File name: Pandora94s1_GuatemalaCity_L2_rsus1p1-8.txt File generation date: 20260625T061856.5Z Data description: Level 2 file (columns and more) Data file version: rsus1p1-8 Data product status: Sulfur dioxide data are official Local principal investigator: Network principal investigator: Alexander Cede DOI: 10.48596/pgn.rsus1p1-8.GuatemalaCity.P94s1 Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Data start time: 20250225T203640.6 Data end time: 20260624T233348. Data caveats: None --------------------------------------------------------------------------------------- Column 1: UT date and time for measurement center, yyyymmddThhmmssZ (ISO 8601) Column 2: Fractional days since 1-Jan-2000 UT midnight for measurement center Column 3: Effective duration of measurement [s] Column 4: Solar zenith angle for measurement center [deg] Column 5: Solar azimuth for measurement center [deg], 0=north, increases clockwise Column 6: Lunar zenith angle for measurement center [deg] Column 7: Lunar azimuth for measurement center [deg], 0=north, increases clockwise Column 8: rms of unweighted fitting residuals, -9=fitting not successful Column 9: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty given Column 10: Expected rms of unweighted fitting residuals based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 11: Expected normalized rms of weighted fitting residuals based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 12: Climatological station pressure [mbar] Column 13: Data processing type index Column 14: Calibration file version Column 15: Calibration file validity starting date Column 16: Mean value of measured data inside fitting window [same units as measurements] Column 17: Wavelength effective temperature [°C], 999=no effective temperature given Column 18: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 19: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 20: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 21: Retrieved resolution change [%], -999=no resolution change fitting Column 22: Integration time [ms] Column 23: Number of bright count cycles Column 24: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 25: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 26: Atmospheric variability [%], 999=no atmospheric variability was determined Column 27: Estimated aerosol optical depth at starting wavelength of fitting window Column 28: Estimated aerosol optical depth at center wavelength of fitting window Column 29: Estimated aerosol optical depth at ending wavelength of fitting window Column 30: L1 data quality flag, 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 31: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 32: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 33: L2Fit data quality flag, 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 34: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 35: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 36: L2 data quality flag for sulfur dioxide, 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality, 20=unusable high quality, 21=unusable medium quality, 22=unusable low quality Column 37: Sum over 2^i using those i, for which the corresponding L2 data quality parameter for sulfur dioxide exceeds the DQ1 limit, 0=L2Fit data quality above 0, 1=Retrieval error, 2=Air mass factor too large, 3=Atmospheric variability too large Column 38: Sum over 2^i using those i, for which the corresponding L2 data quality parameter for sulfur dioxide exceeds the DQ2 limit (same parameters as for DQ1) Column 39: Sulfur dioxide total vertical column amount [moles per square meter], -9e99=retrieval not successful Column 40: Independent uncertainty of sulfur dioxide total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting was not successful Column 41: Structured uncertainty of sulfur dioxide total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -7=not given since method "MEAS" was chosen, -9=spectral fitting was not successful Column 42: Common uncertainty of sulfur dioxide total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting was not successful Column 43: Total uncertainty of sulfur dioxide total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -8=not given, since not all components are given Column 44: rms-based uncertainty of sulfur dioxide total vertical column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -9=spectral fitting was not successful Column 45: Sulfur dioxide effective temperature [K] Column 46: Independent uncertainty of sulfur dioxide effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and common uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -5=spectral fitting was done without using the independent uncertainty input, -6=no independent uncertainty input was given, -9=spectral fitting was not successful Column 47: Structured uncertainty of sulfur dioxide effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -9=spectral fitting was not successful Column 48: Common uncertainty of sulfur dioxide effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and common uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -6=no independent uncertainty input was given, -9=spectral fitting was not successful Column 49: Total uncertainty of sulfur dioxide effective temperature [K] , -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and common uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve temperature, -5=spectral fitting was done without using the independent uncertainty input, -6=no independent uncertainty or common uncertainty input was given, -9=spectral fitting was not successful Column 50: Direct sulfur dioxide air mass factor Column 51: Uncertainty of direct sulfur dioxide air mass factor, -7=uncertainty could not be retrieved since slant column uncertainties were missing Column 52: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not successful, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction --------------------------------------------------------------------------------------- 20250225T203640.6Z 9187.858803 30.01 42.21 238.56 72.27 240.32 0.0009492 0.0007784 0.0001459 0.0001176 846 2 4 20250225 0.16253 26.03 0.31 -0.03074 -0.03282 0.1 13.87 2163 1 5 27.33 0.006 0.002 -0.001 10 0 0 10 0 0 10 0 0 7.094e-05 3.8239e-06 7.5925e-06 3.9795e-06 9.3864e-06 2.163e-05 285.26 -2.0 20.0 -2.0 20.0 1.35 0.0 0.0 20250225T203948.7Z 9187.86098 30.02 42.86 239.18 72.91 240.64 0.0009389 0.0007709 0.000147 0.0001179 846 2 4 20250225 0.16153 26.06 0.31 -0.03094 -0.03292 0.07 13.91 2157 1 5 5.66 -0.001 -0.004 -0.007 10 0 0 10 0 0 10 0 0 6.426e-05 3.8187e-06 7.3093e-06 3.9398e-06 9.1395e-06 2.1174e-05 285.26 -2.0 20.0 -2.0 20.0 1.364 0.0 0.0 20250225T204257.3Z 9187.863163 30.01 43.52 239.79 73.55 240.95 0.000953 0.000779 0.000148 0.0001183 846 2 4 20250225 0.16037 26.09 0.3 -0.03102 -0.033 0.09 13.87 2163 1 5 18.74 -0.004 -0.009 -0.012 10 0 0 10 0 0 10 0 0 6.9591e-05 3.8085e-06 7.1956e-06 3.9038e-06 9.0289e-06 2.1262e-05 285.26 -2.0 20.0 -2.0 20.0 1.379 0.0 0.0 20250225T204605.1Z 9187.865337 30.01 44.17 240.39 74.18 241.26 0.0009335 0.0007591 0.0001518 0.0001206 846 2 4 20250225 0.15407 26.11 0.31 -0.03095 -0.03306 0.1 14.24 2107 1 5 32.48 0.013 0.008 0.005 10 0 0 10 0 0 10 0 0 7.0005e-05 3.8762e-06 7.0292e-06 3.8649e-06 8.9091e-06 2.0603e-05 285.26 -2.0 20.0 -2.0 20.0 1.394 0.0 0.0 20250225T204911Z 9187.867488 30.01 44.83 240.96 74.82 241.56 0.0009756 0.0007942 0.0001655 0.0001311 846 2 4 20250225 0.12853 26.15 0.31 -0.03081 -0.0331 0.11 17.2 1744 1 5 95.91 0.128 0.125 0.123 10 0 0 10 0 0 12 8 8 5.9835e-05 4.185e-06 7.2368e-06 3.8234e-06 9.1926e-06 2.1292e-05 285.26 -2.0 20.0 -2.0 20.0 1.41 0.0 0.0 20250225T205216.5Z 9187.869636 30.02 45.48 241.51 75.45 241.85 0.0009482 0.000773 0.0001585 0.0001246 846 2 4 20250225 0.14331 26.17 0.3 -0.03113 -0.0332 0.11 15.17 1978 1 5 15.64 0.043 0.037 0.033 10 0 0 10 0 0 10 0 0 5.8511e-05 3.9662e-06 5.7348e-06 3.7819e-06 7.9323e-06 2.0459e-05 285.26 -2.0 20.0 -2.0 20.0 1.426 0.0 0.0 20250225T205522Z 9187.871782 30.01 46.14 242.05 76.08 242.14 0.0009863 0.0008025 0.0001562 0.0001225 846 2 4 20250225 0.1489 26.2 0.3 -0.03108 -0.03318 0.12 14.47 2073 1 5 25.96 0.002 -0.002 -0.005 10 0 0 10 0 0 10 0 0 6.3056e-05 3.859e-06 6.4763e-06 3.7367e-06 8.4141e-06 2.1034e-05 285.26 -2.0 20.0 -2.0 20.0 1.443 0.0 0.0 20250225T205836.4Z 9187.874033 30.02 46.83 242.6 76.75 242.44 0.0009744 0.0007841 0.0001591 0.0001245 846 2 4 20250225 0.14365 26.21 0.3 -0.03114 -0.03322 0.1 14.81 2026 1 5 20.26 0.014 0.01 0.007 10 0 0 10 0 0 10 0 0 6.1106e-05 3.872e-06 6.0493e-06 3.6889e-06 8.0743e-06 2.0519e-05 285.26 -2.0 20.0 -2.0 20.0 1.461 0.0 0.0 20250225T210149.6Z 9187.876269 30.01 47.53 243.14 77.42 242.73 0.0009821 0.000787 0.0001639 0.0001275 846 2 4 20250225 0.13701 26.24 0.3 -0.03129 -0.03334 0.12 15.37 1952 1 5 15.34 0.036 0.03 0.026 10 0 0 10 0 0 10 0 0 5.5839e-05 3.9399e-06 5.9822e-06 3.6441e-06 8.0367e-06 2.0413e-05 285.26 -2.0 20.0 -2.0 20.0 1.48 0.0 0.0 20250225T210501Z 9187.878484 30.01 48.22 243.65 78.08 243.01 0.0009769 0.0007921 0.0001683 0.0001303 846 2 4 20250225 0.13056 26.26 0.3 -0.03119 -0.03338 0.09 15.89 1888 1 5 30.79 0.057 0.048 0.044 10 0 0 10 0 0 10 0 0 5.8514e-05 4.0011e-06 7.0009e-06 3.597e-06 8.8295e-06 2.0039e-05 285.26 -2.0 20.0 -2.0 20.0 1.5 0.0 0.0 20250225T210813.3Z 9187.88071 30.02 48.91 244.15 78.74 243.29 0.001012 0.0007928 0.0001674 0.0001289 846 2 4 20250225 0.13365 26.27 0.3 -0.03128 -0.03338 0.07 15.58 1926 1 5 4.6 0.025 0.019 0.016 10 0 0 10 0 0 10 0 0 7.3341e-05 3.9273e-06 8.4817e-06 3.5501e-06 9.9983e-06 2.0481e-05 285.26 -2.0 20.0 -2.0 20.0 1.521 0.0 0.0 20250225T211121Z 9187.882882 30.0 49.6 244.63 79.39 243.56 0.000996 0.0008063 0.0001689 0.0001295 846 2 4 20250225 0.13242 26.29 0.3 -0.03135 -0.0334 0.05 15.5 1935 1 5 3.52 0.018 0.011 0.007 10 0 0 10 0 0 10 0 0 8.0099e-05 3.9176e-06 8.4489e-06 3.5065e-06 9.9512e-06 1.9882e-05 285.26 -2.0 20.0 -2.0 20.0 1.542 0.0 0.0 20250225T211428.3Z 9187.88505 30.01 50.28 245.1 80.04 243.83 0.001002 0.0007824 0.0001726 0.0001311 846 2 4 20250225 0.12886 26.3 0.3 -0.03131 -0.03339 0.06 15.68 1913 1 5 12.81 0.021 0.015 0.011 10 0 0 10 0 0 10 0 0 8.0313e-05 3.9562e-06 8.1058e-06 3.4577e-06 9.6597e-06 1.9724e-05 285.26 -2.0 20.0 -2.0 20.0 1.564 0.0 0.0 20250225T211735Z 9187.887211 30.01 50.96 245.56 80.69 244.08 0.0009708 0.0007773 0.0001787 0.0001347 846 2 4 20250225 0.12205 26.3 0.3 -0.03117 -0.0334 0.06 16.32 1838 1 5 22.85 0.043 0.034 0.03 10 0 0 10 0 0 10 0 0 7.3092e-05 4.0421e-06 7.3753e-06 3.4145e-06 9.077e-06 1.884e-05 285.26 -2.0 20.0 -2.0 20.0 1.587 0.0 0.0 20250225T212030.4Z 9187.889241 30.02 51.61 245.98 81.3 244.32 0.001088 0.0008253 0.0002893 0.0002141 846 2 4 20250225 0.047028 26.3 0.3 -0.03127 -0.03344 0.03 32.62 920 1 5 99.97 0.619 0.613 0.611 10 0 0 10 0 0 12 8 8 7.0282e-05 6.4469e-06 8.8745e-06 3.3727e-06 1.1476e-05 2.082e-05 285.26 -2.0 20.0 -2.0 20.0 1.609 0.0 0.0 20250225T212220.1Z 9187.89051 14.14 52.01 246.23 81.69 244.47 0.001107 0.0008682 0.0004514 0.0003419 846 2 4 20250225 0.03756 26.3 0.3 -0.03123 -0.03347 0.04 58.64 240 1 5 99.61 0.741 0.737 0.736 12 1 1 12 1 1 12 9 9 8.0265e-05 1.0003e-05 1.0005e-05 3.329e-06 1.4534e-05 2.1008e-05 285.26 -2.0 20.0 -2.0 20.0 1.624 0.0 0.0 20250225T212508.8Z 9187.892463 30.0 52.63 246.62 82.28 244.69 0.001023 0.0007885 0.0001934 0.0001434 846 2 4 20250225 0.10686 26.3 0.3 -0.03118 -0.03338 0.0 18.09 1658 1 5 25.47 0.086 0.079 0.074 10 0 0 10 0 0 10 0 0 7.4215e-05 4.1992e-06 9.6796e-06 3.2927e-06 1.1053e-05 1.9143e-05 285.26 -2.0 20.0 -2.0 20.0 1.646 0.0 0.0 20250225T215524.9Z 9187.913482 22.12 59.45 250.35 88.69 246.91 0.001801 0.001278 0.001801 0.001139 846 2 4 20250225 0.0023926 25.91 0.31 -0.02645 -0.02851 -0.03 650.37 33 1 5 99.95 1.85 1.841 1.85 12 1 1 12 9 1 12 9 9 -9.7376e-06 3.2534e-05 2.2454e-06 2.809e-06 3.2732e-05 2.837e-05 285.26 -2.0 20.0 -2.0 20.0 1.965 0.0 0.0 20250225T215821.8Z 9187.91553 30.02 60.12 250.68 89.32 247.1 0.00106 0.0007464 0.0002992 0.0001975 846 2 4 20250225 0.05487 25.92 0.29 -0.02641 -0.02836 -0.05 34.46 871 1 5 98.25 0.24 0.227 0.22 10 0 0 10 0 0 12 8 8 6.8584e-05 5.388e-06 7.2826e-06 2.7374e-06 9.4636e-06 1.6394e-05 285.26 -2.0 20.0 -2.0 20.0 2.005 0.0 0.0 20250225T220126.3Z 9187.917666 30.0 60.82 251.01 89.98 247.31 0.0009819 0.000762 0.0002883 0.0001848 846 2 4 20250225 0.063331 25.93 0.29 -0.02664 -0.02827 -0.05 24.91 1204 1 5 27.41 0.152 0.133 0.125 10 0 0 10 0 0 10 0 0 7.3325e-05 5.0582e-06 8.4453e-06 2.6837e-06 1.0203e-05 1.4869e-05 285.26 -2.0 20.0 -2.0 20.0 2.048 0.001 0.0 20250225T220430.2Z 9187.919794 30.02 61.52 251.34 90.64 247.51 0.00105 0.0007197 0.0003164 0.0001985 846 2 4 20250225 0.054897 25.93 0.29 -0.02665 -0.02845 -0.03 27.51 1091 1 5 14.98 0.194 0.178 0.17 10 0 0 10 0 0 10 0 0 6.934e-05 5.3753e-06 1.0109e-05 2.6303e-06 1.1747e-05 1.5559e-05 285.26 -2.0 20.0 -2.0 20.0 2.094 0.001 0.0 20250225T220734.4Z 9187.921926 30.02 62.23 251.66 91.3 247.7 0.001073 0.0007675 0.0003723 0.0002265 846 2 4 20250225 0.041897 25.95 0.28 -0.02636 -0.0285 -0.02 34.3 875 1 5 84.4 0.298 0.278 0.27 10 0 0 10 0 0 12 8 8 5.6526e-05 6.1777e-06 8.7107e-06 2.5796e-06 1.0986e-05 1.5553e-05 285.26 -2.0 20.0 -2.0 20.0 2.143 0.001 0.0 20250225T221028.1Z 9187.923936 29.96 62.89 251.96 91.92 247.88 0.001518 0.0009153 0.0009168 0.0005168 846 2 4 20250225 0.008304 25.97 0.3 -0.0259 -0.02799 -0.12 117.91 254 1 5 99.46 0.995 0.986 0.983 10 0 0 10 0 0 12 8 8 7.4257e-05 1.4694e-05 1.2623e-05 2.5351e-06 1.9537e-05 2.1538e-05 285.26 -2.0 20.0 -2.0 20.0 2.191 0.001 0.0 20250225T221240.2Z 9187.925465 5.97 63.4 252.18 92.39 248.02 0.008543 0.004113 0.007862 0.004346 846 2 4 20250225 0.00090006 25.98 0.36 -0.02754 -0.03075 0.66 1989.02 2 1 5 999.0 1.949 1.953 1.971 12 1 1 12 9 9 12 9 9 1.0298e-05 0.00012231 1.9306e-05 2.5018e-06 0.00012385 0.00011986 285.26 -2.0 20.0 -2.0 20.0 2.23 0.001 0.0 20250225T225754.9Z 9187.956886 31.22 73.93 256.22 102.2 250.51 0.08751 0.00764 0.06889 0.007158 846 2 4 20250225 9.4796e-05 25.64 0.27 -0.02215 -0.02651 1.85 3120.97 10 1 5 99.91 1.444 1.483 1.505 10 0 0 12 8 8 12 13 9 0.00039344 0.00029898 2.258e-05 1.6405e-06 0.00029983 0.00075253 285.26 -2.0 20.0 -2.0 20.0 3.595 0.003 0.0 20250225T225951Z 9187.958229 6.95 74.38 256.38 102.62 250.6 0.01325 0.002762 0.01325 0.002773 846 2 4 20250225 0.0013577 25.62 0.3 -0.02453 -0.02865 0.16 496.02 13 1 5 99.91 0.765 0.72 0.71 12 1 1 12 9 9 12 13 9 9.0584e-05 8.2748e-05 4.9378e-05 1.5996e-06 9.6374e-05 0.00011377 285.26 -2.0 20.0 -2.0 20.0 3.695 0.004 0.0 20250225T230853.8Z 9187.964512 30.4 76.51 257.08 104.6 251.02 0.06465 0.004687 0.04797 0.004121 846 2 4 20250225 0.00020612 25.54 0.39 -0.02383 -0.02732 0.14 1599.72 19 1 5 99.98 0.965 0.95 0.94 10 0 0 12 8 8 12 13 9 0.00019012 0.00017464 0.00017378 1.4063e-06 0.00024637 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