File name: Pandora94s1_GuatemalaCity_20260524_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260525T061936.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20260524_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20260524 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260524T131441.9Z 9640.551874 71 1 39.99 2 67.44 73.17 161.10 9.43 0.00 1 0.00 1 0 17 1.341e-02 8.269e-03 4.181e-03 1.396e-03 3.041851e-01 6.842736e-04 3.182764e-03 -6.000000e+00 7.375796e-03 228.45 -2.00 3.09 -2.00 317.12 0.00e+00 6.696144e-04 9.545629e-05 2.399605e-04 -6.000000e+00 3.317484e-04 286.55 -2.00 20.00 -2.00 316.31 0.00e+00 2.585 0.000 302.00 328.00 3 3.8792e+00 1.8073e-03 2.5501e-02 -6.0000e+00 1.8351e-02 -2.5098e-02 2.0366e-03 1.3704e-02 -6.0000e+00 1.9953e-02 4.5430e-03 1.2191e-03 6.6953e-03 -6.0000e+00 1.1897e-02 -6.2561e-03 6.0752e-04 1.8912e-03 -6.0000e+00 5.1115e-03 8.8836e-04 3.3878e-04 3.6058e-05 1.7910e-05 -6.0000e+00 3.2532e-04 1.4028e-02 0.0000e+00 12 9 1 12 1 1 99.85 24.66 0.32 0.01403 0.01657 35 5 1 5 0 1110.670 32.25 20.00 24.66 25.97 2.5 970.56 -1461 1553 -1057 -3664 -1907 -6843 1132 -2291 -721 -364 -3288 -101 -1366 -1432 -653 -1395 1230 -117 1683 1909 -13 1763 -450 588 1151 327 -403 -1920 -417 719 -316 2722 110 -1903 -4089 -3721 -3215 -1309 -178 -131 -736 -130 433 -250 602 518 161 281 -525 -562 577 219 1103 1186 939 1227 851 522 -191 128 929 1874 2286 2423 539 -410 -1199 -984 454 756 850 443 506 198 22 -878 -1830 -1844 -1335 -2017 -1743 -1453 -2211 -1588 -571 43 437 917 917 899 462 -290 -879 -964 -721 -231 230 1244 783 -74 -491 -1248 -1755 -490 -704 -657 -759 25 292 910 1354 1102 739 348 -456 -520 -139 -403 246 592 60 405 723 183 502 -186 -915 13 50 130 -137 -217 -661 -328 151 -13 300 520 441 190 -69 -785 -681 -161 178 -125 -440 -200 -756 128 -307 -96 -50 -448 -14 -231 -283 -148 -320 285 -29 427 504 -3 462 -126 175 361 108 -131 -585 -118 205 -101 922 39 -689 -1482 -1361 -1219 -582 -89 -70 -428 -78 251 -146 372 302 98 168 -313 -342 353 145 768 823 670 894 636 386 -139 92 694 1433 1911 2058 457 -335 -927 -750 378 688 793 429 482 181 19 -735 -1491 -1456 -1073 -1785 -1647 -1447 -2346 -1747 -642 49 526 1127 1124 1050 520 -314 -918 -999 -775 -264 280 1605 1029 -95 -610 -1477 -2061 -578 -879 -856 -995 33 404 1301 2047 1687 1086 495 -619 -696 -188 -551 347 889 89 601 1043 263 685 -255 -1183 17 69 186 -208 -324 -1007 -521 248 -22 506 899 767 321 -112 -1272 -1076 SS 20260524T135723.6Z 9640.581523 82 1 54.21 2 57.52 74.35 157.33 36.40 0.00 1 0.00 1 0 17 1.084e-02 8.193e-03 8.396e-04 5.104e-04 2.207873e-01 2.516813e-04 2.327650e-03 -6.000000e+00 5.966510e-03 228.45 -2.00 3.09 -2.00 315.55 0.00e+00 4.979892e-04 2.447334e-05 6.092562e-05 -6.000000e+00 2.683099e-04 286.55 -2.00 20.00 -2.00 314.83 0.00e+00 1.856 0.000 302.00 328.00 3 2.9894e+00 6.4920e-04 1.8351e-02 -6.0000e+00 1.4845e-02 -2.2570e-02 7.2589e-04 9.9125e-03 -6.0000e+00 1.6140e-02 3.6655e-03 4.1646e-04 4.8294e-03 -6.0000e+00 9.6236e-03 -5.6914e-03 1.8984e-04 1.3631e-03 -6.0000e+00 4.1355e-03 4.4773e-03 4.3863e-04 1.3052e-05 1.4488e-05 -6.0000e+00 2.6310e-04 1.2696e-02 0.0000e+00 11 8 0 10 0 0 99.98 24.89 0.23 0.01270 0.01599 248 26 1 5 0 218.560 32.50 20.00 24.89 29.64 2.3 984.77 405 618 -328 -2568 -3260 -2575 -343 278 270 -1256 -2688 -1230 -856 263 1193 210 710 909 1112 1739 633 1158 998 944 619 1022 48 -670 -1164 452 511 979 1171 -1793 -3693 -3406 -2785 -1355 -252 -196 -632 -460 -16 -324 413 -27 -202 -384 -854 -306 697 525 1141 1060 634 1063 955 364 246 114 920 1348 2000 2191 388 -273 -994 -1268 247 548 825 585 496 603 151 -609 -1494 -1871 -1673 -1849 -1558 -1505 -2267 -1565 -757 -75 214 723 1204 758 614 -64 -524 -822 -414 -90 399 1204 609 -87 -415 -1174 -1505 -281 -721 -795 -606 -346 257 783 1292 939 771 130 -424 -513 -324 -259 241 579 128 263 675 158 628 -195 -467 33 129 144 129 -201 -504 -138 148 127 374 467 364 7 -237 -669 -901 110 177 -94 -670 -815 -635 -84 77 82 -394 -817 -386 -284 92 468 89 304 378 477 770 285 507 454 456 296 502 23 -318 -515 197 239 488 599 -934 -1760 -1631 -1488 -800 -161 -136 -471 -338 -12 -243 307 -20 -153 -282 -613 -220 530 408 926 865 528 900 824 311 206 95 797 1210 1857 2071 376 -248 -877 -1093 221 520 842 596 500 606 146 -548 -1278 -1532 -1458 -1695 -1532 -1568 -2413 -1722 -864 -88 257 884 1463 912 701 -69 -552 -848 -441 -102 465 1501 779 -112 -512 -1375 -1741 -331 -880 -1014 -782 -464 347 1094 1835 1340 1076 173 -548 -645 -411 -335 325 811 178 369 922 213 826 -246 -573 41 166 193 175 -278 -707 -195 217 191 570 731 575 11 -363 -990 -1344 SS 20260524T140228.8Z 9640.585055 85 1 52.33 2 56.33 74.46 156.63 38.93 0.00 1 0.00 1 0 17 1.276e-02 9.069e-03 3.728e-03 1.922e-03 2.164163e-01 9.444504e-04 2.277068e-03 -6.000000e+00 7.019508e-03 228.45 -2.00 3.09 -2.00 316.08 0.00e+00 3.414773e-04 1.035318e-04 1.527938e-04 -6.000000e+00 3.156400e-04 286.55 -2.00 20.00 -2.00 315.32 0.00e+00 1.798 0.000 302.00 328.00 3 5.4229e+00 2.4553e-03 1.7833e-02 -6.0000e+00 1.7465e-02 2.5992e-03 2.7508e-03 9.6792e-03 -6.0000e+00 1.8988e-02 3.8663e-03 1.5877e-03 4.7270e-03 -6.0000e+00 1.1322e-02 -6.2662e-03 7.4443e-04 1.3166e-03 -6.0000e+00 4.8656e-03 4.1027e-04 3.8671e-04 4.9503e-05 1.3367e-05 -6.0000e+00 3.0950e-04 1.2222e-02 0.0000e+00 12 9 1 12 1 1 100.00 24.92 0.40 0.01222 0.01513 26 3 1 5 0 1937.930 32.50 20.00 24.92 29.59 2.3 984.38 251 2692 -977 -3564 -2476 -3686 1336 -25 -1770 -166 -3514 -147 -648 -1861 646 -592 795 76 1057 1421 1832 2462 155 -435 651 205 714 -1790 -282 462 -1324 2848 -182 -1791 -5112 -1995 -3059 -1407 -294 143 31 -612 91 14 914 -349 161 432 -260 -672 296 238 1654 998 367 1098 729 697 451 -7 580 1809 2197 2400 397 -311 -1522 -966 586 511 869 378 298 464 319 -879 -1434 -2292 -898 -2504 -2484 -1703 -2054 -1768 -238 291 58 539 999 908 615 -550 -708 -1142 -712 -328 254 1296 575 48 -639 -1315 -1516 -303 -771 -503 -949 117 261 1047 1205 1078 782 446 -397 -834 -268 -270 406 755 276 415 601 309 488 43 -1195 -383 334 -63 331 -298 -592 -520 -42 230 541 759 546 -100 -126 -894 -916 53 580 -217 -722 -479 -715 269 -5 -421 -39 -823 -35 -176 -581 223 -202 296 27 386 536 691 902 60 -180 280 91 308 -725 -114 184 -528 1167 -84 -828 -2192 -835 -1451 -779 -180 93 21 -440 67 10 659 -254 113 292 -172 -448 209 180 1292 823 289 875 594 559 354 -5 473 1581 2073 2245 366 -275 -1259 -774 507 478 873 395 308 459 312 -769 -1219 -1868 -768 -2317 -2407 -1802 -2157 -1926 -276 340 72 681 1254 1089 716 -586 -724 -1143 -764 -365 312 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