File name: Pandora94s1_GuatemalaCity_20250505_L2Fit_fout2c3d20250101p1-8.txt File generation date: 20250924T155440.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora94_OF_v1d20240409.txt Instrument calibration file used: Pandora94s1_CF_v3d20250101.txt Level 1 file used: Pandora94s1_GuatemalaCity_20250505_L1_smca1c3d20250101p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20250505 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 2 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0134 305.1540 305.2945 305.4351 305.5756 305.7162 305.8567 305.9972 306.1377 306.2782 306.4187 306.5592 306.6996 306.8401 306.9805 307.1209 307.2614 307.4018 307.5422 307.6825 307.8229 307.9633 308.1036 308.2440 308.3843 308.5246 308.6649 308.8052 308.9455 309.0858 309.2261 309.3663 309.5066 309.6468 309.7870 309.9272 310.0674 310.2076 310.3478 310.4880 310.6281 310.7683 310.9084 311.0485 311.1886 311.3287 311.4688 311.6089 311.7490 311.8890 312.0291 312.1691 312.3091 312.4491 312.5891 312.7291 312.8691 313.0091 313.1490 313.2890 313.4289 313.5688 313.7087 313.8486 313.9885 314.1284 314.2683 314.4081 314.5480 314.6878 314.8276 314.9675 315.1073 315.2471 315.3868 315.5266 315.6664 315.8061 315.9458 316.0856 316.2253 316.3650 316.5047 316.6443 316.7840 316.9237 317.0633 317.2029 317.3426 317.4822 317.6218 317.7614 317.9009 318.0405 318.1801 318.3196 318.4591 318.5986 318.7382 318.8777 319.0171 319.1566 319.2961 319.4355 319.5750 319.7144 319.8538 319.9932 320.1326 320.2720 320.4114 320.5507 320.6901 320.8294 320.9688 321.1081 321.2474 321.3867 321.5260 321.6652 321.8045 321.9437 322.0830 322.2222 322.3614 322.5006 322.6398 322.7790 322.9182 323.0573 323.1965 323.3356 323.4747 323.6138 323.7529 323.8920 324.0311 324.1702 324.3092 324.4483 324.5873 324.7263 324.8653 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250505T125958.3Z 9256.541647 124 1 23.19 2 71.53 77.24 150.74 356.99 0.00 1 0.00 1 0 25 2.764e-02 9.255e-03 2.099e-02 3.551e-03 3.566503e-01 1.779353e-03 3.827507e-03 -6.000000e+00 1.552333e-02 228.77 -2.00 3.09 -2.00 318.20 0.00e+00 8.300624e-04 3.316315e-04 5.552163e-04 -6.000000e+00 6.866383e-04 286.29 -2.00 20.00 -2.00 317.45 0.00e+00 3.118 0.000 302.00 328.00 3 4.6619e+00 4.7881e-03 3.0728e-02 -6.0000e+00 3.8688e-02 6.7849e-03 5.4253e-03 1.6598e-02 -6.0000e+00 4.1749e-02 -1.1378e-02 3.6497e-03 8.1470e-03 -6.0000e+00 2.4866e-02 3.7747e-04 1.9594e-03 2.3053e-03 -6.0000e+00 1.1025e-02 2.3911e-04 -1.0246e-03 9.1811e-05 2.0987e-05 -6.0000e+00 6.7008e-04 -5.8747e-02 0.0000e+00 12 9 1 12 1 1 98.32 24.53 0.34 -0.05875 -0.06645 8 12 1 5 0 2576.450 32.25 20.01 24.53 26.23 2.2 977.46 900000 36 -9790 631 -13676 -4827 -10663 -8588 -9850 4300 -790 -5391 -2646 -696 -9849 -641 -1236 -3001 2184 -245 3170 -3009 -11 5612 1443 746 1888 -211 1841 -1885 -2680 1298 -721 721 -2331 -3966 -2674 -5158 -1557 -1785 1494 -928 -1838 -1873 2087 372 1347 36 -19 -971 -1877 902 1002 1117 1310 2463 1964 262 741 324 16 1813 2074 2409 2533 1584 -425 181 -2248 151 764 999 117 190 801 -210 -1729 -1654 -3456 -2241 -2152 -2031 -1307 -1612 -1738 -953 -277 619 858 1144 844 1262 190 -1673 -1152 -445 -143 426 1074 795 239 -476 -1073 -1999 -999 -572 -914 -1097 -516 415 1105 1608 1082 503 419 26 -1037 -509 -5 563 219 589 165 461 255 790 -283 -815 -431 58 -215 -384 -133 -609 -515 145 43 381 484 414 -193 -54 -704 900000 2 -580 35 -800 -227 -524 -452 -604 258 -52 -366 -186 -57 -1047 -73 -159 -414 303 -37 480 -494 -2 861 249 138 362 -41 329 -328 -478 248 -156 172 -595 -935 -613 -1352 -425 -599 572 -398 -831 -879 950 172 624 17 -9 -448 -890 451 501 594 741 1425 1172 164 457 195 9 1097 1366 1749 1849 1178 -296 127 -1589 104 612 874 108 174 695 -171 -1264 -1188 -2433 -1667 -1710 -1835 -1219 -1617 -1816 -1063 -308 721 1028 1370 976 1434 199 -1641 -1100 -457 -154 512 1353 1084 322 -601 -1315 -2286 -1172 -739 -1168 -1468 -723 609 1645 2564 1782 808 630 38 -1443 -704 -8 818 342 931 256 692 392 1146 -398 -1081 -571 84 -321 -614 -219 -1027 -855 256 80 686 892 772 -351 -99 -1239 SS 20250505T130524.7Z 9256.545425 127 1 29.69 2 70.25 77.48 150.80 359.56 0.00 1 0.00 1 0 25 3.144e-02 8.871e-03 2.894e-02 4.629e-03 3.335767e-01 2.306595e-03 3.541159e-03 -6.000000e+00 1.766168e-02 228.77 -2.00 3.09 -2.00 318.44 0.00e+00 1.092527e-03 4.579802e-04 3.347197e-04 -6.000000e+00 7.811999e-04 286.29 -2.00 20.00 -2.00 317.69 0.00e+00 2.928 0.000 302.00 328.00 3 5.3602e+00 6.2306e-03 2.8775e-02 -6.0000e+00 4.4017e-02 2.3750e-02 7.1086e-03 1.5385e-02 -6.0000e+00 4.7500e-02 -7.1045e-03 4.8704e-03 7.6335e-03 -6.0000e+00 2.8291e-02 -2.3489e-03 2.6169e-03 2.2563e-03 -6.0000e+00 1.2544e-02 1.4173e-04 -1.0002e-03 1.2107e-04 2.0100e-05 -6.0000e+00 7.6236e-04 -5.8968e-02 0.0000e+00 11 8 0 10 0 0 99.98 24.56 0.24 -0.05897 -0.06648 24 24 1 5 0 1236.920 32.25 20.00 24.56 26.64 2.2 980.31 900000 7254 -8133 10621 -14538 -4394 761 -18763 7420 -1191 -353 -3 -3365 46 -7946 5291 -3076 -15 3031 679 7399 -3895 4794 1611 -5631 -1315 249 -216 -1995 -3300 -3887 711 -1345 -992 -1569 -2513 -1087 -7154 -411 907 -1195 235 844 1704 2161 -763 -1237 1061 -327 -1688 -1602 -291 164 1440 1838 1113 1457 -198 216 293 -595 1148 1972 2258 2219 763 295 -1161 -1803 -306 1090 756 708 1114 551 -404 -1106 -1264 -3114 -2610 -736 -1585 -1011 -1955 -1493 -1175 -290 672 1475 1449 705 601 317 -1619 -585 -1672 -18 549 1471 1037 -165 -501 -747 -1941 -848 -419 -1289 -759 -407 202 293 1167 1134 929 38 -138 -1004 -905 -469 281 457 276 -143 994 -93 693 592 -947 -170 89 -20 425 -83 -46 -781 -197 181 496 181 278 147 -136 -896 900000 331 -474 527 -853 -204 33 -1075 375 -74 -23 0 -229 4 -789 540 -380 -2 390 94 999 -599 662 238 -961 -228 44 -38 -338 -530 -635 123 -262 -215 -353 -517 -217 -1689 -107 286 -452 96 356 739 940 -342 -562 464 -143 -741 -713 -138 76 705 953 600 801 -114 122 161 -327 640 1189 1497 1600 561 199 -741 -1135 -205 840 640 624 971 463 -317 -776 -805 -1935 -1718 -549 -1354 -958 -2003 -1450 -1224 -322 780 1753 1727 815 640 337 -1603 -559 -1743 -19 644 1924 1466 -232 -657 -890 -2166 -970 -529 -1723 -1055 -592 284 446 1889 1881 1492 57 -207 -1423 -1281 -692 409 711 439 -223 1489 -135 1027 844 -1283 -228 131 -30 666 -135 -77 -1351 -362 352 908 341 530 271 -261 -1648 SS 20250505T131038.8Z 9256.549060 130 1 30.00 2 69.01 77.71 150.80 2.03 0.00 1 0.00 1 0 25 1.525e-02 7.820e-03 3.867e-03 1.125e-03 3.180519e-01 5.637708e-04 3.405974e-03 -6.000000e+00 8.567355e-03 228.77 -2.00 3.09 -2.00 317.33 0.00e+00 5.625855e-04 8.253665e-05 2.736121e-04 -6.000000e+00 3.789178e-04 286.29 -2.00 20.00 -2.00 316.57 0.00e+00 2.766 0.000 302.00 328.00 3 3.2855e+00 1.4870e-03 2.7230e-02 -6.0000e+00 2.1352e-02 -1.4926e-02 1.6657e-03 1.4584e-02 -6.0000e+00 2.3040e-02 -2.7151e-03 1.0298e-03 7.1488e-03 -6.0000e+00 1.3723e-02 -2.2838e-03 5.3329e-04 2.0238e-03 -6.0000e+00 6.0852e-03 1.3427e-03 -8.9146e-04 2.8804e-05 1.9307e-05 -6.0000e+00 3.6976e-04 -5.9753e-02 0.0000e+00 11 8 0 10 0 0 86.25 24.58 0.35 -0.05975 -0.06645 59 59 1 5 0 508.330 32.25 20.00 24.58 27.21 2.2 983.03 900000 1227 -1080 -303 -2035 -7619 -5783 -4233 -2301 -494 -1291 -5109 -3089 -3457 -839 1292 677 363 1166 659 1896 352 -218 763 689 996 1328 499 -1233 -2129 -610 232 932 1348 -1214 -4285 -3747 -2724 -2225 -333 -30 -484 -121 16 -138 198 226 -294 -579 -255 -677 741 817 1265 1490 874 1102 964 413 10 272 811 1247 1921 2631 799 -349 -517 -1181 177 859 900 761 306 450 -37 -922 -1772 -2190 -1781 -1895 -1538 -1203 -2088 -1806 -867 -85 242 593 1042 887 828 137 -736 -834 -580 -160 -57 1160 668 85 -444 -1146 -1571 -494 -623 -858 -655 -327 120 651 1340 1022 759 398 -44 -556 -297 -413 246 565 126 270 612 213 493 58 -595 -167 69 13 171 -237 -442 -443 -40 219 50 456 258 -48 -224 -780 900000 114 -112 -32 -201 -696 -509 -400 -245 -58 -160 -641 -399 -525 -133 233 136 76 257 153 453 87 -53 191 186 284 362 136 -348 -566 -161 67 268 430 -409 -1351 -1156 -927 -892 -148 -15 -256 -67 9 -79 113 130 -167 -325 -141 -380 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