File name: Pandora94s1_GuatemalaCity_20250404_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260423T094058.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v1d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20250404_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20250404 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250404T141001.4Z 9225.590294 113 1 14.58 2 58.26 92.05 125.97 38.41 0.00 1 0.00 1 0 17 1.097e-02 8.482e-03 2.432e-03 1.494e-03 2.170157e-01 7.378113e-04 2.303175e-03 -6.000000e+00 6.045502e-03 228.00 -2.00 3.09 -2.00 315.44 0.00e+00 4.593459e-04 7.037997e-05 6.599135e-05 -6.000000e+00 2.706099e-04 285.80 -2.00 20.00 -2.00 314.76 0.00e+00 1.894 0.000 302.00 328.00 3 3.7029e+00 1.8993e-03 1.8526e-02 -6.0000e+00 1.5032e-02 2.9102e-02 2.1200e-03 9.7539e-03 -6.0000e+00 1.6331e-02 -2.5773e-03 1.2183e-03 4.7633e-03 -6.0000e+00 9.7365e-03 -4.2633e-03 5.5855e-04 1.3444e-03 -6.0000e+00 4.2024e-03 2.0956e-03 3.7595e-05 3.8152e-05 1.4478e-05 -6.0000e+00 2.6567e-04 -1.2114e-02 0.0000e+00 12 9 1 12 1 1 94.14 24.47 0.30 -0.01211 -0.01183 15 33 1 5 0 911.110 32.25 20.01 24.47 25.62 2.2 976.64 -1264 1139 -58 -2785 -2327 -2422 -585 -30 -813 -1016 -2538 -2160 81 -228 1240 738 460 845 1386 1484 1110 305 908 1203 494 848 414 25 -960 483 1017 1189 1267 -767 -3485 -3686 -2720 -1783 -434 18 -673 -458 -177 -528 301 116 -103 -303 -1023 -684 677 558 837 1244 670 898 857 527 486 71 791 1337 1862 2406 772 -242 -1115 -1679 37 503 804 837 308 680 207 -560 -1458 -2189 -1581 -1944 -1480 -1214 -2513 -1788 -566 -47 395 800 1104 817 634 73 -776 -914 -678 -187 223 1061 666 87 -52 -978 -1549 -430 -640 -799 -617 -552 11 811 1107 1146 865 300 -271 -699 -307 -255 238 481 332 386 599 146 619 81 -487 -277 35 24 185 -156 -404 -407 -1 213 201 400 590 167 -208 -848 -780 -343 322 -17 -750 -584 -589 -150 -9 -244 -316 -765 -661 27 -82 498 323 191 362 610 676 515 139 420 588 240 424 206 12 -437 212 473 590 642 -404 -1806 -1867 -1416 -1015 -279 13 -516 -344 -136 -409 229 89 -77 -230 -757 -501 519 436 684 1014 561 762 743 454 408 59 677 1174 1767 2319 748 -222 -989 -1438 33 477 829 859 317 701 200 -507 -1247 -1857 -1386 -1767 -1437 -1244 -2770 -1943 -654 -56 477 992 1370 980 727 80 -831 -935 -703 -205 259 1309 851 114 -63 -1135 -1759 -503 -800 -1014 -785 -732 15 1139 1584 1658 1199 414 -353 -884 -385 -321 311 654 465 533 834 196 809 102 -597 -335 45 32 250 -216 -566 -568 -1 322 302 613 918 255 -317 -1252 -1153 SS 20250404T141934.6Z 9225.596928 116 1 4.61 2 55.95 92.71 124.59 40.17 0.00 1 0.00 1 0 17 1.185e-02 8.935e-03 5.972e-03 3.902e-03 2.053203e-01 1.933120e-03 2.173798e-03 -6.000000e+00 6.527707e-03 228.00 -2.00 3.09 -2.00 315.17 0.00e+00 4.981400e-04 1.743649e-04 4.683626e-05 -6.000000e+00 2.921789e-04 285.80 -2.00 20.00 -2.00 314.52 0.00e+00 1.781 0.000 302.00 328.00 3 4.2472e+00 4.9648e-03 1.7440e-02 -6.0000e+00 1.6231e-02 3.2689e-02 5.5334e-03 9.2119e-03 -6.0000e+00 1.7633e-02 -4.4673e-03 3.1756e-03 4.4916e-03 -6.0000e+00 1.0513e-02 -4.2212e-03 1.4415e-03 1.2759e-03 -6.0000e+00 4.5381e-03 1.3625e-03 2.1052e-04 9.9664e-05 1.3945e-05 -6.0000e+00 2.8682e-04 -1.3031e-02 0.0000e+00 12 9 1 12 1 1 999.00 24.54 0.30 -0.01303 -0.01145 2 20 1 5 0 1533.520 32.25 20.01 24.54 26.83 2.2 982.52 412 668 640 -3191 -3581 -2515 453 275 1096 -562 -3032 265 -1588 -202 926 526 -342 886 1804 1484 2555 353 32 94 -415 1727 374 -969 -1647 94 1409 -777 2335 -360 -3527 -3215 -3626 -2150 129 -176 20 408 100 -400 63 -58 8 -221 -1085 -604 203 1042 1250 1221 794 528 674 404 862 -358 208 1318 1975 1407 897 564 -348 -1852 -191 444 392 518 438 831 214 -637 -926 -1906 -2726 -1454 -1238 -1734 -2783 -1636 -535 -267 -102 776 1302 958 835 183 -1187 -919 -778 155 657 1429 842 220 -336 -407 -2028 -315 -290 -560 -883 -155 487 738 905 436 965 493 -693 -934 -242 232 358 1213 77 -119 602 55 350 -53 -602 -235 -172 -210 162 -87 -206 -661 -126 -29 251 669 323 420 -480 -600 -411 124 215 207 -970 -1022 -686 129 82 361 -194 -1020 88 -560 -80 381 235 -156 412 858 733 1266 174 16 47 -219 921 199 -482 -808 44 694 -391 1238 -199 -1809 -1710 -2007 -1293 87 -131 15 318 80 -323 50 -47 6 -165 -834 -458 154 836 1049 1025 684 462 601 357 740 -309 184 1188 1834 1401 886 523 -312 -1612 -175 426 393 540 456 830 209 -584 -798 -1628 -2320 -1323 -1205 -1794 -3084 -1779 -620 -319 -124 965 1617 1150 957 199 -1223 -939 -806 168 754 1743 1064 284 -405 -484 -2297 -366 -359 -704 -1120 -204 661 1028 1282 627 1363 668 -893 -1163 -298 286 459 1670 107 -163 828 73 452 -66 -728 -280 -219 -276 215 -118 -282 -904 -183 -43 380 1001 492 624 -718 -866 -592 SS 20250404T142813.7Z 9225.602936 119 1 10.22 2 53.86 93.33 123.29 41.70 0.00 1 0.00 1 0 17 1.051e-02 8.422e-03 7.499e-04 5.313e-04 1.933552e-01 2.641157e-04 2.060238e-03 -6.000000e+00 5.791605e-03 228.00 -2.00 3.09 -2.00 314.81 0.00e+00 5.209833e-04 2.223545e-05 3.201103e-05 -6.000000e+00 2.592303e-04 285.80 -2.00 20.00 -2.00 314.19 0.00e+00 1.691 0.000 302.00 328.00 3 1.6181e+00 6.7561e-04 1.6534e-02 -6.0000e+00 1.4401e-02 8.0806e-03 7.5164e-04 8.7070e-03 -6.0000e+00 1.5645e-02 -4.3305e-04 4.3140e-04 4.2430e-03 -6.0000e+00 9.3272e-03 -4.3404e-03 1.9326e-04 1.2124e-03 -6.0000e+00 4.0264e-03 2.0960e-02 5.7194e-05 1.3458e-05 1.3539e-05 -6.0000e+00 2.5447e-04 -1.3059e-02 0.0000e+00 12 9 1 12 1 1 99.69 24.62 0.30 -0.01306 -0.01263 108 320 1 5 0 93.690 32.25 20.00 24.62 27.87 2.1 985.96 11 473 437 -2235 -2946 -2285 -615 132 940 -630 -2505 -1737 -832 -33 974 657 426 1022 1072 1637 880 857 1283 1076 431 972 335 -338 -869 185 939 585 1448 -942 -3233 -3301 -2730 -1602 -653 -215 -619 -436 -74 -355 273 -11 -334 -209 -1014 -512 673 684 1023 1177 778 1063 951 564 320 271 914 1237 1643 2243 647 -363 -927 -1688 72 560 640 736 498 820 160 -596 -1271 -2009 -1654 -1842 -1664 -1327 -2167 -1810 -741 -314 246 578 1158 796 639 78 -654 -854 -494 -231 153 1165 942 157 -197 -944 -1440 -487 -562 -877 -671 -395 59 704 1212 1001 878 359 -218 -550 -392 -433 207 573 226 290 639 205 618 238 -377 -84 168 50 42 -328 -418 -348 143 158 110 482 431 24 -92 -685 -928 4 176 163 -776 -944 -748 -199 48 355 -249 -960 -668 -337 -14 468 324 213 524 539 847 465 441 670 595 240 556 190 -187 -464 95 507 321 815 -552 -1823 -1814 -1574 -1023 -460 -162 -486 -352 -61 -285 224 -9 -267 -167 -788 -391 537 562 848 1022 669 924 845 498 277 233 804 1132 1572 2202 637 -343 -831 -1508 65 547 661 767 519 848 160 -553 -1133 -1744 -1429 -1746 -1653 -1364 -2314 -1991 -844 -374 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