File name: Pandora94s1_GuatemalaCity_20250514_L2Fit_fwvt1c4d20250225p1-8.txt File generation date: 20260423T095205.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v1d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20250514_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20250514 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1624 1774 Nominal wavelengths inside fitting window [nm]: 492.0012 492.1219 492.2426 492.3632 492.4839 492.6045 492.7251 492.8457 492.9663 493.0869 493.2075 493.3280 493.4485 493.5690 493.6895 493.8100 493.9304 494.0509 494.1713 494.2917 494.4121 494.5324 494.6528 494.7731 494.8934 495.0137 495.1340 495.2543 495.3746 495.4948 495.6150 495.7352 495.8554 495.9756 496.0957 496.2159 496.3360 496.4561 496.5762 496.6962 496.8163 496.9363 497.0563 497.1763 497.2963 497.4163 497.5362 497.6562 497.7761 497.8960 498.0159 498.1357 498.2556 498.3754 498.4952 498.6150 498.7348 498.8546 498.9743 499.0941 499.2138 499.3335 499.4532 499.5728 499.6925 499.8121 499.9317 500.0513 500.1709 500.2905 500.4100 500.5295 500.6491 500.7686 500.8880 501.0075 501.1269 501.2464 501.3658 501.4852 501.6046 501.7239 501.8433 501.9626 502.0819 502.2012 502.3205 502.4397 502.5590 502.6782 502.7974 502.9166 503.0358 503.1550 503.2741 503.3932 503.5123 503.6314 503.7505 503.8696 503.9886 504.1076 504.2266 504.3456 504.4646 504.5835 504.7025 504.8214 504.9403 505.0592 505.1781 505.2969 505.4158 505.5346 505.6534 505.7722 505.8909 506.0097 506.1284 506.2471 506.3658 506.4845 506.6032 506.7218 506.8405 506.9591 507.0777 507.1963 507.3148 507.4334 507.5519 507.6704 507.7889 507.9074 508.0259 508.1443 508.2627 508.3812 508.4996 508.6179 508.7363 508.8546 508.9730 509.0913 509.2096 509.3278 509.4461 509.5643 509.6826 509.8008 509.9190 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250514T125326.6Z 9265.537113 270 1 29.61 2 72.58 74.54 91.72 241.80 0.00 1 0.00 1 0 15 3.308e-03 3.304e-03 1.179e-03 1.176e-03 4.505498e+03 7.418629e+01 3.144384e+02 -6.000000e+00 1.843606e+02 286.44 -2.00 20.00 -2.00 505.27 0.00e+00 5.346693e-04 3.249381e-05 3.550933e-05 -6.000000e+00 9.321699e-05 286.44 -2.00 20.00 -2.00 500.46 0.00e+00 2.188993e-01 2.321427e-02 3.028235e-02 -6.000000e+00 6.546886e-02 228.76 -2.00 3.09 -2.00 502.05 0.00e+00 3.293 0.000 489.00 513.00 1 7.2138e+00 1.7767e-03 4.7706e-03 -6.0000e+00 5.0150e-03 -7.6801e-03 4.6203e-04 7.5726e-04 -6.0000e+00 1.3162e-03 9.4676e-04 7.7657e-04 1.1054e-04 3.7292e-05 -6.0000e+00 3.2167e-04 -2.1911e-03 -2.0404e-04 10 0 0 10 0 0 -51.91 24.48 0.83 -0.00219 0.00320 8 8 1 4 0 3701.050 32.25 20.00 24.48 26.45 2.1 978.01 900000 -663 -565 -109 -190 381 439 364 580 510 436 191 -29 -333 -449 -283 -196 -131 -64 9 -195 183 148 333 580 180 542 488 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-87 -49 -273 -354 -104 71 80 127 100 315 763 600 486 187 205 111 282 356 395 16 -48 56 198 306 120 -404 -145 -51 -453 -250 -5 -215 -273 5 145 51 170 423 378 418 48 -365 -446 -294 -103 SQ 20250514T125750.4Z 9265.540167 273 1 31.05 2 71.55 74.72 92.62 242.05 0.00 1 0.00 1 0 15 3.318e-03 3.304e-03 1.105e-03 1.103e-03 4.380441e+03 6.905342e+01 3.059448e+02 -6.000000e+00 1.849058e+02 286.44 -2.00 20.00 -2.00 505.27 0.00e+00 6.146962e-04 3.044748e-05 3.971677e-05 -6.000000e+00 9.348551e-05 286.44 -2.00 20.00 -2.00 500.50 0.00e+00 1.901637e-01 2.166415e-02 2.988354e-02 -6.000000e+00 6.564117e-02 228.76 -2.00 3.09 -2.00 502.08 0.00e+00 3.121 0.000 489.00 513.00 1 7.1604e+00 1.6575e-03 4.6034e-03 -6.0000e+00 5.0286e-03 -7.4499e-03 4.3155e-04 7.4110e-04 -6.0000e+00 1.3192e-03 1.0206e-03 4.3014e-05 1.0338e-04 3.5997e-05 -6.0000e+00 3.2256e-04 -5.0238e-03 -1.6154e-04 10 0 0 10 0 0 -107.29 24.50 0.81 -0.00502 -0.00473 9 9 1 4 0 3448.810 32.25 20.00 24.50 26.68 2.1 979.20 900000 -444 -478 -127 -214 358 313 471 672 461 327 548 -6 -225 -553 -202 -59 -144 -166 -169 -64 217 128 31 503 525 478 446 91 -532 -433 -230 -277 51 68 -114 -365 71 93 54 -85 -92 -78 242 150 256 132 350 368 227 -290 -591 -660 -836 -425 -315 -297 374 -225 93 -86 222 435 275 191 -11 461 272 -34 -303 -461 -72 16 -121 -78 -41 -388 -23 99 -380 -651 -405 -591 -364 105 -142 -319 -332 -58 -211 235 51 496 276 71 265 570 264 -40 -464 -772 -736 -335 -195 88 -481 -205 -66 -371 -202 -90 -38 -44 158 189 380 644 670 424 460 248 141 174 347 270 217 187 375 101 237 209 11 -426 -181 -389 -124 66 -1 -334 -173 139 48 121 245 582 198 -31 -101 -437 -379 -125 900000 -423 -465 -128 -214 365 327 499 688 471 342 564 -6 -226 -552 -200 -59 -146 -173 -174 -66 225 132 32 522 547 498 463 93 -553 -436 -228 -277 52 69 -119 -384 74 95 55 -86 -93 -79 248 156 268 138 364 378 229 -286 -589 -643 -809 -414 -316 -296 378 -230 95 -87 226 445 282 196 -11 461 268 -33 -292 -457 -71 16 -121 -76 -40 -379 -23 97 -370 -632 -394 -581 -360 101 -138 -313 -327 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9 1 4 0 3172.670 32.25 20.00 24.52 26.94 2.1 980.45 900000 -505 -579 -67 -101 335 291 540 546 466 228 258 -22 -231 -473 -454 -212 -257 111 -171 -157 189 23 230 298 500 362 490 -92 -448 -490 -103 -1 -130 24 -68 -67 255 212 -121 -198 -72 28 199 172 380 467 376 310 202 -247 -510 -629 -732 -501 28 -449 285 -250 114 -63 138 425 272 326 55 131 167 -39 -200 -573 -287 63 -62 -41 -203 -195 -198 205 -57 -417 -228 -466 -600 -164 -115 -206 -225 -219 -157 134 135 505 317 137 264 333 275 52 -486 -634 -498 -391 -155 -310 -291 -214 -99 -297 53 131 -350 -80 121 119 381 842 407 440 447 193 155 312 293 357 137 129 381 129 378 290 -228 -299 -357 -484 -363 55 -118 -265 111 107 -78 153 367 418 298 173 -400 -293 -364 -398 900000 -481 -563 -67 -101 341 303 571 560 476 239 267 -23 -232 -471 -451 -212 -261 116 -176 -163 196 24 238 310 521 378 508 -94 -465 -493 -102 -1 -133 25 -71 -70 265 217 -123 -200 -73 29 205 179 397 489 391 318 204 -244 -507 -611 -707 -488 28 -447 288 -257 116 -64 141 434 279 334 56 132 165 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