File name: Pandora94s1_GuatemalaCity_20260422_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260521T164423.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20260422_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20260422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260422T130609.4Z 9608.545943 27 1 53.68 2 71.27 81.70 128.13 37.73 0.00 1 0.00 1 0 17 2.596e-02 8.443e-03 9.284e-03 2.007e-03 3.408923e-01 9.845002e-04 3.557021e-03 -6.000000e+00 1.431248e-02 228.77 -2.00 3.09 -2.00 317.87 0.00e+00 9.316885e-04 1.694409e-04 3.617212e-04 -6.000000e+00 6.407066e-04 286.07 -2.00 20.00 -2.00 317.08 0.00e+00 3.077 0.000 302.00 328.00 3 4.3241e+00 2.6361e-03 2.9896e-02 -6.0000e+00 3.5647e-02 1.0974e-02 2.9919e-03 1.5514e-02 -6.0000e+00 3.8735e-02 1.3875e-02 1.9058e-03 7.6003e-03 -6.0000e+00 2.3082e-02 -1.1664e-02 9.8944e-04 2.1923e-03 -6.0000e+00 9.9210e-03 3.5492e-04 1.9561e-04 5.2020e-05 1.9414e-05 -6.0000e+00 6.2943e-04 4.1617e-03 0.0000e+00 12 9 1 12 9 1 99.42 24.18 0.38 0.00416 0.00563 21 2 1 5 0 2439.590 32.00 20.00 24.18 24.52 2.4 963.94 -6664 4459 -5225 -15722 -971 -14411 3778 -5906 569 845 -8601 -2462 -1873 -3344 -3277 -376 139 4547 2487 2088 1547 3006 -84 122 -1065 914 888 -1132 -1754 -31 -2918 1866 1760 -2688 -4589 -2838 -4006 -1247 -568 6 -829 -64 714 -275 879 1837 629 -100 -366 -1300 -80 953 3 761 771 1640 714 584 -339 -177 304 1881 2895 3263 639 269 -1490 -1751 705 552 512 1025 424 602 265 -1138 -1502 -2655 -1275 -1807 -1059 -1474 -2180 -1731 -403 -65 162 511 991 882 905 -487 -758 -912 -206 -29 220 770 783 102 -375 -1387 -1735 -473 -479 -767 -755 -119 -141 828 1215 1082 892 25 -430 -717 -110 -305 404 553 393 291 439 169 765 5 -1054 -205 230 -258 161 -230 -531 -453 6 -40 439 796 325 33 -62 -494 -871 -464 303 -400 -1216 -57 -973 234 -465 47 72 -791 -230 -206 -443 -509 -57 22 731 428 378 286 538 -16 25 -238 209 201 -243 -358 -6 -689 465 491 -795 -1254 -764 -1227 -444 -226 3 -385 -31 354 -138 438 914 312 -49 -180 -661 -44 560 2 470 490 1061 478 387 -221 -114 203 1354 2124 2585 516 199 -1129 -1314 531 483 456 942 387 524 227 -878 -1136 -1967 -1007 -1551 -958 -1494 -2228 -1834 -455 -74 194 628 1210 1032 1029 -513 -780 -928 -214 -34 271 1001 1031 138 -474 -1692 -1983 -562 -595 -999 -1029 -161 -201 1212 1896 1720 1368 36 -598 -990 -152 -422 599 832 598 433 665 246 1050 7 -1393 -273 319 -391 246 -362 -854 -727 9 -69 768 1421 587 58 -109 -830 -1427 SS 20260422T131655.0Z 9608.553415 30 1 54.28 2 68.69 82.25 126.60 39.83 0.00 1 0.00 1 0 17 1.403e-02 7.901e-03 5.764e-04 2.300e-04 3.052083e-01 1.129302e-04 3.195702e-03 -6.000000e+00 7.733277e-03 228.77 -2.00 3.09 -2.00 316.81 0.00e+00 7.185474e-04 1.452007e-05 1.362138e-04 -6.000000e+00 3.461700e-04 286.07 -2.00 20.00 -2.00 316.03 0.00e+00 2.727 0.000 302.00 328.00 3 5.6828e-01 2.9637e-04 2.6527e-02 -6.0000e+00 1.9260e-02 -1.5746e-02 3.3310e-04 1.3784e-02 -6.0000e+00 2.0929e-02 1.1114e-03 1.9570e-04 6.7183e-03 -6.0000e+00 1.2472e-02 -3.6761e-03 9.5524e-05 1.9169e-03 -6.0000e+00 5.3607e-03 2.1613e-02 2.8052e-04 5.9062e-06 1.8202e-05 -6.0000e+00 3.4007e-04 3.8752e-03 0.0000e+00 11 8 0 10 0 0 99.60 24.21 0.26 0.00388 0.00598 1731 182 1 5 0 31.350 32.00 20.00 24.21 24.49 2.4 964.84 -1407 -510 -1450 -4146 -5514 -4983 -2678 -1942 -989 -2935 -4971 -3413 -1722 -279 815 328 721 1220 1555 1878 968 898 1512 1102 479 1078 85 -830 -1517 254 700 1095 1624 -1380 -3653 -3607 -2714 -1299 -232 20 -443 -271 189 -199 656 287 -19 -278 -826 -231 869 710 1077 1169 786 1077 929 477 212 194 1036 1438 1953 2362 547 -262 -904 -1346 224 606 776 641 389 546 3 -744 -1571 -1938 -1644 -1789 -1497 -1299 -2317 -1721 -835 -251 183 639 1117 796 643 -35 -594 -777 -388 -244 222 1158 610 -96 -399 -1138 -1528 -286 -704 -794 -608 -345 200 747 1250 936 737 201 -359 -530 -266 -265 267 518 153 350 706 234 647 3 -473 60 268 121 52 -273 -477 -228 157 102 233 476 361 -24 -174 -705 -859 -204 -79 -231 -613 -729 -651 -375 -310 -160 -500 -840 -605 -352 -66 203 90 205 364 449 564 297 270 471 371 172 373 29 -286 -494 83 250 398 652 -577 -1411 -1394 -1094 -615 -118 11 -269 -171 116 -124 404 178 -12 -176 -520 -147 561 473 758 832 577 807 714 364 158 144 792 1144 1626 2027 473 -215 -730 -1073 185 555 740 636 382 513 3 -628 -1267 -1578 -1372 -1587 -1437 -1333 -2460 -1891 -948 -294 218 780 1357 929 737 -38 -616 -794 -413 -280 266 1489 815 -126 -501 -1346 -1759 -342 -878 -1037 -805 -463 273 1069 1845 1405 1093 286 -484 -692 -350 -356 373 752 226 505 1017 334 871 5 -615 78 371 172 76 -409 -729 -353 252 169 383 800 612 -39 -283 -1131 -1342 SS 20260422T132644.6Z 9608.560238 33 1 54.30 2 66.34 82.74 125.14 41.65 0.00 1 0.00 1 0 17 1.242e-02 8.103e-03 3.371e-04 1.684e-04 2.783218e-01 8.297250e-05 2.923616e-03 -6.000000e+00 6.851048e-03 228.77 -2.00 3.09 -2.00 316.25 0.00e+00 6.398465e-04 9.329186e-06 9.065007e-05 -6.000000e+00 3.066646e-04 286.07 -2.00 20.00 -2.00 315.49 0.00e+00 2.474 0.000 302.00 328.00 3 2.1643e-01 2.1588e-04 2.4088e-02 -6.0000e+00 1.7063e-02 -1.4567e-02 2.4198e-04 1.2549e-02 -6.0000e+00 1.8541e-02 1.7892e-03 1.3990e-04 6.1072e-03 -6.0000e+00 1.1049e-02 -3.7777e-03 6.5978e-05 1.7339e-03 -6.0000e+00 4.7493e-03 3.9269e-02 2.4959e-04 4.3171e-06 1.7395e-05 -6.0000e+00 3.0126e-04 3.5780e-03 0.0000e+00 11 8 0 10 0 0 98.86 24.23 0.28 0.00358 0.00545 1899 199 1 5 0 28.590 32.00 20.00 24.23 25.24 2.4 968.49 -632 -159 -740 -3672 -4202 -3531 -1956 -904 -444 -2237 -3973 -2569 -1261 99 1473 659 968 1201 1536 1985 1000 1131 1439 1192 658 1220 118 -646 -1361 233 695 831 1433 -1527 -3656 -3584 -2616 -1421 -240 -103 -442 -342 127 -172 591 205 -187 -271 -866 -341 804 688 1057 1104 747 1083 902 490 256 209 971 1406 1898 2281 534 -247 -933 -1329 206 582 771 646 369 578 9 -687 -1475 -1952 -1616 -1826 -1544 -1336 -2282 -1685 -800 -244 224 628 1157 826 629 -52 -668 -809 -347 -245 240 1183 689 -7 -346 -1124 -1543 -258 -658 -782 -612 -352 203 743 1251 949 746 200 -364 -500 -318 -230 246 510 150 347 687 237 674 20 -436 74 207 63 35 -241 -533 -267 150 124 250 499 391 -9 -168 -707 -889 -123 -33 -157 -723 -792 -655 -361 -189 -103 -504 -948 -593 -334 28 474 218 330 428 568 717 369 408 537 477 264 506 49 -263 -521 88 287 352 631 -698 -1624 -1590 -1221 -739 -137 -65 -289 -232 85 -116 394 138 -128 -182 -575 -228 550 488 789 839 584 863 710 396 202 165 789 1195 1639 2038 494 -215 -789 -1104 178 543 755 637 361 558 8 -608 -1233 -1628 -1384 -1682 -1498 -1391 -2468 -1830 -905 -287 269 754 1419 973 719 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