File name: Pandora94s1_GuatemalaCity_20251221_L2Fit_fwvt1c3d20250101p1-8.txt
File generation date: 20251222T060726.4Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Daniel Alvarez
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 94
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora94_OF_v3d20240409.txt
Instrument calibration file used: Pandora94s1_CF_v3d20250101.txt
Level 1 file used: Pandora94s1_GuatemalaCity_20251221_L1_smca1c3d20250101p1-8.txt
Full location name: Ciudad de Guatemala
Short location name: GuatemalaCity
Country of location: Guatemala
Location latitude [deg]: 14.6192
Location longitude [deg]: -90.4838
Location altitude [m]: 1547
Local noon date: 20251221
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based on clearance session 2
First and last pixel inside fitting window: 1624 1774
Nominal wavelengths inside fitting window [nm]: 492.0461 492.1668 492.2875 492.4082 492.5288 492.6494 492.7700 492.8906 493.0112 493.1318 493.2523 493.3728 493.4934 493.6138 493.7343 493.8548 493.9752 494.0957 494.2161 494.3365 494.4568 494.5772 494.6975 494.8179 494.9382 495.0585 495.1788 495.2990 495.4193 495.5395 495.6597 495.7799 495.9001 496.0202 496.1404 496.2605 496.3806 496.5007 496.6208 496.7408 496.8609 496.9809 497.1009 497.2209 497.3409 497.4608 497.5808 497.7007 497.8206 497.9405 498.0604 498.1803 498.3001 498.4199 498.5397 498.6595 498.7793 498.8991 499.0188 499.1385 499.2582 499.3779 499.4976 499.6173 499.7369 499.8565 499.9762 500.0957 500.2153 500.3349 500.4544 500.5739 500.6935 500.8129 500.9324 501.0519 501.1713 501.2907 501.4101 501.5295 501.6489 501.7683 501.8876 502.0069 502.1262 502.2455 502.3648 502.4841 502.6033 502.7225 502.8417 502.9609 503.0801 503.1992 503.3184 503.4375 503.5566 503.6757 503.7948 503.9138 504.0329 504.1519 504.2709 504.3899 504.5088 504.6278 504.7467 504.8656 504.9845 505.1034 505.2223 505.3412 505.4600 505.5788 505.6976 505.8164 505.9352 506.0539 506.1726 506.2914 506.4101 506.5287 506.6474 506.7661 506.8847 507.0033 507.1219 507.2405 507.3590 507.4776 507.5961 507.7146 507.8331 507.9516 508.0701 508.1885 508.3069 508.4254 508.5438 508.6621 508.7805 508.8988 509.0172 509.1355 509.2538 509.3720 509.4903 509.6085 509.7268 509.8450 509.9632
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20251221T132104.4Z 9486.556301 57 1 39.33 2 78.08 118.37 95.86 116.15 0.00 1 0.00 1 0 15 2.961e-03 2.955e-03 3.123e-04 3.119e-04 5.385572e+03 1.977896e+01 3.786345e+02 -6.000000e+00 1.641079e+02 285.23 -2.00 20.00 -2.00 505.28 0.00e+00 5.429422e-04 8.600497e-06 3.896432e-05 -6.000000e+00 8.316509e-05 285.23 -2.00 20.00 -2.00 500.51 0.00e+00 2.999145e-01 6.094649e-03 3.535931e-02 -6.000000e+00 5.816548e-02 224.46 -2.00 3.09 -2.00 502.09 0.00e+00 4.698 0.000 489.00 513.00 1 5.1222e+00 4.6685e-04 6.4344e-03 -6.0000e+00 4.4583e-03 1.5859e-03 1.2067e-04 9.1658e-04 -6.0000e+00 1.1656e-03 6.4382e-03 1.5064e-03 2.9002e-05 4.5085e-05 -6.0000e+00 2.8756e-04 -3.8589e-02 -6.3993e-05 12 1 1 12 1 1 99.60 23.90 0.73 -0.03859 -0.02814 76 11 1 4 0 510.660 32.00 20.00 23.90 21.70 2.5 954.97 900000 -410 -271 -61 -116 364 570 482 453 304 343 343 -100 -299 -320 -283 -88 30 26 -197 -35 167 192 242 363 267 391 354 -272 -543 -245 -202 -251 132 28 -263 2 117 -52 -107 -27 19 79 161 222 299 306 392 341 7 -493 -597 -686 -614 -334 -388 -360 360 -181 -51 92 263 334 253 233 90 155 120 -75 -330 -429 -56 -90 -31 42 -254 -317 -29 -98 -329 -460 -372 -489 -389 -23 -140 -308 -249 -70 -124 17 284 436 261 166 415 377 78 -261 -520 -588 -464 -315 -160 -287 -546 -290 -153 -247 23 76 -121 22 133 233 428 669 634 419 234 384 246 165 434 242 -25 155 242 238 364 111 -200 -39 -61 -300 -118 -11 -198 -200 -9 82 92 247 301 276 156 -53 -300 -324 -162 -165 900000 -394 -268 -60 -117 373 587 504 475 316 352 352 -102 -300 -322 -286 -88 31 27 -205 -37 174 200 254 381 277 404 369 -280 -551 -245 -201 -252 134 29 -275 2 120 -54 -109 -28 19 81 165 230 312 318 404 351 7 -494 -590 -675 -603 -328 -387 -364 367 -184 -52 93 266 340 258 237 90 155 119 -74 -324 -418 -55 -88 -31 42 -252 -315 -28 -95 -318 -444 -362 -473 -379 -23 -137 -305 -246 -69 -122 16 283 433 261 166 412 366 75 -249 -495 -552 -437 -299 -155 -282 -549 -291 -152 -242 22 74 -121 22 133 235 433 669 639 424 235 385 243 163 425 239 -25 152 237 236 360 110 -196 -37 -59 -288 -113 -11 -195 -198 -8 82 92 249 300 277 156 -54 -297 -318 -156 -162
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SQ 20251221T133017.8Z 9486.562707 63 1 28.49 2 76.13 119.20 93.93 116.63 0.00 1 0.00 1 0 15 2.869e-03 2.862e-03 1.476e-04 1.474e-04 4.819596e+03 9.286888e+00 3.401106e+02 -6.000000e+00 1.590079e+02 285.23 -2.00 20.00 -2.00 505.27 0.00e+00 4.937251e-04 4.061103e-06 3.525876e-05 -6.000000e+00 8.057974e-05 285.23 -2.00 20.00 -2.00 500.47 0.00e+00 2.283606e-01 2.885552e-03 3.180950e-02 -6.000000e+00 5.635236e-02 224.46 -2.00 3.09 -2.00 502.06 0.00e+00 4.079 0.000 489.00 513.00 1 3.3996e+00 2.2111e-04 5.6354e-03 -6.0000e+00 4.3194e-03 9.4658e-03 5.7238e-05 8.1929e-04 -6.0000e+00 1.1291e-03 3.9074e-02 1.2969e-03 1.3781e-05 4.0141e-05 -6.0000e+00 2.7863e-04 -4.0942e-02 -4.1769e-05 10 0 0 10 0 0 99.34 23.92 0.76 -0.04094 -0.03195 567 60 1 4 0 50.240 31.75 20.00 23.92 22.11 2.5 956.81 900000 -455 -318 -120 -55 315 568 442 393 294 342 314 -100 -289 -277 -263 -154 -7 31 -213 -23 210 142 259 340 287 431 348 -261 -567 -201 -225 -282 109 33 -243 22 161 -59 -125 -38 1 49 222 265 281 298 360 311 -1 -435 -552 -644 -591 -319 -357 -404 372 -113 -16 165 283 261 197 210 109 155 171 -45 -409 -395 -113 -71 -52 -11 -256 -258 -57 -122 -344 -397 -306 -418 -319 -43 -181 -237 -190 -148 -85 41 277 446 231 179 385 393 48 -208 -547 -612 -439 -274 -150 -252 -512 -276 -183 -183 37 58 -106 -13 136 230 408 618 607 350 240 327 187 203 399 236 -15 199 243 166 399 165 -254 -110 -58 -300 -102 36 -219 -243 49 88 65 258 296 300 154 -83 -305 -321 -196 -195 900000 -441 -316 -120 -56 326 588 465 409 308 353 325 -102 -290 -280 -266 -155 -7 32 -223 -24 220 149 271 358 304 454 363 -269 -576 -201 -224 -284 111 34 -254 23 169 -61 -128 -39 1 50 230 274 293 310 370 319 -1 -435 -544 -632 -577 -312 -355 -407 379 -116 -16 168 290 268 200 216 111 155 171 -45 -400 -387 -110 -70 -51 -11 -255 -255 -56 -118 -331 -381 -295 -407 -313 -42 -178 -236 -189 -147 -85 41 274 446 231 178 381 385 47 -198 -517 -572 -411 -258 -144 -249 -510 -274 -180 -179 36 57 -104 -13 137 229 409 622 614 356 242 323 185 198 392 230 -14 195 238 162 388 160 -246 -106 -56 -287 -98 35 -212 -240 48 87 65 256 295 300 153 -82 -300 -314 -188 -188
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