal investigator: Network principal investigator: Alexander Cede DOI: 10.48596/pgn.rfus5p1-8.GuatemalaCity.P94s1 Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Data start time: 20250225T203640.6 Data end time: 20260624T233348. Data caveats: None --------------------------------------------------------------------------------------- Column 1: UT date and time for measurement center, yyyymmddThhmmssZ (ISO 8601) Column 2: Fractional days since 1-Jan-2000 UT midnight for measurement center Column 3: Effective duration of measurement [s] Column 4: Solar zenith angle for measurement center [deg] Column 5: Solar azimuth for measurement center [deg], 0=north, increases clockwise Column 6: Lunar zenith angle for measurement center [deg] Column 7: Lunar azimuth for measurement center [deg], 0=north, increases clockwise Column 8: rms of unweighted fitting residuals, -9=fitting not successful Column 9: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty given Column 10: Expected rms of unweighted fitting residuals based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 11: Expected normalized rms of weighted fitting residuals based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 12: Climatological station pressure [mbar] Column 13: Data processing type index Column 14: Calibration file version Column 15: Calibration file validity starting date Column 16: Mean value of measured data inside fitting window [same units as measurements] Column 17: Wavelength effective temperature [°C], 999=no effective temperature given Column 18: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 19: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 20: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 21: Retrieved resolution change [%], -999=no resolution change fitting Column 22: Integration time [ms] Column 23: Number of bright count cycles Column 24: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 25: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 26: Atmospheric variability [%], 999=no atmospheric variability was determined Column 27: Estimated aerosol optical depth at starting wavelength of fitting window Column 28: Estimated aerosol optical depth at center wavelength of fitting window Column 29: Estimated aerosol optical depth at ending wavelength of fitting window Column 30: L1 data quality flag, 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 31: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 32: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 33: L2Fit data quality flag, 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 34: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 35: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 36: L2 data quality flag for formaldehyde, 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality, 20=unusable high quality, 21=unusable medium quality, 22=unusable low quality Column 37: Sum over 2^i using those i, for which the corresponding L2 data quality parameter for formaldehyde exceeds the DQ1 limit, 0=L2Fit data quality above 0, 1=Retrieval error, 2=Air mass factor too large, 3=Atmospheric variability too large Column 38: Sum over 2^i using those i, for which the corresponding L2 data quality parameter for formaldehyde exceeds the DQ2 limit (same parameters as for DQ1) Column 39: Formaldehyde total vertical column amount [moles per square meter], -9e99=retrieval not successful Column 40: Independent uncertainty of formaldehyde total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting was not successful Column 41: Structured uncertainty of formaldehyde total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -7=not given since method "MEAS" was chosen, -9=spectral fitting was not successful Column 42: Common uncertainty of formaldehyde total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting was not successful Column 43: Total uncertainty of formaldehyde total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -8=not given, since not all components are given Column 44: rms-based uncertainty of formaldehyde total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -9=spectral fitting was not successful Column 45: Formaldehyde effective temperature [K] Column 46: Independent uncertainty of formaldehyde effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and common uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -5=spectral fitting was done without using the independent uncertainty input, -6=no independent uncertainty input was given, -9=spectral fitting was not successful Column 47: Structured uncertainty of formaldehyde effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -9=spectral fitting was not successful Column 48: Common uncertainty of formaldehyde effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and common uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -6=no independent uncertainty input was given, -9=spectral fitting was not successful Column 49: Total uncertainty of formaldehyde effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and common uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -5=spectral fitting was done without using the independent uncertainty input, -6=no independent uncertainty or common uncertainty input was given, -9=spectral fitting was not successful Column 50: Direct formaldehyde air mass factor Column 51: Uncertainty of direct formaldehyde air mass factor, -7=uncertainty could not be retrieved since slant column uncertainties were missing Column 52: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not successful, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction --------------------------------------------------------------------------------------- 20250225T203640.6Z 9187.858803 30.01 42.21 238.56 72.27 240.32 0.0005995 0.0005884 6.992e-05 6.805e-05 846 2 4 20250225 0.42367 26.03 0.31 -0.03074 -0.03272 0.18 13.87 2163 1 5 27.33 0.007 -0.0 -0.001 10 0 0 11 8 0 11 1 0 0.00018343 4.2628e-06 4.2676e-06 1.3119e-05 1.4439e-05 3.746e-05 285.26 -2.0 20.0 -2.0 20.0 1.35 0.0 0.0 20250225T203948.7Z 9187.86098 30.02 42.86 239.18 72.91 240.64 0.0006034 0.0005918 6.991e-05 6.804e-05 846 2 4 20250225 0.42349 26.06 0.31 -0.03094 -0.0328 0.18 13.91 2157 1 5 5.66 0.001 -0.006 -0.007 10 0 0 11 8 0 11 1 0 0.00018238 4.219e-06 4.3172e-06 1.2981e-05 1.4316e-05 3.7324e-05 285.26 -2.0 20.0 -2.0 20.0 1.364 0.0 0.0 20250225T204257.3Z 9187.863163 30.01 43.52 239.79 73.55 240.95 0.0006148 0.0006019 6.994e-05 6.805e-05 846 2 4 20250225 0.42308 26.09 0.3 -0.03102 -0.03287 0.19 13.87 2163 1 5 18.74 -0.005 -0.012 -0.013 10 0 0 11 8 0 11 1 0 0.00018428 4.1761e-06 4.0688e-06 1.2843e-05 1.4104e-05 3.7634e-05 285.26 -2.0 20.0 -2.0 20.0 1.379 0.0 0.0 20250225T204605.1Z 9187.865337 30.01 44.17 240.39 74.18 241.26 0.000601 0.0005901 7.104e-05 6.91e-05 846 2 4 20250225 0.40937 26.11 0.31 -0.03095 -0.03293 0.2 14.24 2107 1 5 32.48 0.013 0.006 0.005 10 0 0 11 8 0 11 1 0 0.00018249 4.1952e-06 4.1971e-06 1.2706e-05 1.4024e-05 3.6408e-05 285.26 -2.0 20.0 -2.0 20.0 1.394 0.0 0.0 20250225T204911Z 9187.867488 30.01 44.83 240.96 74.82 241.56 0.0006074 0.0005937 7.714e-05 7.503e-05 846 2 4 20250225 0.34336 26.15 0.31 -0.03081 -0.03294 0.2 17.2 1744 1 5 95.91 0.13 0.124 0.122 10 0 0 11 8 0 12 9 8 0.00019897 4.5098e-06 4.2616e-06 1.2563e-05 1.4012e-05 3.6392e-05 285.26 -2.0 20.0 -2.0 20.0 1.41 0.0 0.0 20250225T205216.5Z 9187.869636 30.02 45.48 241.51 75.45 241.85 0.0006101 0.0005963 7.297e-05 7.093e-05 846 2 4 20250225 0.38703 26.17 0.3 -0.03113 -0.03304 0.2 15.17 1978 1 5 15.64 0.041 0.032 0.029 10 0 0 11 8 0 11 1 0 0.000173 4.2208e-06 4.2638e-06 1.2421e-05 1.3794e-05 3.617e-05 285.26 -2.0 20.0 -2.0 20.0 1.426 0.0 0.0 20250225T205522Z 9187.871782 30.01 46.14 242.05 76.08 242.14 0.000612 0.0005966 7.157e-05 6.954e-05 846 2 4 20250225 0.40407 26.2 0.3 -0.03108 -0.03313 0.19 14.47 2073 1 5 25.96 0.002 -0.006 -0.008 10 0 0 11 8 0 11 1 0 0.00018304 4.0887e-06 4.0977e-06 1.2275e-05 1.3572e-05 3.5861e-05 285.26 -2.0 20.0 -2.0 20.0 1.443 0.0 0.0 20250225T205836.4Z 9187.874033 30.02 46.83 242.6 76.75 242.44 0.0006139 0.000603 7.248e-05 7.042e-05 846 2 4 20250225 0.39307 26.21 0.3 -0.03114 -0.03314 0.2 14.81 2026 1 5 20.26 0.014 0.006 0.004 10 0 0 11 8 0 11 1 0 0.00018693 4.0917e-06 4.2713e-06 1.2121e-05 1.3487e-05 3.5538e-05 285.26 -2.0 20.0 -2.0 20.0 1.461 0.0 0.0 20250225T210149.6Z 9187.876269 30.01 47.53 243.14 77.42 242.73 0.0006107 0.0006005 7.385e-05 7.172e-05 846 2 4 20250225 0.37783 26.24 0.3 -0.03129 -0.03322 0.2 15.37 1952 1 5 15.34 0.033 0.025 0.022 10 0 0 11 8 0 11 1 0 0.00017576 4.1176e-06 3.8836e-06 1.1962e-05 1.3233e-05 3.4911e-05 285.26 -2.0 20.0 -2.0 20.0 1.48 0.0 0.0 20250225T210501Z 9187.878484 30.01 48.22 243.65 78.08 243.01 0.0006165 0.0006027 7.533e-05 7.312e-05 846 2 4 20250225 0.36285 26.26 0.3 -0.03119 -0.03323 0.2 15.89 1888 1 5 30.79 0.052 0.043 0.041 10 0 0 11 8 0 11 1 0 0.00018554 4.1451e-06 4.1192e-06 1.1806e-05 1.3173e-05 3.4789e-05 285.26 -2.0 20.0 -2.0 20.0 1.5 0.0 0.0 20250225T210813.3Z 9187.88071 30.02 48.91 244.15 78.74 243.29 0.0006042 0.0005939 7.42e-05 7.198e-05 846 2 4 20250225 0.37489 26.27 0.3 -0.03128 -0.03325 0.18 15.58 1926 1 5 4.6 0.022 0.013 0.01 10 0 0 11 8 0 11 1 0 0.00018314 4.0306e-06 4.4314e-06 1.165e-05 1.31e-05 3.3658e-05 285.26 -2.0 20.0 -2.0 20.0 1.521 0.0 0.0 20250225T211121Z 9187.882882 30.0 49.6 244.63 79.39 243.56 0.0006111 0.0005984 7.435e-05 7.211e-05 846 2 4 20250225 0.37401 26.29 0.3 -0.03135 -0.03328 0.19 15.5 1935 1 5 3.52 0.014 0.006 0.004 10 0 0 11 8 0 11 1 0 0.00018161 3.9822e-06 4.0471e-06 1.1489e-05 1.2815e-05 3.358e-05 285.26 -2.0 20.0 -2.0 20.0 1.542 0.0 0.0 20250225T211428.3Z 9187.88505 30.01 50.28 245.1 80.04 243.83 0.0006142 0.0006032 7.499e-05 7.274e-05 846 2 4 20250225 0.36722 26.3 0.3 -0.03131 -0.03323 0.19 15.68 1913 1 5 12.81 0.017 0.009 0.007 10 0 0 11 8 0 11 1 0 0.00018096 3.9654e-06 4.3037e-06 1.133e-05 1.2752e-05 3.3293e-05 285.26 -2.0 20.0 -2.0 20.0 1.564 0.0 0.0 20250225T211735Z 9187.887211 30.01 50.96 245.56 80.69 244.08 0.0006083 0.0005973 7.658e-05 7.424e-05 846 2 4 20250225 0.35133 26.3 0.3 -0.03117 -0.03322 0.19 16.32 1838 1 5 22.85 0.037 0.028 0.025 10 0 0 11 8 0 11 1 0 0.00018043 3.9941e-06 4.066e-06 1.1167e-05 1.2537e-05 3.252e-05 285.26 -2.0 20.0 -2.0 20.0 1.587 0.0 0.0 20250225T212030.4Z 9187.889241 30.02 51.61 245.98 81.3 244.32 0.0006626 0.0006402 0.000121 0.0001172 846 2 4 20250225 0.13533 26.3 0.3 -0.03127 -0.03327 0.15 32.62 920 1 5 99.97 0.619 0.614 0.615 10 0 0 11 8 0 12 9 8 0.00017071 6.218e-06 4.6414e-06 1.1008e-05 1.3468e-05 3.491e-05 285.26 -2.0 20.0 -2.0 20.0 1.609 0.0 0.0 20250225T212220.1Z 9187.89051 14.14 52.01 246.23 81.69 244.47 0.000654 0.000642 0.0001947 0.0001887 846 2 4 20250225 0.10869 26.3 0.3 -0.03123 -0.03334 0.13 58.64 240 1 5 99.61 0.74 0.736 0.737 12 1 1 12 9 1 12 9 9 0.00019579 9.9158e-06 4.6715e-06 1.0913e-05 1.5468e-05 3.4159e-05 285.26 -2.0 20.0 -2.0 20.0 1.624 0.0 0.0 20250225T212508.8Z 9187.892463 30.0 52.63 246.62 82.28 244.69 0.0006203 0.0006093 8.052e-05 7.792e-05 846 2 4 20250225 0.31667 26.3 0.3 -0.03118 -0.03306 0.11 18.09 1658 1 5 25.47 0.08 0.069 0.064 10 0 0 11 8 0 11 1 0 0.00020866 4.0471e-06 4.9867e-06 1.0763e-05 1.2534e-05 3.2016e-05 285.26 -2.0 20.0 -2.0 20.0 1.646 0.0 0.0 20250225T215524.9Z 9187.913482 22.12 59.45 250.35 88.69 246.91 0.0009249 0.0008916 0.0006117 0.0005908 846 2 4 20250225 0.0074037 25.91 0.31 -0.02645 -0.02822 0.22 650.37 33 1 5 99.95 1.853 1.873 1.899 12 1 1 12 9 9 12 9 9 0.00014161 2.5737e-05 5.37e-06 9.0156e-06 2.7794e-05 3.9918e-05 285.26 -2.0 20.0 -2.0 20.0 1.965 0.0 0.0 20250225T215821.8Z 9187.91553 30.02 60.12 250.68 89.32 247.1 0.0005631 0.0005463 0.0001042 9.998e-05 846 2 4 20250225 0.18762 25.92 0.29 -0.02641 -0.02822 0.14 34.46 871 1 5 98.25 0.225 0.213 0.206 10 0 0 11 8 0 12 9 8 0.0001921 4.3353e-06 4.6753e-06 8.8457e-06 1.0904e-05 2.4059e-05 285.26 -2.0 20.0 -2.0 20.0 2.005 0.0 0.0 20250225T220126.3Z 9187.917666 30.0 60.82 251.01 89.98 247.31 0.0005658 0.0005518 9.671e-05 9.273e-05 846 2 4 20250225 0.21998 25.93 0.29 -0.02664 -0.02816 0.13 24.91 1204 1 5 27.41 0.13 0.118 0.112 10 0 0 11 8 0 11 1 0 0.00018355 3.9395e-06 4.9673e-06 8.6613e-06 1.0734e-05 2.3676e-05 285.26 -2.0 20.0 -2.0 20.0 2.048 0.001 0.0 20250225T220430.2Z 9187.919794 30.02 61.52 251.34 90.64 247.51 0.0005592 0.0005475 0.0001028 9.841e-05 846 2 4 20250225 0.19457 25.93 0.29 -0.02665 -0.0282 0.13 27.51 1091 1 5 14.98 0.175 0.162 0.154 10 0 0 11 8 0 11 1 0 0.00019365 4.1025e-06 5.2641e-06 8.4706e-06 1.0784e-05 2.2916e-05 285.26 -2.0 20.0 -2.0 20.0 2.094 0.001 0.0 20250225T220734.4Z 9187.921926 30.02 62.23 251.66 91.3 247.7 0.0005595 0.0005463 0.0001162 0.000111 846 2 4 20250225 0.15162 25.95 0.28 -0.02636 -0.02827 0.13 34.3 875 1 5 84.4 0.275 0.261 0.252 10 0 0 11 8 0 12 9 8 0.00020003 4.5299e-06 5.0591e-06 8.2803e-06 1.0709e-05 2.2429e-05 285.26 -2.0 20.0 -2.0 20.0 2.143 0.001 0.0 20250225T221028.1Z 9187.923936 29.96 62.89 251.96 91.92 247.88 0.0007357 0.0006845 0.0002605 0.0002484 846 2 4 20250225 0.029979 25.97 0.3 -0.0259 -0.0277 0.11 117.91 254 1 5 99.46 0.992 0.984 0.981 10 0 0 11 8 0 12 9 8 0.00015532 9.9272e-06 4.5867e-06 8.0998e-06 1.3609e-05 2.8825e-05 285.26 -2.0 20.0 -2.0 20.0 2.191 0.001 0.0 20250225T221240.2Z 9187.925465 5.97 63.4 252.18 92.39 248.02 0.002418 0.002374 0.00221 0.002115 846 2 4 20250225 0.0031341 25.98 0.36 -0.02754 -0.0289 0.37 1989.02 2 1 5 999.0 1.961 1.97 1.985 12 1 1 12 9 9 12 9 9 0.00018423 8.2365e-05 5.1045e-06 7.9521e-06 8.2905e-05 9.262e-05 285.26 -2.0 20.0 -2.0 20.0 2.23 0.001 0.0 20250225T225754.9Z 9187.956886 31.22 73.93 256.22 102.2 250.51 0.002744 0.002458 0.00261 0.002274 846 2 4 20250225 0.00048133 25.64 0.27 -0.02215 -0.02709 0.4 3120.97 10 1 5 99.91 1.5 1.523 1.541 10 0 0 12 8 8 12 9 9 0.00013376 5.839e-05 9.4376e-06 4.9471e-06 5.9354e-05 6.5897e-05 285.26 -2.0 20.0 -2.0 20.0 3.595 0.003 0.0 20250225T225951Z 9187.958229 6.95 74.38 256.38 102.62 250.6 0.001405 0.001288 0.001122 0.001012 846 2 4 20250225 0.0083289 25.62 0.3 -0.02453 -0.02632 0.26 496.02 13 1 5 99.91 0.711 0.698 0.692 12 1 1 12 9 9 12 9 9 0.00016198 2.5416e-05 6.2887e-06 4.8246e-06 2.6623e-05 3.3165e-05 285.26 -2.0 20.0 -2.0 20.0 3.695 0.004 0.0 20250225T230853.8Z 9187.964512 30.4 76.51 257.08 104.6 251.02 0.001563 0.001324 0.001404 0.001181 846 2 4 20250225 0.0014836 25.54 0.39 -0.02383 -0.02647 0.16 1599.72 19 1 5 99.98 0.948 0.938 0.931 10 0 0 12 8 8 12 9 9 0.00017827 2.6529e-05 6.257e-06 4.1939e-06 2.7578e-05 3.1884e-05 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