File name: Pandora94s1_GuatemalaCity_20260307_L2Fit_fout2c4d20250225p1-8.txt
File generation date: 20260423T105243.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Daniel Alvarez
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 94
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora94_OF_v3d20240409.txt
Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt
Level 1 file used: Pandora94s1_GuatemalaCity_20260307_L1_smca1c4d20250225p1-8.txt
Full location name: Ciudad de Guatemala
Short location name: GuatemalaCity
Country of location: Guatemala
Location latitude [deg]: 14.6192
Location longitude [deg]: -90.4838
Location altitude [m]: 1547
Local noon date: 20260307
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 201 343
Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20260307T135228.9Z 9562.578112 272 1 1.58 2 67.48 102.02 78.51 248.12 0.00 1 0.00 1 0 17 1.335e-02 8.456e-03 3.281e-03 1.622e-03 2.803475e-01 7.902534e-04 2.959823e-03 -6.000000e+00 7.288349e-03 226.00 -2.00 3.09 -2.00 316.26 0.00e+00 6.380923e-04 9.011145e-05 1.036982e-04 -6.000000e+00 3.286323e-04 285.40 -2.00 20.00 -2.00 315.52 0.00e+00 2.590 0.000 302.00 328.00 3 1.0845e+00 2.0463e-03 2.4837e-02 -6.0000e+00 1.8039e-02 -4.2576e-03 2.2990e-03 1.2494e-02 -6.0000e+00 1.9644e-02 -8.3483e-04 1.3335e-03 6.1287e-03 -6.0000e+00 1.1727e-02 -3.1057e-03 6.3402e-04 1.7620e-03 -6.0000e+00 5.0691e-03 1.4967e-02 2.5037e-04 4.1521e-05 1.7714e-05 -6.0000e+00 3.2358e-04 2.7479e-03 0.0000e+00 12 9 1 12 1 1 97.44 24.16 0.27 0.00275 0.00463 19 73 1 5 0 78.600 32.00 20.00 24.16 23.45 2.5 961.03 -1512 158 -305 -3858 -6323 -4055 -1903 -823 -426 -1868 -4088 -2461 -674 -441 2203 310 401 1333 1089 1624 1655 869 1395 1700 1112 1029 -384 -947 -932 1240 263 609 1370 -1621 -3350 -3395 -2779 -1457 -36 -176 -333 -131 -174 -35 515 205 44 -218 -864 -247 953 859 891 1160 914 979 832 516 265 254 688 1253 1710 2228 665 -325 -1199 -1437 205 418 652 933 286 828 -183 -620 -1739 -2122 -1829 -1762 -1875 -972 -2169 -1683 -702 -369 211 611 940 870 540 0 -607 -1001 -617 -189 355 1430 878 10 -186 -1246 -1795 -323 -616 -862 -755 -299 194 672 1388 1095 871 164 -490 -659 -298 -250 186 556 334 494 709 184 795 -67 -443 -27 432 115 34 -474 -700 -322 166 35 139 468 431 175 -199 -671 -856 -293 32 -64 -752 -1109 -745 -346 -169 -97 -446 -963 -560 -175 -124 695 102 136 469 400 582 599 310 515 669 439 423 -157 -382 -351 460 108 256 631 -735 -1470 -1487 -1284 -749 -20 -110 -215 -88 -120 -24 354 142 30 -145 -568 -163 643 626 660 872 706 772 672 413 207 197 554 1054 1513 2037 609 -280 -1008 -1184 176 387 633 937 286 789 -168 -543 -1443 -1756 -1555 -1606 -1808 -999 -2322 -1812 -786 -430 251 746 1144 1041 612 0 -628 -1016 -655 -210 427 1805 1155 13 -229 -1483 -2072 -377 -776 -1111 -991 -399 265 960 2045 1601 1250 230 -647 -858 -390 -334 254 795 487 703 1006 251 1075 -88 -571 -35 578 158 48 -693 -1017 -486 256 55 225 758 706 285 -318 -1035 -1314
SS 20260307T140717.3Z 9562.588395 277 1 3.61 2 63.99 103.30 81.77 249.22 0.00 1 0.00 1 0 17 1.224e-02 8.879e-03 4.378e-03 2.475e-03 2.469756e-01 1.209011e-03 2.608135e-03 -6.000000e+00 6.680749e-03 226.00 -2.00 3.09 -2.00 315.81 0.00e+00 5.585601e-04 1.247156e-04 8.387504e-05 -6.000000e+00 3.012111e-04 285.40 -2.00 20.00 -2.00 315.10 0.00e+00 2.267 0.000 302.00 328.00 3 2.9609e+00 3.1125e-03 2.1760e-02 -6.0000e+00 1.6536e-02 1.2931e-02 3.4886e-03 1.0974e-02 -6.0000e+00 1.8006e-02 1.4736e-03 2.0111e-03 5.3773e-03 -6.0000e+00 1.0749e-02 -4.2712e-03 9.3715e-04 1.5388e-03 -6.0000e+00 4.6468e-03 3.1151e-03 3.3376e-04 6.3249e-05 1.6034e-05 -6.0000e+00 2.9656e-04 2.1690e-03 0.0000e+00 12 9 1 12 9 1 99.84 24.18 0.36 0.00217 0.00468 7 13 1 5 0 450.930 32.00 20.00 24.18 24.37 2.4 965.55 -1058 1213 -1387 -3097 -3541 -2545 386 -1717 664 -1106 -2311 -1829 -1605 -2009 -646 1548 1029 574 1923 2467 938 1689 725 811 1498 1103 340 -1656 -525 984 689 -273 1928 -1600 -3936 -3270 -2831 -905 102 -164 -769 -613 -198 -320 406 -170 -113 74 -799 -403 778 767 998 1763 560 518 846 1125 227 553 747 1815 1891 2139 182 101 -1585 -1525 124 853 802 742 296 680 -199 -228 -1956 -1937 -2200 -1694 -1366 -1261 -2748 -1630 -685 -217 61 449 1172 624 835 233 -647 -896 -303 -327 132 1203 498 -282 -71 -803 -1751 -224 -1054 -818 -543 -209 89 853 1525 1094 582 362 -494 -424 -272 -370 677 468 207 466 487 256 828 -27 -612 -40 160 236 -151 -81 -618 -308 13 95 330 679 568 115 -292 -929 -1013 -253 303 -358 -730 -794 -557 82 -428 179 -312 -633 -521 -487 -656 -238 566 387 226 774 1026 400 698 313 350 676 518 158 -723 -223 412 313 -127 963 -785 -1881 -1547 -1407 -495 63 -108 -548 -431 -143 -231 290 -122 -83 53 -559 -283 577 585 765 1414 464 421 699 915 189 457 614 1604 1749 2031 173 90 -1375 -1286 108 820 807 747 296 675 -191 -202 -1651 -1620 -1880 -1585 -1328 -1307 -2956 -1800 -783 -257 74 556 1442 739 963 254 -665 -929 -325 -364 158 1489 640 -365 -87 -936 -2002 -267 -1313 -1033 -714 -278 121 1193 2181 1584 830 492 -652 -539 -347 -481 914 662 292 660 672 348 1092 -35 -777 -51 207 318 -209 -114 -887 -445 19 146 518 1062 898 183 -447 -1407 -1494
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