File name: Pandora94s1_GuatemalaCity_20260127_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260423T103813.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20260127_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20260127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260127T140254.7Z 9523.585355 109 1 0.82 2 70.23 116.08 139.28 20.74 0.00 1 0.00 1 0 17 2.117e-02 1.022e-02 1.771e-02 7.203e-03 2.999282e-01 3.485527e-03 3.142556e-03 -6.000000e+00 1.147247e-02 224.12 -2.00 3.09 -2.00 316.71 0.00e+00 9.760633e-04 4.444590e-04 1.053783e-04 -6.000000e+00 5.200922e-04 285.02 -2.00 20.00 -2.00 315.95 0.00e+00 2.926 0.000 302.00 328.00 3 2.4627e+00 9.0493e-03 2.7565e-02 -6.0000e+00 2.8279e-02 -3.7482e-03 1.0209e-02 1.3258e-02 -6.0000e+00 3.0838e-02 -1.9284e-03 6.0239e-03 6.5268e-03 -6.0000e+00 1.8433e-02 1.0476e-04 2.9544e-03 1.9724e-03 -6.0000e+00 7.9970e-03 2.8042e-03 4.3009e-04 1.8490e-04 1.8654e-05 -6.0000e+00 5.1275e-04 3.0313e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.90 0.30 0.00303 0.00626 1 14 1 5 0 408.150 31.75 20.00 23.90 20.92 2.5 950.77 -4038 8779 1791 -1713 2412 -1240 -7394 -7434 -1829 -2400 -10229 2867 -2478 -1168 3295 -2977 1382 936 4927 -1756 -244 -2839 3918 -763 -2236 -848 -1590 1942 -3321 -870 1484 3237 564 -580 -1099 -2139 -2914 110 -113 909 4075 -728 578 -2109 1102 -1236 519 337 -524 -1849 79 -197 5472 -55 2056 511 697 36 -377 585 711 1324 1832 1442 -239 -600 -1495 -436 1002 -274 606 612 23 880 462 324 -696 -2883 -358 -2161 -1527 -1459 -2748 -1924 -1175 -221 206 973 967 1575 483 -362 -838 -627 314 35 161 260 -26 222 -174 -2307 -1539 -102 -885 -366 14 -477 224 1076 1058 811 906 678 -501 -177 -396 -760 990 280 435 744 22 -78 1085 98 -676 166 -20 -446 -76 -500 -467 87 878 -368 -283 695 484 515 35 -924 -1185 -600 1238 275 -246 319 -169 -1073 -1236 -320 -435 -1946 510 -545 -274 858 -841 388 277 1463 -582 -80 -940 1262 -258 -809 -315 -586 640 -1160 -301 516 1211 225 -236 -434 -854 -1232 51 -60 526 2460 -456 369 -1388 703 -812 328 210 -325 -1180 51 -137 3823 -41 1543 381 531 27 -279 446 539 1044 1516 1290 -215 -511 -1201 -355 847 -251 574 601 22 847 412 278 -572 -2332 -291 -1979 -1453 -1487 -2907 -2101 -1329 -257 244 1177 1169 1871 550 -392 -862 -632 329 40 192 335 -35 288 -217 -2739 -1814 -121 -1097 -473 18 -638 314 1529 1559 1215 1336 956 -672 -228 -516 -1045 1403 405 637 1090 32 -110 1486 129 -870 215 -27 -631 -110 -746 -707 133 1391 -608 -464 1156 814 860 57 -1471 -1888 SS 20260127T140756.2Z 9523.588845 112 1 54.30 2 69.14 116.59 138.84 22.26 0.00 1 0.00 1 0 17 1.372e-02 8.277e-03 4.256e-04 1.974e-04 2.864166e-01 9.567068e-05 3.035558e-03 -6.000000e+00 7.434305e-03 224.12 -2.00 3.09 -2.00 316.44 0.00e+00 7.367237e-04 1.144739e-05 1.049582e-04 -6.000000e+00 3.370595e-04 285.02 -2.00 20.00 -2.00 315.71 0.00e+00 2.782 0.000 302.00 328.00 3 3.1700e-01 2.4720e-04 2.6267e-02 -6.0000e+00 1.8325e-02 -9.4202e-03 2.7831e-04 1.2702e-02 -6.0000e+00 1.9984e-02 2.2903e-03 1.6249e-04 6.2593e-03 -6.0000e+00 1.1945e-02 -4.0160e-03 7.8406e-05 1.8344e-03 -6.0000e+00 5.1817e-03 2.7554e-02 2.7551e-04 5.0525e-06 1.7929e-05 -6.0000e+00 3.3231e-04 3.6978e-03 0.0000e+00 11 8 0 10 0 0 99.96 23.90 0.27 0.00370 0.00577 1588 167 1 5 0 34.190 32.00 20.00 23.90 20.89 2.5 950.65 -1003 -477 -1353 -3969 -5284 -4387 -2621 -1680 -845 -2755 -4429 -3031 -1564 -298 1273 709 1088 1538 1562 2034 1134 1069 1500 1279 858 1030 357 -795 -1504 116 594 818 1476 -1449 -3751 -3629 -2892 -1555 -218 48 -427 -154 163 36 703 287 -55 -144 -741 -255 917 742 1160 1191 811 1091 915 480 300 211 971 1499 1917 2368 529 -265 -1005 -1410 157 514 749 606 352 579 15 -768 -1567 -2086 -1742 -1866 -1606 -1362 -2319 -1748 -849 -257 155 592 1118 806 597 -72 -689 -819 -413 -255 300 1246 695 -28 -353 -1163 -1541 -246 -673 -760 -598 -337 230 817 1329 981 750 232 -333 -520 -286 -261 260 500 176 335 727 246 678 -5 -479 57 274 134 19 -270 -542 -263 119 108 225 488 364 -36 -174 -701 -873 -182 -86 -248 -730 -866 -707 -454 -330 -169 -580 -918 -657 -390 -79 360 221 348 515 544 689 392 362 526 481 323 402 138 -306 -545 42 233 330 654 -630 -1593 -1539 -1289 -770 -123 29 -276 -98 107 24 462 190 -36 -92 -490 -163 624 523 860 898 629 830 713 371 235 165 753 1214 1636 2088 469 -229 -819 -1175 136 478 729 592 341 554 14 -679 -1314 -1689 -1450 -1726 -1560 -1418 -2505 -1893 -956 -300 185 723 1358 968 678 -77 -721 -842 -444 -288 354 1590 899 -37 -439 -1397 -1796 -290 -833 -985 -789 -453 316 1173 1972 1444 1085 329 -444 -669 -370 -346 360 723 253 483 1041 339 906 -6 -611 74 374 188 28 -401 -800 -394 185 173 370 801 604 -59 -277 -1096 -1361 SS 20260127T141827.6Z 9523.596152 115 1 54.30 2 66.88 117.72 137.84 25.34 0.00 1 0.00 1 0 17 1.215e-02 8.150e-03 3.011e-04 1.583e-04 2.620021e-01 7.680432e-05 2.784491e-03 -6.000000e+00 6.582188e-03 224.12 -2.00 3.09 -2.00 316.07 0.00e+00 6.468225e-04 8.438569e-06 7.874618e-05 -6.000000e+00 2.984183e-04 285.02 -2.00 20.00 -2.00 315.35 0.00e+00 2.527 0.000 302.00 328.00 3 1.1595e-01 1.9755e-04 2.3899e-02 -6.0000e+00 1.6225e-02 -5.3146e-03 2.2212e-04 1.1610e-02 -6.0000e+00 1.7693e-02 2.3306e-03 1.2849e-04 5.7174e-03 -6.0000e+00 1.0576e-02 -4.5421e-03 6.0715e-05 1.6665e-03 -6.0000e+00 4.5879e-03 4.2918e-02 2.7598e-04 4.0527e-06 1.6809e-05 -6.0000e+00 2.9421e-04 3.5319e-03 0.0000e+00 11 8 0 10 0 0 99.97 23.90 0.29 0.00353 0.00561 2382 250 1 5 0 22.790 32.00 19.99 23.90 21.40 2.5 953.72 -667 -149 -968 -3538 -4110 -3488 -1671 -799 -275 -2026 -3659 -2322 -1259 30 1353 642 848 1265 1537 1934 1044 996 1293 1036 583 1044 132 -608 -1246 380 760 827 1458 -1451 -3618 -3565 -2700 -1378 -237 -21 -487 -309 77 -167 536 162 -120 -185 -795 -201 828 657 1043 1163 818 1081 916 456 318 207 987 1392 1830 2229 480 -358 -971 -1425 186 532 749 608 382 610 47 -688 -1516 -2012 -1646 -1840 -1571 -1357 -2306 -1737 -801 -259 192 591 1120 803 582 -50 -677 -781 -351 -211 241 1211 701 16 -338 -1087 -1540 -246 -688 -790 -626 -342 219 771 1297 969 771 230 -362 -502 -297 -265 233 522 164 322 705 222 662 -3 -420 65 235 112 44 -258 -544 -285 131 117 232 483 387 -17 -165 -718 -860 -145 -35 -229 -771 -790 -659 -338 -183 -65 -499 -882 -581 -361 9 439 228 309 479 568 740 407 380 510 437 246 455 57 -259 -497 150 325 361 697 -680 -1647 -1619 -1289 -732 -137 -14 -324 -213 54 -118 377 115 -83 -125 -530 -134 589 483 776 911 658 853 739 365 258 167 793 1169 1615 2029 437 -317 -833 -1199 162 499 737 601 387 592 44 -614 -1279 -1692 -1416 -1695 -1519 -1404 -2473 -1869 -896 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