File name: Pandora94s1_GuatemalaCity_20260525_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260526T062011.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20260525_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20260525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260525T140812.6Z 9641.589035 112 1 54.29 2 55.01 74.34 166.26 24.73 0.00 1 0.00 1 0 25 1.130e-02 8.219e-03 2.912e-03 1.480e-03 2.114550e-01 7.244481e-04 2.218773e-03 -6.000000e+00 6.213974e-03 228.41 -2.00 3.09 -2.00 316.13 0.00e+00 7.110452e-04 7.992501e-05 6.385976e-05 -6.000000e+00 2.795330e-04 286.56 -2.00 20.00 -2.00 315.37 0.00e+00 1.739 0.000 302.00 328.00 3 4.9567e+00 1.8829e-03 1.7316e-02 -6.0000e+00 1.5459e-02 4.6609e-03 2.1103e-03 9.5083e-03 -6.0000e+00 1.6809e-02 6.4431e-03 1.2200e-03 4.6343e-03 -6.0000e+00 1.0023e-02 -8.8697e-03 5.7311e-04 1.3543e-03 -6.0000e+00 4.3067e-03 6.9047e-04 5.3438e-04 3.8188e-05 1.3325e-05 -6.0000e+00 2.7410e-04 1.3792e-02 0.0000e+00 11 9 0 11 8 0 100.00 24.62 0.43 0.01379 0.01781 178 19 1 5 0 304.990 32.25 20.00 24.62 25.86 2.4 969.13 -581 -105 -1320 -2538 -2499 -4458 148 711 50 260 -2303 -511 -1018 -1267 -11 -208 749 726 413 1394 1784 1544 86 1131 -172 244 511 -1222 -287 727 658 2559 2048 -1878 -3174 -2775 -3413 -1182 -699 -160 -698 -609 270 -787 588 146 -781 98 -565 -220 832 153 969 1020 267 1020 1056 772 420 -270 440 1664 2024 2042 246 -208 -1352 -1031 160 635 686 869 443 644 -178 -573 -1643 -1770 -1105 -1743 -1379 -1820 -2572 -1591 -457 -290 112 659 1064 867 813 158 -216 -750 -556 -221 350 1105 639 -46 -439 -1407 -1371 -431 -679 -735 -754 -227 63 827 1129 1007 520 157 -697 -594 -242 -459 278 580 190 450 579 69 835 -43 -840 144 533 66 -59 -178 -522 13 385 379 405 371 308 -117 -273 -777 -912 -126 -24 -301 -519 -449 -810 28 152 12 62 -539 -123 -256 -363 -3 -71 257 259 152 528 676 573 33 461 -74 108 220 -490 -106 265 257 1050 920 -865 -1327 -1166 -1620 -597 -424 -102 -476 -428 193 -566 417 104 -541 65 -367 -143 572 113 744 820 219 848 893 644 343 -222 375 1413 1854 1979 235 -177 -1159 -858 134 611 663 866 437 653 -168 -517 -1351 -1388 -918 -1542 -1357 -1846 -2757 -1757 -540 -344 140 838 1344 1046 957 170 -224 -764 -569 -249 407 1416 863 -61 -535 -1684 -1562 -519 -848 -958 -1028 -301 87 1214 1637 1460 760 212 -912 -729 -300 -598 391 822 275 638 799 97 1102 -55 -1071 184 688 92 -80 -246 -731 19 596 583 633 597 499 -186 -418 -1215 -1396 SS 20260525T151344.6Z 9641.634544 135 1 19.52 2 39.73 74.56 155.59 61.84 0.00 1 0.00 1 0 17 1.042e-02 8.565e-03 1.607e-03 1.193e-03 1.630566e-01 5.940633e-04 1.738486e-03 -6.000000e+00 5.734455e-03 228.41 -2.00 3.09 -2.00 314.53 0.00e+00 4.556459e-04 4.744862e-05 3.546411e-05 -6.000000e+00 2.579346e-04 286.56 -2.00 20.00 -2.00 313.92 0.00e+00 1.299 0.000 302.00 328.00 3 4.1442e+00 1.5184e-03 1.3077e-02 -6.0000e+00 1.4266e-02 2.2375e-02 1.6878e-03 7.3374e-03 -6.0000e+00 1.5511e-02 1.6544e-03 9.6796e-04 3.5765e-03 -6.0000e+00 9.2492e-03 -5.6255e-03 4.2870e-04 1.0127e-03 -6.0000e+00 3.9747e-03 2.4406e-03 4.1128e-04 3.0278e-05 1.1428e-05 -6.0000e+00 2.5292e-04 1.3024e-02 0.0000e+00 12 9 1 12 1 1 100.00 24.75 0.26 0.01302 0.01611 66 20 1 5 0 291.350 32.50 20.00 24.75 27.43 2.3 976.14 -160 507 -363 -2452 -2869 -2379 552 1052 536 -723 -2100 -967 -140 -353 675 165 623 1212 1199 1611 681 1078 619 994 377 1064 211 -407 -537 367 475 1371 1397 -1400 -3611 -2923 -2633 -1690 -144 -325 -744 -508 -412 -530 116 -44 -473 -267 -635 -124 749 470 1115 1137 740 855 1086 549 153 278 885 1207 1776 2339 129 -353 -1208 -1296 220 443 856 703 926 626 103 -562 -1693 -1857 -1638 -1929 -1461 -1443 -2295 -1601 -664 -211 70 622 1023 609 554 -61 -441 -976 -501 -153 521 1168 767 -33 -428 -958 -1570 -296 -794 -729 -666 -131 362 938 1299 985 788 276 -369 -607 -511 -375 294 647 249 436 538 238 601 -135 -483 -112 135 116 -169 -135 -588 -115 218 157 218 549 347 22 -335 -702 -819 -62 203 -144 -944 -967 -786 192 413 215 -296 -884 -414 -62 -175 345 89 336 667 677 878 376 614 341 575 228 657 127 -240 -291 194 264 798 822 -832 -2087 -1685 -1587 -1121 -107 -262 -635 -422 -350 -448 97 -39 -398 -216 -494 -101 606 404 944 1004 663 776 999 500 136 248 817 1143 1798 2361 128 -342 -1079 -1177 204 449 887 754 980 639 103 -523 -1503 -1555 -1443 -1835 -1464 -1510 -2533 -1743 -775 -252 84 766 1252 744 646 -67 -458 -984 -537 -172 611 1442 957 -42 -501 -1078 -1775 -338 -962 -922 -843 -172 471 1286 1781 1346 1056 353 -448 -722 -613 -453 367 868 330 591 711 299 743 -167 -558 -130 167 146 -222 -172 -756 -152 297 225 306 791 505 31 -480 -973 -1111 SS 20260525T151840.5Z 9641.637968 138 1 54.31 2 38.58 74.48 154.59 63.31 0.00 1 0.00 1 0 17 1.018e-02 8.486e-03 1.267e-04 9.928e-05 1.609876e-01 4.947314e-05 1.716150e-03 -6.000000e+00 5.603487e-03 228.41 -2.00 3.09 -2.00 314.24 0.00e+00 4.720046e-04 3.771281e-06 1.860956e-05 -6.000000e+00 2.520492e-04 286.56 -2.00 20.00 -2.00 313.66 0.00e+00 1.278 0.000 302.00 328.00 3 3.3743e-01 1.2611e-04 1.2881e-02 -6.0000e+00 1.3940e-02 -3.8092e-03 1.4013e-04 7.2503e-03 -6.0000e+00 1.5157e-02 4.1462e-04 8.0410e-05 3.5286e-03 -6.0000e+00 9.0380e-03 -4.7733e-03 3.5239e-05 1.0069e-03 -6.0000e+00 3.8839e-03 1.1334e-01 3.9648e-04 2.5124e-06 1.1619e-05 -6.0000e+00 2.4715e-04 1.3166e-02 0.0000e+00 11 9 0 11 8 0 99.84 24.76 0.30 0.01317 0.01614 3325 349 1 5 0 16.330 32.25 20.01 24.76 27.85 2.4 979.37 87 756 -183 -2451 -2626 -1609 30 566 920 -977 -2123 -1138 -634 170 1087 234 589 831 1251 1643 665 907 1125 965 518 1011 190 -438 -928 675 729 971 1323 -1631 -3388 -3256 -2510 -1396 -332 -276 -692 -494 -180 -418 255 -107 -339 -429 -908 -247 762 592 1082 1114 782 1061 870 487 333 267 965 1298 1757 2012 341 -356 -1068 -1277 255 541 748 619 512 692 137 -562 -1487 -1835 -1644 -1813 -1522 -1428 -2265 -1602 -724 -213 178 677 1085 721 605 -86 -625 -730 -373 -198 372 1236 705 25 -316 -1078 -1525 -244 -748 -739 -624 -393 225 790 1296 987 796 272 -365 -520 -402 -282 218 531 165 336 609 221 677 -24 -342 65 220 136 21 -201 -535 -201 193 105 294 458 317 8 -187 -743 -928 39 337 -81 -1028 -1013 -639 12 243 412 -448 -974 -532 -315 90 605 133 333 481 739 960 393 543 663 599 323 645 119 -260 -531 390 425 572 837 -1043 -2051 -1978 -1625 -977 -249 -229 -590 -418 -156 -359 217 -91 -285 -358 -731 -197 637 509 936 1005 695 955 796 441 304 244 886 1246 1757 2051 339 -333 -977 -1130 236 542 783 652 534 714 135 -524 -1331 -1602 -1463 -1724 -1514 -1512 -2465 -1753 -829 -248 212 827 1319 859 692 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