File name: Pandora94s1_GuatemalaCity_20260309_L2Fit_fout2c4d20250225p1-8.txt
File generation date: 20260423T105343.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Daniel Alvarez
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 94
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora94_OF_v3d20240409.txt
Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt
Level 1 file used: Pandora94s1_GuatemalaCity_20260309_L1_smca1c4d20250225p1-8.txt
Full location name: Ciudad de Guatemala
Short location name: GuatemalaCity
Country of location: Guatemala
Location latitude [deg]: 14.6192
Location longitude [deg]: -90.4838
Location altitude [m]: 1547
Local noon date: 20260309
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 201 343
Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20260309T143909.1Z 9564.610522 301 1 0.33 2 56.14 105.61 71.93 236.41 0.00 1 0.00 1 0 17 1.256e-02 9.823e-03 7.458e-03 5.265e-03 1.978691e-01 2.593738e-03 2.115126e-03 -6.000000e+00 6.856192e-03 226.14 -2.00 3.09 -2.00 314.85 0.00e+00 7.244258e-04 2.211345e-04 1.676865e-05 -6.000000e+00 3.090061e-04 285.43 -2.00 20.00 -2.00 314.23 0.00e+00 1.789 0.000 302.00 328.00 3 2.0175e+00 6.6155e-03 1.7276e-02 -6.0000e+00 1.6975e-02 1.3607e-02 7.3808e-03 8.8841e-03 -6.0000e+00 1.8483e-02 2.7472e-03 4.2376e-03 4.3334e-03 -6.0000e+00 1.1033e-02 -6.9384e-03 1.8997e-03 1.2980e-03 -6.0000e+00 4.7678e-03 1.2873e-02 2.7824e-04 1.3382e-04 1.3894e-05 -6.0000e+00 3.0422e-04 2.5298e-03 0.0000e+00 12 9 9 12 1 1 999.00 24.20 0.36 0.00253 0.00462 1 35 1 5 0 163.700 32.00 20.00 24.20 23.43 2.5 961.98 -586 495 1480 -1290 -2569 -3744 237 9 -731 -1164 -4906 -353 1680 1981 824 -29 910 361 1227 141 1837 -953 2449 1600 34 -939 183 542 219 426 424 -505 1127 -669 -4284 -4254 -3235 -1166 -852 225 -381 697 -136 -344 137 -510 452 -277 -536 -379 1486 682 554 2201 1672 547 63 855 -39 119 1774 1163 1976 1690 53 -241 -1027 -1402 222 519 726 -31 336 499 333 -1063 -678 -1970 -1220 -1600 -2434 -539 -2565 -2039 -901 -750 -61 -167 1705 759 896 -47 -341 -172 -276 -463 228 2226 154 100 -892 -1356 -1025 340 -338 -1235 -827 93 -278 671 1773 1288 740 725 59 -1157 -194 235 -173 245 -113 127 939 242 708 76 -503 -369 -322 -465 438 -914 -187 242 674 38 529 693 -103 -344 -710 478 -1273 -213 178 528 -446 -828 -1195 79 3 -275 -448 -1860 -132 696 882 381 -14 455 179 623 75 968 -503 1282 856 19 -534 105 296 111 222 225 -276 658 -381 -2359 -2326 -1873 -750 -592 173 -303 548 -111 -280 110 -413 362 -215 -418 -294 1165 557 460 1885 1464 477 56 748 -34 105 1553 1077 1910 1690 53 -225 -915 -1246 204 505 743 -33 346 507 323 -979 -592 -1694 -1062 -1499 -2430 -566 -2750 -2255 -1038 -884 -74 -203 2085 918 1040 -51 -351 -175 -293 -516 266 2693 197 124 -1084 -1586 -1157 390 -413 -1556 -1060 120 -369 918 2471 1808 1013 952 74 -1401 -233 288 -227 330 -153 172 1262 320 900 94 -605 -443 -406 -600 574 -1231 -251 329 956 55 776 1023 -155 -514 -1030 687 -1813
SS 20260309T152253.8Z 9564.640900 335 1 4.17 2 46.08 111.06 80.72 240.40 0.00 1 0.00 1 0 17 1.033e-02 8.468e-03 1.102e-03 8.617e-04 1.626185e-01 4.274371e-04 1.750242e-03 -6.000000e+00 5.641156e-03 226.14 -2.00 3.09 -2.00 314.23 0.00e+00 4.603238e-04 3.254643e-05 1.520481e-05 -6.000000e+00 2.542181e-04 285.43 -2.00 20.00 -2.00 313.67 0.00e+00 1.439 0.000 302.00 328.00 3 1.9621e+00 1.0840e-03 1.3988e-02 -6.0000e+00 1.3967e-02 1.7378e-02 1.2049e-03 7.2930e-03 -6.0000e+00 1.5207e-02 -9.2330e-04 6.9389e-04 3.5678e-03 -6.0000e+00 9.0774e-03 -4.4015e-03 3.0621e-04 1.0297e-03 -6.0000e+00 3.9232e-03 1.9425e-02 1.9368e-04 2.1850e-05 1.1983e-05 -6.0000e+00 2.5026e-04 1.8159e-03 0.0000e+00 12 9 1 12 1 1 99.77 24.32 0.31 0.00182 0.00327 39 55 1 5 0 104.050 32.25 20.00 24.32 24.01 2.5 964.28 1 645 -77 -2380 -2900 -1763 257 456 754 -756 -2160 -1482 -863 -15 1420 179 671 771 983 1672 765 1048 1309 1178 695 1218 149 -404 -990 452 589 835 1609 -1352 -3536 -3269 -2485 -1617 -478 -370 -595 -543 -267 -389 272 -191 -269 -355 -805 -218 873 570 1028 1163 729 1037 1050 558 218 272 723 1265 1800 2073 388 -352 -1028 -1415 103 463 790 704 437 823 -1 -550 -1431 -1754 -1513 -1776 -1545 -1323 -2213 -1719 -795 -272 114 445 1117 648 526 -72 -630 -682 -295 -230 211 1185 823 69 -236 -945 -1353 -85 -632 -737 -646 -324 79 647 1250 1039 899 282 -204 -631 -385 -484 75 519 177 267 628 286 810 110 -440 -113 265 93 61 -174 -561 -234 106 128 263 428 315 97 -109 -762 -952 1 286 -34 -1006 -1123 -694 101 193 350 -345 -988 -685 -422 -8 776 101 377 443 578 1009 450 623 793 722 446 770 93 -240 -566 259 340 507 1004 -865 -2148 -1961 -1578 -1107 -363 -302 -502 -470 -229 -333 236 -166 -225 -295 -645 -178 719 485 908 1039 664 953 953 502 198 246 656 1195 1773 2090 396 -340 -939 -1283 96 455 816 734 466 844 -1 -512 -1278 -1517 -1320 -1655 -1553 -1378 -2379 -1903 -896 -320 138 552 1377 770 601 -79 -652 -695 -309 -251 239 1441 1010 84 -277 -1073 -1499 -96 -755 -902 -805 -417 104 869 1709 1423 1193 361 -248 -738 -450 -579 94 672 237 352 825 368 1003 135 -516 -131 321 116 78 -226 -717 -309 145 177 371 606 452 138 -151 -1052 -1312
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