File name: Pandora94s1_GuatemalaCity_20251210_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260423T102329.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20251210_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20251210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251210T143541.0Z 9475.608114 302 1 32.65 2 61.54 126.87 51.35 272.07 0.00 1 0.00 1 0 17 1.146e-02 8.432e-03 2.003e-03 1.150e-03 2.218159e-01 5.588938e-04 2.365067e-03 -6.000000e+00 6.224921e-03 224.78 -2.00 3.09 -2.00 315.70 0.00e+00 6.047541e-04 5.671364e-05 6.108586e-05 -6.000000e+00 2.818622e-04 285.38 -2.00 20.00 -2.00 315.00 0.00e+00 2.089 0.000 302.00 328.00 3 3.8918e+00 1.4348e-03 1.9893e-02 -6.0000e+00 1.5365e-02 1.6178e-02 1.6095e-03 9.8692e-03 -6.0000e+00 1.6745e-02 4.3243e-03 9.2764e-04 4.8526e-03 -6.0000e+00 1.0006e-02 -5.7680e-03 4.3279e-04 1.4115e-03 -6.0000e+00 4.3379e-03 1.4839e-03 2.3836e-04 2.9411e-05 1.4840e-05 -6.0000e+00 2.7743e-04 9.2122e-04 0.0000e+00 12 9 1 12 1 1 99.99 24.27 0.34 0.00092 0.00271 66 12 1 5 0 487.240 32.00 20.01 24.27 24.79 2.4 968.22 -427 1152 -291 -3944 -3401 -2454 -1197 15 -94 -62 -2941 -1530 -1268 77 997 41 496 963 1847 1405 949 1516 774 1597 439 1002 282 -779 -713 140 393 1044 1292 -1572 -3978 -2899 -2913 -1302 -465 -46 -672 -706 -112 -8 256 75 -271 -304 -683 -329 521 579 902 1360 558 1173 735 405 106 214 972 1372 1968 2528 508 -424 -1030 -1356 -81 590 642 741 541 710 469 -676 -1498 -1904 -1626 -1921 -1326 -1417 -2340 -1873 -811 -298 190 425 1076 863 653 -306 -609 -726 -532 -95 303 1396 929 85 -291 -1113 -1521 -364 -820 -700 -562 -283 283 715 1296 1173 741 94 -244 -615 -410 -500 232 584 274 293 514 131 499 139 -648 -216 319 -39 217 -91 -472 -340 169 187 373 458 343 -82 -153 -642 -885 -104 295 -76 -954 -778 -545 -285 4 -26 -17 -805 -428 -403 25 371 17 189 379 744 590 404 626 331 719 210 493 137 -352 -298 57 173 488 658 -772 -1922 -1375 -1438 -747 -300 -32 -479 -520 -84 -6 191 56 -198 -215 -498 -239 378 450 695 1096 462 983 631 344 88 177 827 1198 1855 2404 482 -382 -905 -1157 -70 560 661 753 546 721 443 -602 -1272 -1621 -1380 -1772 -1298 -1462 -2573 -2033 -941 -354 228 523 1317 1057 766 -343 -648 -747 -558 -105 355 1727 1224 110 -364 -1337 -1727 -431 -1035 -887 -743 -374 389 1006 1844 1682 1054 129 -316 -779 -521 -640 306 828 384 403 715 174 653 175 -797 -264 404 -53 297 -127 -668 -480 254 285 580 706 534 -130 -234 -944 -1316 SS 20251210T144030.8Z 9475.611467 305 1 6.54 2 60.61 127.57 52.49 272.30 0.00 1 0.00 1 0 17 1.121e-02 8.476e-03 2.004e-03 1.307e-03 2.150351e-01 6.386882e-04 2.312408e-03 -6.000000e+00 6.092252e-03 224.78 -2.00 3.09 -2.00 315.24 0.00e+00 4.955779e-04 5.898909e-05 4.163483e-05 -6.000000e+00 2.758623e-04 285.38 -2.00 20.00 -2.00 314.59 0.00e+00 2.029 0.000 302.00 328.00 3 2.6523e+00 1.6313e-03 1.9328e-02 -6.0000e+00 1.5038e-02 7.2816e-03 1.8249e-03 9.5912e-03 -6.0000e+00 1.6388e-02 5.0575e-03 1.0478e-03 4.7170e-03 -6.0000e+00 9.7927e-03 -5.8420e-03 4.7853e-04 1.3594e-03 -6.0000e+00 4.2453e-03 5.4688e-03 1.6670e-04 3.3299e-05 1.4952e-05 -6.0000e+00 2.7154e-04 1.1488e-03 0.0000e+00 12 9 1 12 9 1 95.92 24.28 0.27 0.00115 0.00240 20 18 1 5 0 311.020 32.25 20.00 24.28 25.10 2.4 969.53 1112 707 -217 -3265 -3635 -2978 -1022 551 76 -1008 -2687 -1269 -1034 -233 1402 316 311 1005 1240 1308 1246 1074 1501 896 777 1190 371 -230 -1185 298 804 1000 1357 -1199 -3352 -2928 -2968 -1339 -523 -309 -543 -235 -68 -679 312 -142 -301 -618 -1065 -279 849 723 1190 1007 715 955 454 506 100 202 1011 1437 1964 2322 625 -368 -999 -1316 7 846 613 462 268 795 131 -520 -1484 -1772 -1593 -1816 -1602 -1516 -2363 -1799 -861 -249 333 608 1193 791 779 2 -775 -695 -369 -202 242 1404 858 -50 -379 -1038 -1644 -305 -787 -765 -472 -321 296 719 1342 1100 892 327 -357 -537 -204 -312 28 316 39 213 325 172 501 36 -312 39 116 204 276 -348 -500 -202 148 149 160 396 436 131 -158 -659 -943 339 230 -71 -991 -1034 -825 -301 170 24 -336 -867 -417 -386 -92 587 144 144 453 576 629 606 510 730 442 402 635 196 -118 -567 139 399 503 743 -643 -1730 -1493 -1607 -803 -346 -226 -411 -183 -52 -525 238 -109 -232 -463 -778 -210 647 569 978 840 610 827 389 428 85 172 888 1314 1814 2274 609 -335 -870 -1152 7 819 626 475 274 802 127 -483 -1294 -1518 -1384 -1682 -1604 -1573 -2533 -1989 -989 -297 405 742 1447 948 905 2 -816 -706 -387 -227 284 1714 1089 -64 -462 -1195 -1847 -357 -969 -961 -601 -425 397 1001 1910 1578 1251 436 -457 -661 -251 -393 37 438 54 291 442 229 648 46 -383 48 149 266 378 -475 -689 -281 214 222 244 602 671 197 -235 -970 -1353 SS 20251210T145557.4Z 9475.622192 317 1 5.41 2 57.70 129.94 56.16 273.05 0.00 1 0.00 1 0 17 1.076e-02 8.481e-03 1.905e-03 1.321e-03 1.985361e-01 6.468975e-04 2.132979e-03 -6.000000e+00 5.844530e-03 224.78 -2.00 3.09 -2.00 314.93 0.00e+00 4.635768e-04 5.626018e-05 3.816665e-05 -6.000000e+00 2.646268e-04 285.38 -2.00 20.00 -2.00 314.31 0.00e+00 1.865 0.000 302.00 328.00 3 2.6451e+00 1.6478e-03 1.7779e-02 -6.0000e+00 1.4426e-02 1.4191e-02 1.8403e-03 8.8385e-03 -6.0000e+00 1.5722e-02 3.3172e-03 1.0573e-03 4.3436e-03 -6.0000e+00 9.3943e-03 -5.6030e-03 4.7786e-04 1.2489e-03 -6.0000e+00 4.0730e-03 6.4756e-03 2.0887e-04 3.3612e-05 1.3880e-05 -6.0000e+00 2.6046e-04 5.7296e-04 0.0000e+00 12 9 1 12 1 1 99.50 24.36 0.24 0.00057 0.00214 19 21 1 5 0 270.450 32.25 20.00 24.36 25.40 2.4 969.23 75 405 -396 -3143 -2696 -2292 -735 646 360 -655 -2581 -1575 -882 -236 1022 268 721 1051 1317 1835 847 559 2021 1103 46 1013 555 -654 -504 208 957 623 1692 -1422 -3219 -3170 -2686 -1179 -493 -241 -826 -636 65 -198 159 -122 -279 -344 -831 -310 908 462 1023 1140 782 945 1039 416 335 250 791 1343 1872 2278 408 -355 -1028 -1614 52 402 576 882 591 596 81 -476 -1364 -2130 -1674 -1849 -1674 -1448 -2204 -1558 -727 -265 217 516 1062 761 694 -103 -711 -833 -254 -103 387 1096 824 18 -344 -1137 -1591 -360 -669 -810 -677 -358 251 570 1329 1024 817 376 -405 -564 -258 -458 329 567 185 342 634 128 542 186 -176 85 341 65 70 -241 -481 -114 4 294 158 378 352 22 -165 -726 -1069 26 140 -138 -1072 -849 -702 -240 222 129 -242 -924 -574 -361 -103 470 127 343 513 661 949 447 288 1053 585 26 581 313 -343 -255 103 500 331 967 -801 -1732 -1689 -1586 -738 -341 -184 -655 -501 52 -159 127 -97 -223 -266 -648 -239 709 373 861 970 680 833 902 371 292 217 708 1250 1817 2265 404 -326 -930 -1416 47 391 589 904 622 604 79 -441 -1184 -1817 -1441 -1752 -1659 -1529 -2400 -1698 -824 -313 262 640 1312 904 798 -114 -736 -856 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