File name: Pandora94s1_GuatemalaCity_20250513_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260423T095707.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v1d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20250513_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20250513 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250513T140116.0Z 9264.584212 304 1 31.90 2 56.69 77.19 116.40 248.64 0.00 1 0.00 1 0 17 1.535e-02 9.939e-03 6.500e-03 3.028e-03 2.171513e-01 1.487973e-03 2.294370e-03 -6.000000e+00 8.478314e-03 228.77 -2.00 3.09 -2.00 316.41 0.00e+00 7.675170e-04 1.747140e-04 1.197679e-04 -6.000000e+00 3.794236e-04 286.43 -2.00 20.00 -2.00 315.64 0.00e+00 1.815 0.000 302.00 328.00 3 5.6309e+00 3.8834e-03 1.8020e-02 -6.0000e+00 2.1115e-02 3.7152e-02 4.3542e-03 9.8128e-03 -6.0000e+00 2.2923e-02 -3.6846e-03 2.5326e-03 4.7970e-03 -6.0000e+00 1.3663e-02 -4.9807e-03 1.2087e-03 1.3941e-03 -6.0000e+00 5.8918e-03 3.2307e-04 1.3651e-04 7.8362e-05 1.3510e-05 -6.0000e+00 3.7153e-04 -1.2990e-02 0.0000e+00 12 8 8 10 0 0 9.19 25.04 0.27 -0.01299 -0.01196 8 8 1 5 0 3986.190 32.75 20.01 25.04 31.44 2.0 998.90 -375 -91 -374 -430 -5796 -4973 614 2038 1433 -210 -7012 -1571 -2091 -865 1327 1157 166 3088 -1571 2126 1061 703 902 1173 1398 1158 -493 -1670 -1555 458 427 953 1922 -745 -3757 -4870 -2860 -2433 -1323 716 58 -59 160 -766 41 502 -30 -537 -1760 349 317 1110 729 726 969 726 1135 812 30 -232 891 1703 2313 2208 365 -310 -862 -925 241 703 730 915 259 1246 524 -777 -2216 -2473 -2016 -2747 -2466 -1072 -2519 -1954 -1497 -260 417 924 1199 1185 722 144 -361 -1718 -588 -593 591 1130 1480 421 -502 -1383 -1465 -903 -851 -922 -752 118 89 970 1352 1150 724 487 -334 -1218 -269 -1137 728 468 587 564 560 -42 -15 -487 -277 -386 563 -33 616 -511 -645 -546 45 91 303 618 454 13 132 -580 -1083 -71 -18 -76 -80 -979 -805 101 374 294 -45 -1542 -333 -506 -236 402 380 51 1046 -524 708 362 234 306 420 524 451 -193 -609 -573 162 161 348 756 -307 -1431 -2012 -1164 -1156 -753 464 37 -39 109 -530 28 341 -20 -346 -1114 234 207 770 532 557 757 577 917 652 23 -182 712 1459 2139 2014 336 -279 -712 -734 202 626 710 924 262 1204 475 -687 -1779 -1865 -1574 -2453 -2275 -1077 -2724 -2172 -1782 -306 515 1173 1523 1450 816 160 -362 -1662 -597 -665 724 1423 1987 559 -625 -1708 -1692 -1081 -1049 -1196 -1015 165 121 1391 2039 1757 1063 709 -445 -1518 -331 -1473 999 650 839 793 823 -59 -20 -626 -357 -492 711 -45 876 -750 -954 -778 67 145 494 1030 769 21 211 -899 -1633 SS 20250513T141156.3Z 9264.591624 307 1 30.85 2 54.17 77.47 118.71 248.81 0.00 1 0.00 1 0 17 1.337e-02 9.776e-03 5.591e-03 2.845e-03 2.026510e-01 1.403695e-03 2.141117e-03 -6.000000e+00 7.387874e-03 228.77 -2.00 3.09 -2.00 316.11 0.00e+00 3.652859e-04 1.536524e-04 1.554090e-04 -6.000000e+00 3.306340e-04 286.43 -2.00 20.00 -2.00 315.36 0.00e+00 1.704 0.000 302.00 328.00 3 5.6353e+00 3.6512e-03 1.6860e-02 -6.0000e+00 1.8399e-02 2.7672e-02 4.0870e-03 9.1036e-03 -6.0000e+00 1.9975e-02 9.5765e-04 2.3654e-03 4.4442e-03 -6.0000e+00 1.1906e-02 -6.1304e-03 1.1109e-03 1.2409e-03 -6.0000e+00 5.1337e-03 3.6355e-04 6.1920e-05 7.3613e-05 1.2647e-05 -6.0000e+00 3.2377e-04 -1.2512e-02 0.0000e+00 12 8 8 10 0 0 -33.45 25.12 0.27 -0.01251 -0.01205 8 8 1 5 0 3855.460 32.50 20.00 25.12 31.68 1.9 999.14 -1988 1859 652 -1774 -3240 -2169 -639 2212 806 -2785 -2074 -1257 -1384 -1437 1695 -330 383 -678 959 3302 1429 63 1346 1423 -304 1093 -464 -1932 -2257 -232 2447 181 1487 -308 -2932 -5180 -2901 -1817 -411 -546 -417 102 469 -907 216 989 -233 -931 -1281 -1213 258 1168 1406 1436 442 1438 1216 669 518 348 559 1040 1985 2431 798 -316 -1066 -1434 -615 269 897 565 455 1160 198 -732 -1634 -2771 -2458 -2295 -1880 -1290 -2305 -1554 -528 32 157 1292 1233 903 406 183 -1105 -1441 -954 -341 251 1230 1320 296 -463 -1909 -1848 -728 -695 -586 -454 -761 315 877 1507 923 914 214 -15 -1030 -784 -663 477 640 467 817 551 277 818 135 -1218 -815 -30 143 45 -345 -280 -539 -45 317 42 741 440 168 -88 -633 -934 -437 420 150 -379 -606 -388 -121 462 190 -702 -494 -301 -374 -440 517 -111 129 -239 342 1192 534 23 500 559 -127 468 -199 -774 -832 -90 978 72 631 -135 -1186 -2089 -1264 -918 -248 -352 -289 72 341 -669 157 711 -164 -637 -851 -797 177 849 1068 1145 363 1187 1027 563 425 284 469 866 1773 2303 759 -272 -912 -1181 -536 248 897 589 474 1158 187 -669 -1346 -2159 -1978 -2090 -1764 -1327 -2540 -1757 -590 39 199 1669 1601 1132 471 207 -1136 -1415 -987 -387 291 1565 1672 397 -582 -2224 -2169 -819 -866 -768 -618 -1013 431 1270 2287 1422 1346 293 -21 -1284 -970 -857 658 889 671 1154 761 394 1092 173 -1479 -973 -38 194 65 -471 -384 -763 -67 503 68 1151 696 260 -140 -981 -1405 SS 20250513T142127.1Z 9264.598230 310 1 29.80 2 51.93 77.69 120.77 248.92 0.00 1 0.00 1 0 17 1.403e-02 9.753e-03 4.929e-03 2.729e-03 1.924067e-01 1.346095e-03 2.026897e-03 -6.000000e+00 7.750522e-03 228.77 -2.00 3.09 -2.00 315.83 0.00e+00 2.901554e-04 1.379357e-04 1.158256e-04 -6.000000e+00 3.468387e-04 286.43 -2.00 20.00 -2.00 315.10 0.00e+00 1.618 0.000 302.00 328.00 3 5.6259e+00 3.4914e-03 1.6000e-02 -6.0000e+00 1.9303e-02 2.4527e-02 3.8995e-03 8.6252e-03 -6.0000e+00 2.0954e-02 -5.2813e-04 2.2466e-03 4.1997e-03 -6.0000e+00 1.2490e-02 -4.9660e-03 1.0425e-03 1.1663e-03 -6.0000e+00 5.3864e-03 4.0245e-04 1.4522e-04 7.0306e-05 1.2434e-05 -6.0000e+00 3.3960e-04 -1.3561e-02 0.0000e+00 12 8 8 10 0 0 89.16 25.16 0.28 -0.01356 -0.01247 8 8 1 5 0 3724.570 32.75 20.01 25.16 31.88 1.9 1000.50 2154 -606 951 -4918 -4262 -3958 -1900 1825 590 -1065 -3984 -1576 -706 -81 1887 40 322 2013 51 3371 646 306 1979 659 1577 664 322 -1264 53 761 2214 818 1058 -2331 -3293 -3478 -3010 -2171 -714 -165 -364 -487 -490 53 -68 935 271 -607 -1272 -714 79 311 1141 905 271 903 635 386 607 -64 904 1237 1669 3051 407 -376 -1146 -1934 202 693 778 1256 386 827 390 -711 -1628 -2457 -1876 -2582 -2135 -1019 -1944 -1833 -725 -195 680 846 1530 1084 387 196 -1062 -1355 -1110 -574 253 1351 942 407 -41 -1071 -1752 -936 -538 -821 -604 -753 185 1003 1510 1236 751 320 -272 -978 -208 -713 497 387 339 784 706 -391 445 125 -691 -661 11 -308 312 -92 -702 -699 224 -99 321 699 777 106 223 -707 -1090 517 -159 247 -1225 -910 -812 -410 430 157 -297 -1085 -423 -211 -25 635 15 120 757 20 1334 266 123 799 285 708 311 150 -548 21 288 870 346 484 -1121 -1434 -1478 -1407 -1178 -424 -113 -269 -371 -383 41 -52 715 202 -439 -895 -493 57 240 915 704 216 726 522 316 483 -51 733 1078 1568 3006 406 -338 -945 -1665 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