File name: Pandora94s1_GuatemalaCity_20260404_L2Fit_fout2c4d20250225p1-8.txt
File generation date: 20260423T110304.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Daniel Alvarez
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 94
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora94_OF_v3d20240409.txt
Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt
Level 1 file used: Pandora94s1_GuatemalaCity_20260404_L1_smca1c4d20250225p1-8.txt
Full location name: Ciudad de Guatemala
Short location name: GuatemalaCity
Country of location: Guatemala
Location latitude [deg]: 14.6192
Location longitude [deg]: -90.4838
Location altitude [m]: 1547
Local noon date: 20260404
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 201 343
Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20260404T123422.1Z 9590.523867 234 1 53.64 2 81.44 86.18 80.07 245.80 0.00 1 0.00 1 0 17 4.672e-01 1.298e-02 1.815e-01 4.500e-03 6.605414e-01 2.400759e-03 6.871025e-03 -6.000000e+00 2.612235e-01 228.00 -2.00 3.09 -2.00 320.99 0.00e+00 3.468431e-03 1.117511e-03 3.128411e-03 -6.000000e+00 1.321692e-02 285.80 -2.00 20.00 -2.00 320.38 0.00e+00 6.341 0.001 302.00 328.00 3 2.8283e+00 7.9571e-03 6.2008e-02 -6.0000e+00 6.5126e-01 -6.0974e-03 1.1127e-02 3.5199e-02 -6.0000e+00 7.1060e-01 -3.2385e-02 1.1642e-02 1.9301e-02 -6.0000e+00 4.1989e-01 4.4230e-03 5.6018e-03 6.2017e-03 -6.0000e+00 1.8212e-01 8.5328e-05 -2.4114e-04 1.1602e-04 8.0533e-05 -6.0000e+00 1.1710e-02 3.8715e-03 0.0000e+00 12 8 8 10 0 0 67.78 24.16 0.60 0.00387 0.00206 28 3 1 5 0 1915.620 32.00 20.00 24.16 23.11 2.5 959.44 900000 -209151 25359 -210363 900000 -213333 900000 -198998 -153728 900000 -182359 900000 900000 900000 -43398 -24826 -44555 900000 130753 48592 900000 900000 -27311 900000 -55151 -13517 -39143 -55194 9707 -3528 -16693 51559 -3447 -2818 -48326 39000 -17235 12706 -11398 20653 1804 8407 8854 -12355 8128 18496 15504 4686 9720 -5364 -4384 -6811 3971 -5554 4628 4370 -1946 6777 -1286 270 -3419 8827 5928 10378 1032 5578 705 -3110 639 327 2301 2734 1368 884 1002 1765 -4981 2432 1815 -1604 -493 -3464 -4158 -2685 335 837 1176 554 1369 1223 2768 -1935 -2108 -712 -2031 -1 186 1216 780 -783 -801 -1785 -2324 -1279 -121 -615 -1970 297 -221 325 1550 1664 993 -527 -308 -811 -1487 -189 523 835 193 619 302 589 994 655 -2092 -670 482 94 425 -212 -1136 -444 -314 -20 819 769 768 233 -124 -570 -1038 900000 -2414 111 -2512 900000 -2463 900000 -2614 -1616 900000 -2875 900000 900000 900000 -456 -261 -644 900000 573 362 900000 900000 -478 900000 -1546 -266 -1011 -1619 149 -70 -468 880 -121 -104 -2603 888 -785 523 -749 1185 140 655 729 -1288 705 1498 1331 470 979 -679 -626 -1124 647 -1092 869 861 -423 1338 -266 54 -749 1925 1537 2940 335 1658 219 -1040 212 128 969 1192 592 361 371 634 -1808 845 727 -730 -260 -2165 -2855 -1911 229 607 896 436 1067 915 2059 -1411 -1478 -513 -1554 -1 188 1303 917 -924 -877 -1896 -2247 -1262 -130 -641 -2198 347 -285 439 2312 2619 1567 -811 -444 -1122 -2104 -278 819 1362 311 949 450 846 1367 941 -2935 -973 742 166 763 -405 -2295 -888 -678 -46 1873 1690 1695 524 -262 -1136 -2135
SS 20260404T133054.9Z 9590.563136 267 1 23.64 2 67.77 89.61 92.40 249.53 0.00 1 0.00 1 0 17 1.466e-02 8.265e-03 2.765e-03 1.035e-03 3.023485e-01 5.067271e-04 3.171220e-03 -6.000000e+00 8.059037e-03 228.00 -2.00 3.09 -2.00 316.86 0.00e+00 6.079071e-04 6.618859e-05 1.652755e-04 -6.000000e+00 3.612962e-04 285.80 -2.00 20.00 -2.00 316.08 0.00e+00 2.621 0.000 302.00 328.00 3 2.7991e+00 1.3296e-03 2.5687e-02 -6.0000e+00 2.0037e-02 -1.0257e-02 1.4963e-03 1.3600e-02 -6.0000e+00 2.1786e-02 5.2164e-03 8.8603e-04 6.6583e-03 -6.0000e+00 1.2988e-02 -5.7835e-03 4.3577e-04 1.8921e-03 -6.0000e+00 5.5918e-03 2.5262e-03 2.6606e-04 2.6518e-05 1.7711e-05 -6.0000e+00 3.5527e-04 2.5560e-03 0.0000e+00 12 9 1 12 9 1 99.98 24.30 0.30 0.00256 0.00456 87 21 1 5 0 268.560 32.00 20.00 24.30 25.12 2.4 967.91 -1741 -503 -1233 -5574 -2954 -4448 -1875 -3030 -1643 -3356 -6921 -2789 -1296 322 1501 395 -66 1738 1134 1500 1192 658 980 1348 463 1108 79 -202 -1694 -92 121 932 1578 -1672 -4163 -3780 -2893 -1574 -297 -71 -540 14 287 -196 678 556 94 -40 -877 -244 646 749 1071 1134 669 972 855 574 142 26 734 1454 2043 2337 694 2 -812 -1579 376 550 883 704 389 674 121 -681 -1672 -2404 -1588 -1837 -1754 -1338 -2345 -1842 -784 -244 376 674 1221 825 628 -55 -663 -869 -432 -276 454 918 673 -150 -339 -1177 -1703 -293 -726 -829 -627 -270 192 856 1397 1115 780 114 -381 -593 -225 -340 342 533 208 367 609 119 521 64 -576 -80 224 119 21 -204 -548 -110 145 174 147 527 412 -9 -122 -804 -822 -227 -70 -176 -750 -341 -518 -233 -438 -262 -562 -1166 -480 -257 67 359 105 -18 498 315 433 350 190 294 433 159 393 28 -66 -529 -29 41 346 600 -664 -1530 -1383 -1177 -702 -150 -39 -323 8 183 -126 432 357 59 -25 -542 -152 407 510 729 818 498 739 633 443 107 20 569 1159 1693 2081 621 2 -656 -1262 308 497 826 684 375 649 108 -570 -1347 -1875 -1318 -1677 -1725 -1393 -2510 -1959 -891 -284 443 815 1467 990 721 -60 -696 -897 -462 -316 554 1160 877 -198 -432 -1426 -1942 -347 -918 -1060 -837 -364 262 1255 2099 1650 1148 162 -514 -779 -297 -455 474 789 304 540 872 170 702 86 -755 -105 311 166 31 -301 -824 -172 235 288 240 880 695 -15 -198 -1297 -1289
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