File name: Pandora94s1_GuatemalaCity_20251214_L2Fit_fwvt1c4d20250225p1-8.txt
File generation date: 20260423T101954.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c4p1-8
Local principal investigator: Daniel Alvarez
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 94
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora94_OF_v3d20240409.txt
Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt
Level 1 file used: Pandora94s1_GuatemalaCity_20251214_L1_smca1c4d20250225p1-8.txt
Full location name: Ciudad de Guatemala
Short location name: GuatemalaCity
Country of location: Guatemala
Location latitude [deg]: 14.6192
Location longitude [deg]: -90.4838
Location altitude [m]: 1547
Local noon date: 20251214
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1624 1774
Nominal wavelengths inside fitting window [nm]: 492.0012 492.1219 492.2426 492.3632 492.4839 492.6045 492.7251 492.8457 492.9663 493.0869 493.2075 493.3280 493.4485 493.5690 493.6895 493.8100 493.9304 494.0509 494.1713 494.2917 494.4121 494.5324 494.6528 494.7731 494.8934 495.0137 495.1340 495.2543 495.3746 495.4948 495.6150 495.7352 495.8554 495.9756 496.0957 496.2159 496.3360 496.4561 496.5762 496.6962 496.8163 496.9363 497.0563 497.1763 497.2963 497.4163 497.5362 497.6562 497.7761 497.8960 498.0159 498.1357 498.2556 498.3754 498.4952 498.6150 498.7348 498.8546 498.9743 499.0941 499.2138 499.3335 499.4532 499.5728 499.6925 499.8121 499.9317 500.0513 500.1709 500.2905 500.4100 500.5295 500.6491 500.7686 500.8880 501.0075 501.1269 501.2464 501.3658 501.4852 501.6046 501.7239 501.8433 501.9626 502.0819 502.2012 502.3205 502.4397 502.5590 502.6782 502.7974 502.9166 503.0358 503.1550 503.2741 503.3932 503.5123 503.6314 503.7505 503.8696 503.9886 504.1076 504.2266 504.3456 504.4646 504.5835 504.7025 504.8214 504.9403 505.0592 505.1781 505.2969 505.4158 505.5346 505.6534 505.7722 505.8909 506.0097 506.1284 506.2471 506.3658 506.4845 506.6032 506.7218 506.8405 506.9591 507.0777 507.1963 507.3148 507.4334 507.5519 507.6704 507.7889 507.9074 508.0259 508.1443 508.2627 508.3812 508.4996 508.6179 508.7363 508.8546 508.9730 509.0913 509.2096 509.3278 509.4461 509.5643 509.6826 509.8008 509.9190
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20251214T143739.0Z 9479.609479 255 1 54.74 2 61.68 127.15 29.75 204.56 0.00 1 0.00 1 0 15 3.542e-02 4.373e-02 1.251e-03 1.248e-03 8.185253e+03 8.241493e+01 7.344368e+02 -6.000000e+00 1.963956e+03 285.31 -2.00 20.00 -2.00 505.26 0.00e+00 -4.129689e-04 3.447377e-05 3.628626e-05 -6.000000e+00 9.951791e-04 285.31 -2.00 20.00 -2.00 500.45 0.00e+00 -1.664776e+00 2.461685e-02 1.710335e-02 -6.000000e+00 6.961797e-01 224.63 -2.00 3.09 -2.00 502.04 0.00e+00 2.098 0.000 489.00 513.00 1 8.2786e+00 1.8846e-03 3.1609e-03 -6.0000e+00 5.3359e-02 2.9588e-02 4.9074e-04 8.0610e-04 -6.0000e+00 1.3955e-02 4.3530e-04 -5.2266e-03 1.1340e-04 8.9514e-05 -6.0000e+00 3.4405e-03 4.7365e-03 -8.2214e-05 12 8 8 10 0 0 99.86 24.27 0.98 0.00474 -0.03152 14 1 1 4 0 3909.610 32.00 20.00 24.27 24.50 2.4 966.72 900000 -539 -1529 -1513 -1461 -363 -638 -219 -34 741 722 608 188 57 -202 -554 -635 -1083 -1001 -822 9 -39 61 -45 210 98 546 690 508 432 315 -70 -830 -1433 -1816 -1217 -27 413 126 580 -196 -534 -401 -719 -343 -160 141 918 689 927 466 254 -612 -1020 -1631 -1527 -1862 -399 -237 -86 783 261 291 402 883 838 1450 1597 1288 1060 875 964 801 434 601 823 1381 2450 2227 916 604 575 435 368 1340 1142 1716 1696 2056 1452 1524 1549 1319 1034 1296 1201 771 -31 -279 -795 -1326 -1230 -1911 -1623 -610 726 2549 3390 2907 2905 2330 1759 1738 1428 1163 1423 1475 1774 2051 2790 -40124 2669 1984 1576 842 801 950 690 871 1235 626 499 851 506 238 46 -295 -842 -667 16 124 412 749 704 610 741 639 1059 796 528 194 900000 -523 -1526 -1500 -1498 -377 -679 -227 -36 764 764 635 194 58 -204 -557 -643 -1119 -1059 -856 10 -41 64 -47 220 103 571 717 521 449 317 -70 -835 -1483 -1878 -1288 -29 429 129 587 -198 -541 -408 -742 -357 -167 147 947 703 926 473 251 -595 -984 -1598 -1536 -1865 -404 -241 -88 788 264 297 411 897 846 1435 1615 1290 1051 858 939 785 432 605 803 1387 2394 2143 883 582 555 425 363 1324 1103 1665 1652 1993 1414 1486 1520 1313 1044 1303 1188 747 -29 -268 -749 -1236 -1144 -1824 -1541 -600 730 2548 3343 2842 2810 2271 1744 1745 1450 1146 1403 1458 1762 2045 2754 -50617 2650 1946 1533 825 788 935 681 856 1204 612 485 811 476 223 43 -279 -819 -660 16 121 402 733 693 603 730 626 1017 778 507 185
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SQ 20251214T162104.7Z 9479.681304 329 1 2.60 2 44.52 147.89 46.37 235.43 0.00 1 0.00 1 0 15 2.650e-03 2.652e-03 1.811e-04 1.808e-04 2.091876e+03 1.067862e+01 1.495626e+02 -6.000000e+00 1.468857e+02 285.31 -2.00 20.00 -2.00 505.25 0.00e+00 3.449017e-04 4.970242e-06 2.218638e-05 -6.000000e+00 7.441272e-05 285.31 -2.00 20.00 -2.00 500.42 0.00e+00 -7.248046e-02 3.522611e-03 1.502089e-02 -6.000000e+00 5.190552e-02 224.63 -2.00 3.09 -2.00 502.02 0.00e+00 1.401 0.000 489.00 513.00 1 1.4620e+00 2.7009e-04 2.1643e-03 -6.0000e+00 3.9820e-03 5.4133e-03 7.0013e-05 3.6410e-04 -6.0000e+00 1.0347e-03 3.8386e-01 6.7736e-04 1.7058e-05 1.8998e-05 -6.0000e+00 2.5655e-04 1.9559e-03 -6.3050e-06 12 1 1 12 1 1 97.80 24.57 0.83 0.00196 0.00665 229 55 1 4 0 11.270 32.25 20.00 24.57 26.02 2.3 971.98 -235 -399 -293 -100 -116 285 510 434 353 280 355 301 -91 -222 -230 -255 -133 -17 -13 -237 -68 233 166 240 357 246 416 339 -242 -497 -127 -150 -245 120 -47 -308 2 152 -8 -122 -16 8 54 176 276 261 291 330 310 6 -405 -473 -589 -535 -262 -369 -408 355 -145 -9 170 261 222 205 226 142 160 189 -43 -357 -352 -104 -61 -29 -33 -298 -268 -12 -90 -261 -339 -263 -401 -303 -45 -151 -244 -178 -101 -111 60 219 419 194 118 348 332 13 -214 -449 -476 -370 -186 -121 -254 -528 -259 -150 -137 67 23 -59 -10 131 230 357 599 536 318 211 281 212 270 385 157 -26 164 213 187 340 143 -304 -99 -97 -280 -105 74 -217 -245 22 42 86 267 287 272 132 -139 -342 -304 -113 -173 -228 -389 -289 -100 -119 295 529 456 369 293 367 310 -93 -226 -232 -256 -135 -17 -14 -248 -72 245 174 251 375 256 437 354 -249 -509 -127 -150 -245 121 -48 -322 2 158 -8 -125 -16 9 55 182 284 271 302 342 317 6 -407 -468 -579 -523 -256 -368 -413 359 -148 -9 172 266 227 210 230 143 161 187 -43 -350 -341 -102 -59 -28 -32 -295 -265 -11 -87 -251 -327 -256 -388 -296 -44 -148 -242 -176 -100 -110 60 216 420 195 118 348 326 12 -206 -429 -450 -350 -177 -117 -253 -530 -259 -150 -134 65 23 -58 -10 131 231 360 606 538 319 213 278 209 263 378 154 -26 161 208 183 331 139 -298 -95 -93 -266 -100 71 -212 -241 22 41 85 266 284 270 131 -137 -335 -293 -108 -166
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