File name: Pandora94s1_GuatemalaCity_20251027_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260423T101654.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20251027_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20251027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251027T135254.9Z 9431.578413 89 1 54.20 2 63.91 112.73 130.83 114.13 0.00 1 0.00 1 0 17 1.163e-02 8.274e-03 2.541e-04 1.440e-04 2.514625e-01 7.035575e-05 2.668976e-03 -6.000000e+00 6.354134e-03 226.23 -2.00 3.09 -2.00 315.82 0.00e+00 6.345886e-04 7.290191e-06 6.871289e-05 -6.000000e+00 2.869407e-04 286.06 -2.00 20.00 -2.00 315.10 0.00e+00 2.261 0.000 302.00 328.00 3 1.4413e-01 1.8127e-04 2.1841e-02 -6.0000e+00 1.5732e-02 -8.0967e-03 2.0317e-04 1.1230e-02 -6.0000e+00 1.7125e-02 3.0500e-03 1.1707e-04 5.5045e-03 -6.0000e+00 1.0225e-02 -4.7331e-03 5.4501e-05 1.5866e-03 -6.0000e+00 4.4224e-03 5.2434e-02 2.3633e-04 3.6764e-06 1.6343e-05 -6.0000e+00 2.8168e-04 1.8121e-05 0.0000e+00 11 8 0 10 0 0 99.95 24.36 0.28 0.00002 0.00179 2495 262 1 5 0 21.720 32.25 20.00 24.36 25.78 2.3 972.58 -352 380 -188 -3027 -4028 -3158 -1280 -308 307 -1369 -3119 -2054 -991 25 1279 581 812 1186 1413 1808 821 875 1289 1144 611 1096 243 -510 -1243 237 775 809 1482 -1343 -3615 -3611 -2825 -1555 -330 -67 -510 -351 -24 -277 473 145 -161 -241 -849 -301 802 669 1045 1161 761 1079 862 439 237 177 878 1326 1793 2298 576 -355 -950 -1420 161 536 763 637 361 629 36 -681 -1474 -2039 -1671 -1816 -1578 -1289 -2271 -1772 -818 -253 212 616 1171 816 643 -2 -643 -763 -365 -214 269 1218 732 -10 -322 -1121 -1590 -326 -658 -841 -613 -403 200 765 1343 1003 805 235 -332 -542 -314 -304 227 504 162 283 678 200 640 50 -436 49 244 98 60 -251 -530 -283 113 138 232 487 394 -3 -139 -694 -895 -84 96 -48 -717 -908 -694 -300 -76 84 -390 -869 -552 -303 8 446 221 316 480 559 741 344 358 542 514 275 509 112 -231 -526 99 347 371 705 -663 -1728 -1714 -1411 -864 -201 -45 -357 -245 -17 -199 337 104 -113 -171 -592 -210 570 512 807 912 614 885 724 366 193 144 733 1155 1640 2168 544 -314 -811 -1184 144 516 748 649 366 628 34 -605 -1276 -1687 -1411 -1699 -1553 -1317 -2412 -1944 -933 -301 257 748 1414 973 745 -2 -676 -780 -388 -239 322 1531 935 -13 -395 -1329 -1828 -379 -807 -1082 -802 -537 271 1080 1950 1444 1135 322 -439 -687 -399 -395 309 703 232 396 945 275 848 65 -551 61 316 134 84 -352 -754 -407 170 214 358 772 632 -4 -215 -1054 -1354 SS 20251027T135722.3Z 9431.581508 92 1 54.20 2 62.92 113.22 129.89 114.04 0.00 1 0.00 1 0 17 1.150e-02 8.297e-03 2.273e-04 1.336e-04 2.440476e-01 6.542671e-05 2.593225e-03 -6.000000e+00 6.282277e-03 226.23 -2.00 3.09 -2.00 315.68 0.00e+00 5.916748e-04 6.566743e-06 6.220441e-05 -6.000000e+00 2.836976e-04 286.06 -2.00 20.00 -2.00 314.97 0.00e+00 2.185 0.000 302.00 328.00 3 7.3194e-02 1.6825e-04 2.1132e-02 -6.0000e+00 1.5555e-02 -6.9834e-03 1.8845e-04 1.0894e-02 -6.0000e+00 1.6931e-02 3.0444e-03 1.0848e-04 5.3411e-03 -6.0000e+00 1.0110e-02 -5.0420e-03 5.0163e-05 1.5370e-03 -6.0000e+00 4.3724e-03 6.0584e-02 2.2805e-04 3.4113e-06 1.5890e-05 -6.0000e+00 2.7850e-04 6.8652e-05 0.0000e+00 11 8 0 10 0 0 61.65 24.38 0.28 0.00007 0.00178 2531 266 1 5 0 21.410 32.25 20.00 24.38 26.04 2.3 974.49 252 422 -50 -3000 -3833 -3194 -1125 -72 435 -1373 -2966 -1814 -1034 -73 1235 480 658 1171 1178 1929 956 930 1338 1186 639 1073 212 -592 -1206 291 735 784 1561 -1361 -3642 -3533 -2832 -1555 -308 -82 -562 -343 -25 -236 490 150 -216 -276 -908 -359 832 648 1040 1169 733 1064 892 459 231 160 900 1314 1797 2281 589 -305 -984 -1443 135 601 774 676 382 660 121 -643 -1438 -2021 -1667 -1799 -1566 -1305 -2271 -1736 -779 -250 185 594 1157 809 606 -7 -636 -765 -354 -193 255 1237 724 5 -319 -1094 -1582 -335 -671 -830 -629 -402 184 780 1329 1001 782 233 -333 -541 -362 -312 203 503 170 267 644 187 631 44 -439 24 251 105 66 -239 -530 -284 144 133 215 492 400 10 -151 -699 -883 63 112 -13 -750 -904 -736 -276 -19 124 -411 -865 -545 -332 -25 452 192 269 470 489 827 419 397 588 528 301 522 102 -265 -531 126 341 373 770 -697 -1800 -1731 -1465 -897 -195 -55 -396 -249 -18 -171 363 112 -157 -195 -656 -259 612 494 803 950 592 872 748 382 188 129 751 1147 1647 2157 557 -269 -835 -1235 119 577 759 688 387 659 116 -587 -1231 -1710 -1438 -1667 -1531 -1368 -2406 -1898 -887 -296 224 723 1402 967 701 -7 -664 -775 -373 -219 304 1549 923 7 -389 -1288 -1805 -388 -820 -1039 -821 -534 249 1100 1929 1440 1100 318 -436 -679 -456 -403 274 699 242 373 894 255 832 58 -548 31 331 141 92 -332 -748 -406 215 205 331 775 638 16 -231 -1055 -1326 SS 20251027T140215.4Z 9431.584901 95 1 11.10 2 61.83 113.78 128.86 113.96 0.00 1 0.00 1 0 17 1.171e-02 8.525e-03 1.907e-03 1.134e-03 2.360961e-01 5.557892e-04 2.508501e-03 -6.000000e+00 6.399267e-03 226.23 -2.00 3.09 -2.00 315.60 0.00e+00 5.201769e-04 5.499564e-05 6.573881e-05 -6.000000e+00 2.889706e-04 286.06 -2.00 20.00 -2.00 314.90 0.00e+00 2.108 0.000 302.00 328.00 3 2.7806e+00 1.4277e-03 2.0404e-02 -6.0000e+00 1.5844e-02 1.3128e-02 1.5983e-03 1.0532e-02 -6.0000e+00 1.7246e-02 1.8676e-03 9.2007e-04 5.1641e-03 -6.0000e+00 1.0298e-02 -4.7123e-03 4.2563e-04 1.4753e-03 -6.0000e+00 4.4540e-03 4.3213e-03 2.7479e-04 2.8944e-05 1.5828e-05 -6.0000e+00 2.8366e-04 -2.0842e-04 0.0000e+00 12 9 1 12 1 1 99.90 24.39 0.28 -0.00021 0.00186 34 18 1 5 0 316.930 32.00 20.00 24.39 26.33 2.3 975.53 487 879 -233 -3847 -3974 -2313 -872 -17 224 -760 -3120 -2033 -578 -47 884 141 482 869 1484 1668 1068 1241 1082 1313 701 908 204 -561 -1174 214 587 1259 1682 -1723 -3804 -3161 -3310 -1308 -394 -291 -234 -507 177 -425 627 237 -293 -404 -960 -260 594 707 879 1215 655 964 963 275 392 -255 819 1290 2087 2287 606 -329 -1029 -1543 242 561 869 639 554 640 150 -578 -1508 -1928 -1558 -1874 -1712 -1256 -2334 -1834 -653 -223 87 542 1187 777 594 125 -752 -694 -441 -74 181 1461 821 33 -273 -1019 -1630 -535 -651 -903 -551 -301 126 818 1275 979 747 87 -161 -695 -314 -395 222 505 182 307 733 293 540 77 -565 7 298 74 -65 -271 -502 -205 170 70 291 589 401 27 -164 -680 -1008 123 237 -64 -982 -955 -537 -217 -4 65 -228 -915 -613 -183 -17 339 59 193 359 631 735 479 541 488 593 335 448 100 -269 -524 94 275 596 868 -877 -1874 -1535 -1701 -740 -255 -199 -172 -370 132 -319 463 176 -213 -297 -692 -187 432 552 691 1002 534 797 813 231 320 -209 688 1126 1896 2213 586 -299 -901 -1316 212 546 884 653 562 645 146 -520 -1281 -1621 -1325 -1759 -1676 -1308 -2515 -2039 -750 -266 106 657 1473 928 692 138 -777 -717 -472 -82 215 1799 1051 43 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