File name: Pandora94s1_GuatemalaCity_20250425_L2Fit_fout2c3d20250101p1-8.txt File generation date: 20250924T155222.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora94_OF_v1d20240409.txt Instrument calibration file used: Pandora94s1_CF_v3d20250101.txt Level 1 file used: Pandora94s1_GuatemalaCity_20250425_L1_smca1c3d20250101p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20250425 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 2 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0134 305.1540 305.2945 305.4351 305.5756 305.7162 305.8567 305.9972 306.1377 306.2782 306.4187 306.5592 306.6996 306.8401 306.9805 307.1209 307.2614 307.4018 307.5422 307.6825 307.8229 307.9633 308.1036 308.2440 308.3843 308.5246 308.6649 308.8052 308.9455 309.0858 309.2261 309.3663 309.5066 309.6468 309.7870 309.9272 310.0674 310.2076 310.3478 310.4880 310.6281 310.7683 310.9084 311.0485 311.1886 311.3287 311.4688 311.6089 311.7490 311.8890 312.0291 312.1691 312.3091 312.4491 312.5891 312.7291 312.8691 313.0091 313.1490 313.2890 313.4289 313.5688 313.7087 313.8486 313.9885 314.1284 314.2683 314.4081 314.5480 314.6878 314.8276 314.9675 315.1073 315.2471 315.3868 315.5266 315.6664 315.8061 315.9458 316.0856 316.2253 316.3650 316.5047 316.6443 316.7840 316.9237 317.0633 317.2029 317.3426 317.4822 317.6218 317.7614 317.9009 318.0405 318.1801 318.3196 318.4591 318.5986 318.7382 318.8777 319.0171 319.1566 319.2961 319.4355 319.5750 319.7144 319.8538 319.9932 320.1326 320.2720 320.4114 320.5507 320.6901 320.8294 320.9688 321.1081 321.2474 321.3867 321.5260 321.6652 321.8045 321.9437 322.0830 322.2222 322.3614 322.5006 322.6398 322.7790 322.9182 323.0573 323.1965 323.3356 323.4747 323.6138 323.7529 323.8920 324.0311 324.1702 324.3092 324.4483 324.5873 324.7263 324.8653 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250425T130543.0Z 9246.545636 129 1 29.96 2 71.03 80.60 45.24 102.31 0.00 1 0.00 1 0 17 1.891e-02 7.966e-03 2.519e-03 6.189e-04 3.486856e-01 3.103386e-04 3.721641e-03 -6.000000e+00 1.061732e-02 228.77 -2.00 3.09 -2.00 317.62 0.00e+00 7.383146e-04 4.889969e-05 3.448009e-04 -6.000000e+00 4.693810e-04 286.12 -2.00 20.00 -2.00 316.86 0.00e+00 3.040 0.000 302.00 328.00 3 1.8780e+00 8.2340e-04 2.9918e-02 -6.0000e+00 2.6462e-02 -3.2974e-02 9.2445e-04 1.6013e-02 -6.0000e+00 2.8559e-02 -1.8125e-03 5.8502e-04 7.8551e-03 -6.0000e+00 1.7008e-02 -1.1811e-03 3.0681e-04 2.2295e-03 -6.0000e+00 7.5377e-03 4.2435e-03 -8.4965e-04 1.5846e-05 2.0732e-05 -6.0000e+00 4.5843e-04 -5.7248e-02 0.0000e+00 11 8 0 10 0 0 95.98 24.16 0.29 -0.05725 -0.06363 232 232 1 5 0 129.100 32.00 20.01 24.16 24.10 2.3 969.45 900000 -2518 -2433 -2523 -6281 -8446 -7169 -5869 -4296 -2206 -4361 -6726 -4496 -3290 -1125 415 169 514 936 768 2470 713 644 837 981 226 1280 -101 -1284 -2157 -883 293 289 1949 -1093 -4084 -3787 -3266 -1735 -255 182 -302 -41 73 20 687 397 8 -95 -820 -276 914 829 1179 1336 913 1181 861 383 137 12 956 1275 1839 2580 953 -202 -647 -1341 -30 741 870 683 378 701 40 -842 -1702 -2221 -1921 -2032 -1617 -1162 -2188 -1715 -728 -169 325 578 1243 924 609 -21 -892 -835 -424 -357 152 1174 739 -48 -351 -1206 -1667 -583 -709 -894 -644 -425 121 767 1410 1074 883 308 -252 -472 -251 -215 297 572 241 301 624 207 654 -74 -641 -104 176 0 25 -283 -504 -395 -20 59 93 417 359 -68 -258 -777 900000 -191 -203 -217 -515 -623 -516 -457 -379 -215 -454 -703 -490 -419 -151 65 30 94 181 156 516 155 137 185 234 53 312 -25 -325 -518 -213 71 78 579 -345 -1209 -1105 -1059 -608 -108 84 -153 -22 37 10 352 206 4 -52 -449 -143 508 502 710 857 609 806 606 269 93 8 665 909 1440 2064 779 -162 -489 -1003 -24 651 792 649 357 632 35 -669 -1312 -1658 -1531 -1774 -1515 -1152 -2237 -1816 -785 -195 377 690 1478 1060 676 -23 -925 -848 -444 -401 182 1503 982 -63 -448 -1470 -1978 -711 -879 -1167 -877 -583 168 1149 2172 1641 1358 462 -363 -638 -339 -305 433 859 370 450 939 300 934 -102 -870 -141 251 -1 39 -451 -792 -646 -34 102 163 749 653 -121 -452 -1309 SS 20250425T131100.4Z 9246.549310 132 1 30.01 2 69.76 80.86 44.01 102.88 0.00 1 0.00 1 0 17 1.760e-02 8.199e-03 2.048e-03 6.023e-04 3.302614e-01 3.016923e-04 3.529285e-03 -6.000000e+00 9.885392e-03 228.77 -2.00 3.09 -2.00 317.31 0.00e+00 8.561450e-04 4.389786e-05 2.634985e-04 -6.000000e+00 4.369909e-04 286.12 -2.00 20.00 -2.00 316.56 0.00e+00 2.862 0.000 302.00 328.00 3 1.9945e+00 7.9647e-04 2.8201e-02 -6.0000e+00 2.4638e-02 -2.3128e-02 8.9096e-04 1.5122e-02 -6.0000e+00 2.6590e-02 -3.1020e-03 5.4933e-04 7.4298e-03 -6.0000e+00 1.5836e-02 -1.4987e-03 2.8447e-04 2.1308e-03 -6.0000e+00 7.0186e-03 4.4511e-03 -8.1626e-04 1.5445e-05 1.9948e-05 -6.0000e+00 4.2677e-04 -5.7840e-02 0.0000e+00 11 8 0 10 0 0 74.35 24.18 0.27 -0.05784 -0.06397 216 216 1 5 0 138.910 32.00 20.01 24.18 24.63 2.3 972.24 900000 -2057 -1528 -1490 -5856 -7413 -6826 -3977 -3278 -2060 -4907 -5667 -4529 -3308 -931 682 613 631 1393 1951 2272 594 899 1691 1449 599 1084 -72 -972 -1854 -295 1287 904 1686 -1158 -3899 -4032 -3109 -1608 -46 -147 -310 -354 110 -290 680 209 -143 28 -902 -587 981 685 1150 1172 680 1202 899 593 192 248 730 1429 1930 2418 849 -265 -815 -1467 251 666 958 768 500 632 -83 -919 -1679 -2338 -1774 -2038 -1636 -1249 -2276 -1813 -836 -216 407 664 1170 926 615 45 -681 -855 -473 -322 88 1238 762 54 -391 -1191 -1619 -517 -714 -1019 -707 -436 226 769 1320 1140 950 396 -260 -568 -275 -295 264 546 198 238 703 213 608 -47 -616 -109 154 -3 131 -302 -501 -350 59 56 111 425 265 -162 -232 -741 900000 -199 -161 -161 -606 -684 -617 -381 -358 -250 -582 -726 -553 -470 -152 129 129 139 321 430 522 141 209 405 374 166 312 -21 -265 -477 -76 360 280 578 -388 -1320 -1349 -1062 -642 -21 -72 -166 -198 63 -169 393 122 -83 16 -515 -339 566 431 765 780 470 846 652 428 136 173 525 1051 1558 1999 715 -217 -628 -1117 204 594 887 741 480 581 -75 -784 -1308 -1761 -1417 -1787 -1541 -1246 -2344 -1932 -950 -251 476 800 1406 1120 687 48 -705 -865 -493 -360 105 1575 1007 70 -497 -1440 -1903 -625 -918 -1326 -959 -595 324 1143 2018 1786 1442 585 -368 -783 -379 -409 378 807 299 350 1043 304 854 -64 -819 -144 215 -5 197 -470 -792 -556 97 98 191 744 470 -281 -398 -1219 SS 20250425T131602.7Z 9246.552809 135 1 8.16 2 68.56 81.11 42.84 103.44 0.00 1 0.00 1 0 17 1.479e-02 8.382e-03 7.539e-03 2.510e-03 3.103999e-01 1.257237e-03 3.315441e-03 -6.000000e+00 8.306214e-03 228.77 -2.00 3.09 -2.00 317.06 0.00e+00 1.029905e-03 1.712614e-04 1.684620e-04 -6.000000e+00 3.671801e-04 286.12 -2.00 20.00 -2.00 316.31 0.00e+00 2.711 0.000 302.00 328.00 3 3.5983e+00 3.3027e-03 2.6645e-02 -6.0000e+00 2.0702e-02 -1.4562e-02 3.6933e-03 1.4197e-02 -6.0000e+00 2.2342e-02 6.8202e-04 2.2371e-03 6.9666e-03 -6.0000e+00 1.3306e-02 -3.1509e-03 1.1418e-03 2.0429e-03 -6.0000e+00 5.8974e-03 1.0345e-03 -8.8213e-04 6.4211e-05 1.9292e-05 -6.0000e+00 3.5859e-04 -5.7890e-02 0.0000e+00 12 9 1 12 1 1 97.48 24.21 0.33 -0.05789 -0.06452 10 40 1 5 0 741.800 32.00 20.00 24.21 25.29 2.3 975.11 900000 -1422 -2064 -2232 -4023 -3792 -4076 -4391 -2476 -507 -2952 -5200 -2320 -2329 -1260 1434 1207 2199 1915 1415 1113 1847 672 789 687 781 520 -1469 -460 -763 -657 -3 985 2106 -1172 -4201 -3022 -4081 -2519 -711 764 228 -116 -286 -330 533 -136 -227 -140 -916 -369 660 886 1417 1323 477 1012 1374 538 -80 -166 1157 1469 1604 2107 727 -761 -218 -1008 -92 935 1090 657 927 816 214 -862 -1814 -2232 -2504 -2168 -1439 -1635 -1989 -1882 -871 -77 75 913 1217 1044 479 366 -1041 -733 -415 -89 -45 1112 800 78 -376 -1092 -1235 -714 -478 -795 -480 -387 199 572 1266 1212 974 135 -479 -599 -594 -263 259 637 399 74 681 165 205 273 -765 -84 320 -23 105 -247 -493 -253 271 252 75 176 398 -150 -133 -966 900000 -153 -244 -271 -456 -413 -437 -514 -325 -67 -414 -724 -331 -389 -244 316 271 509 468 364 300 502 181 220 205 247 172 -493 -142 -221 -192 -1 316 742 -438 -1466 -1027 -1562 -1043 -353 409 125 -66 -171 -198 317 -82 -135 -82 -533 -216 411 563 950 942 353 720 998 391 -60 -124 834 1150 1307 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