File name: Pandora94s1_GuatemalaCity_20260118_L2Fit_fout2c3d20250101p1-8.txt File generation date: 20260119T061742.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v3d20250101.txt Level 1 file used: Pandora94s1_GuatemalaCity_20260118_L1_smca1c3d20250101p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20260118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 2 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0134 305.1540 305.2945 305.4351 305.5756 305.7162 305.8567 305.9972 306.1377 306.2782 306.4187 306.5592 306.6996 306.8401 306.9805 307.1209 307.2614 307.4018 307.5422 307.6825 307.8229 307.9633 308.1036 308.2440 308.3843 308.5246 308.6649 308.8052 308.9455 309.0858 309.2261 309.3663 309.5066 309.6468 309.7870 309.9272 310.0674 310.2076 310.3478 310.4880 310.6281 310.7683 310.9084 311.0485 311.1886 311.3287 311.4688 311.6089 311.7490 311.8890 312.0291 312.1691 312.3091 312.4491 312.5891 312.7291 312.8691 313.0091 313.1490 313.2890 313.4289 313.5688 313.7087 313.8486 313.9885 314.1284 314.2683 314.4081 314.5480 314.6878 314.8276 314.9675 315.1073 315.2471 315.3868 315.5266 315.6664 315.8061 315.9458 316.0856 316.2253 316.3650 316.5047 316.6443 316.7840 316.9237 317.0633 317.2029 317.3426 317.4822 317.6218 317.7614 317.9009 318.0405 318.1801 318.3196 318.4591 318.5986 318.7382 318.8777 319.0171 319.1566 319.2961 319.4355 319.5750 319.7144 319.8538 319.9932 320.1326 320.2720 320.4114 320.5507 320.6901 320.8294 320.9688 321.1081 321.2474 321.3867 321.5260 321.6652 321.8045 321.9437 322.0830 322.2222 322.3614 322.5006 322.6398 322.7790 322.9182 323.0573 323.1965 323.3356 323.4747 323.6138 323.7529 323.8920 324.0311 324.1702 324.3092 324.4483 324.5873 324.7263 324.8653 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260118T132806.3Z 9514.561184 56 1 19.82 2 78.12 115.09 78.42 119.88 0.00 1 0.00 1 0 25 7.868e-02 8.122e-03 1.251e-02 1.201e-03 4.822467e-01 5.955356e-04 5.089636e-03 -6.000000e+00 4.334941e-02 223.95 -2.00 3.09 -2.00 318.86 0.00e+00 1.534711e-03 1.382951e-04 7.021311e-04 -6.000000e+00 1.945199e-03 284.97 -2.00 20.00 -2.00 318.16 0.00e+00 4.712 0.000 302.00 328.00 3 1.3553e+00 1.6218e-03 4.4612e-02 -6.0000e+00 1.0688e-01 -1.1132e-02 1.8785e-03 2.1888e-02 -6.0000e+00 1.1583e-01 -2.0047e-02 1.4287e-03 1.1068e-02 -6.0000e+00 6.9206e-02 5.9342e-03 7.7892e-04 3.4060e-03 -6.0000e+00 3.0905e-02 1.6096e-03 -4.8151e-04 2.9998e-05 3.0569e-05 -6.0000e+00 1.9089e-03 -4.4952e-02 0.0000e+00 12 9 1 12 1 1 39.56 23.56 0.27 -0.04495 -0.04857 105 30 1 5 0 186.950 31.75 20.01 23.56 18.83 2.6 942.69 900000 -26425 -18898 -18943 -33910 -24829 -37307 -26345 -28980 -21738 -22101 -23460 -14938 -12282 -6336 -2559 -880 -3614 197 2913 -2418 -1485 -2175 -3905 -1313 -3277 -1786 -1439 -3625 -6234 -2062 -342 37 441 -4032 -4602 -5621 -4450 -1236 -52 310 -3 420 1721 556 1475 1712 81 872 -270 186 1107 1343 2075 2499 685 962 1206 757 101 498 577 1903 2262 2902 1071 84 -734 -770 511 631 1014 864 279 280 -479 -1030 -2247 -2343 -1466 -2096 -1774 -1478 -2431 -1656 -789 -187 374 661 1380 869 934 30 -556 -893 -544 -481 108 1116 732 -129 -521 -1352 -1768 -314 -826 -931 -687 -410 138 770 1222 926 718 243 -394 -216 -151 -22 413 510 270 393 719 172 655 0 -758 -4 67 44 -15 -288 -504 -305 40 -63 257 379 239 -41 -234 -736 900000 -702 -520 -543 -1040 -625 -1079 -762 -998 -787 -846 -918 -607 -605 -364 -172 -67 -305 17 266 -245 -152 -221 -430 -140 -384 -217 -174 -423 -722 -245 -47 6 79 -775 -815 -1015 -900 -268 -14 97 -1 140 593 196 521 614 30 321 -103 74 451 602 997 1203 350 508 654 407 53 258 312 1056 1409 1876 714 56 -477 -507 349 475 784 694 221 222 -350 -711 -1457 -1519 -1049 -1682 -1547 -1380 -2347 -1661 -807 -203 408 739 1528 925 957 30 -525 -859 -556 -539 131 1464 997 -173 -677 -1652 -2089 -367 -1025 -1210 -901 -568 197 1172 1883 1481 1124 373 -584 -314 -222 -32 637 801 424 616 1091 262 949 0 -1088 -6 103 71 -25 -500 -877 -542 73 -122 493 742 471 -80 -434 -1337 SS 20260118T133239.7Z 9514.564349 59 1 54.29 2 77.13 115.48 77.49 120.27 0.00 1 0.00 1 0 25 6.195e-02 8.425e-03 3.531e-03 4.586e-04 4.517327e-01 2.268569e-04 4.796917e-03 -6.000000e+00 3.412788e-02 223.95 -2.00 3.09 -2.00 318.53 0.00e+00 1.295302e-03 4.746282e-05 6.018282e-04 -6.000000e+00 1.531545e-03 284.97 -2.00 20.00 -2.00 317.81 0.00e+00 4.373 0.000 302.00 328.00 3 7.7324e-01 6.1193e-04 4.1483e-02 -6.0000e+00 8.4142e-02 -1.6209e-02 7.0206e-04 2.0459e-02 -6.0000e+00 9.1190e-02 -2.0020e-02 5.0429e-04 1.0298e-02 -6.0000e+00 5.4485e-02 7.4661e-03 2.7406e-04 3.1083e-03 -6.0000e+00 2.4329e-02 3.9165e-03 -5.7374e-04 1.1535e-05 2.7976e-05 -6.0000e+00 1.5030e-03 -4.4361e-02 0.0000e+00 11 8 0 10 0 0 30.31 23.57 0.30 -0.04436 -0.04867 683 72 1 5 0 79.480 31.75 20.05 23.57 19.08 2.7 944.04 900000 -21101 -14390 -15518 -21368 -23298 -27193 -23545 -21408 -16795 -15243 -20662 -15064 -10082 -6191 -2274 -1902 -1117 853 1675 957 -392 -534 -669 1159 -821 551 -1712 -3072 -4233 -2934 -396 512 1188 -2160 -4490 -4932 -3913 -1397 353 547 8 43 1252 694 1416 1177 543 192 -286 126 1245 1410 1591 1781 1312 1532 1109 733 125 263 1030 1642 2388 2847 826 84 -1033 -1078 238 666 943 782 399 277 -236 -1116 -2177 -2650 -2104 -2132 -1647 -1331 -2425 -1780 -922 -197 358 670 1197 863 581 -213 -922 -1076 -575 -328 134 1137 669 -91 -473 -1252 -1646 -314 -870 -821 -594 -314 277 887 1358 1036 789 241 -296 -404 -194 -88 277 564 183 435 815 264 648 -140 -608 -58 134 37 -23 -325 -611 -328 38 19 183 452 320 -70 -271 -858 900000 -789 -558 -631 -845 -841 -1031 -958 -987 -834 -782 -1121 -865 -678 -490 -209 -180 -113 91 188 114 -48 -65 -86 160 -124 86 -272 -466 -624 -453 -69 101 243 -468 -909 -1011 -898 -377 107 194 3 16 494 278 567 480 223 80 -121 56 561 698 793 953 733 883 660 433 72 150 608 1004 1535 2011 601 57 -682 -717 175 536 783 674 339 223 -185 -826 -1506 -1828 -1597 -1714 -1439 -1248 -2359 -1799 -955 -217 397 761 1349 972 604 -215 -915 -1081 -611 -365 161 1485 909 -122 -610 -1517 -1927 -379 -1081 -1067 -781 -436 397 1303 2088 1647 1225 366 -431 -577 -279 -129 421 875 285 675 1224 396 958 -200 -854 -81 202 59 -37 -549 -1036 -584 68 37 344 864 616 -134 -492 -1528 SS 20260118T133816.0Z 9514.568240 62 1 54.32 2 75.90 115.98 76.36 120.77 0.00 1 0.00 1 0 25 4.083e-02 8.413e-03 2.172e-03 3.805e-04 4.185708e-01 1.878701e-04 4.456752e-03 -6.000000e+00 2.249101e-02 223.95 -2.00 3.09 -2.00 318.14 0.00e+00 1.227925e-03 3.494078e-05 4.523001e-04 -6.000000e+00 1.009304e-03 284.97 -2.00 20.00 -2.00 317.41 0.00e+00 4.018 0.000 302.00 328.00 3 7.3457e-01 5.0060e-04 3.8168e-02 -6.0000e+00 5.5451e-02 -1.6680e-02 5.6847e-04 1.8845e-02 -6.0000e+00 6.0096e-02 -1.3856e-02 3.8326e-04 9.4245e-03 -6.0000e+00 3.5907e-02 4.5768e-03 2.0691e-04 2.8308e-03 -6.0000e+00 1.6034e-02 5.6052e-03 -5.5236e-04 9.6182e-06 2.5813e-05 -6.0000e+00 9.9050e-04 -4.4468e-02 0.0000e+00 11 8 0 10 0 0 46.76 23.58 0.27 -0.04447 -0.04862 826 87 1 5 0 65.750 31.75 19.97 23.58 19.50 2.6 946.57 900000 -11331 -10937 -10237 -12756 -16540 -17162 -15149 -12813 -10446 -10894 -13593 -10751 -6535 -3166 -595 467 434 2421 891 1409 808 450 721 711 -80 -138 -213 -2453 -3443 -1274 -463 538 1370 -1862 -4866 -4325 -3861 -1722 122 827 94 678 937 508 1371 1034 449 187 -319 33 1411 1002 1533 1562 1090 1338 1051 437 204 80 998 1625 2141 2691 717 29 -849 -1297 188 647 858 788 338 401 -256 -1179 -2088 -2575 -2057 -1985 -1658 -1265 -2387 -1826 -817 -237 243 651 1233 800 580 -183 -790 -960 -530 -379 222 1150 729 -18 -411 -1190 -1623 -291 -753 -861 -675 -310 263 888 1375 1083 838 269 -352 -460 -257 -174 313 539 251 451 810 204 600 -140 -625 -57 161 38 -26 -312 -614 -315 34 17 205 430 311 -90 -284 -851 900000 -578 -613 -588 -687 -825 -868 -833 -795 -712 -780 -994 -846 -601 -310 -68 60 59 347 137 226 132 73 123 132 -15 -26 -41 -450 -665 -253 -96 124 356 -511 -1253 -1116 -1034 -542 43 341 40 300 431 236 636 488 212 89 -154 15 717 527 860 939 645 814 659 272 124 48 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