File name: Pandora94s1_GuatemalaCity_20260708_L2Fit_fout2c4d20250225p1-8.txt
File generation date: 20260709T063353.4Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Daniel Alvarez
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 94
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora94_OF_v3d20240409.txt
Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt
Level 1 file used: Pandora94s1_GuatemalaCity_20260708_L1_smca1c4d20250225p1-8.txt
Full location name: Ciudad de Guatemala
Short location name: GuatemalaCity
Country of location: Guatemala
Location latitude [deg]: 14.6192
Location longitude [deg]: -90.4838
Location altitude [m]: 1547
Local noon date: 20260708
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 201 343
Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20260708T124244.0Z 9685.529676 242 1 11.81 2 76.42 69.96 4.66 260.06 0.00 1 0.00 1 0 17 6.694e-02 8.561e-03 3.300e-02 2.778e-03 4.730328e-01 1.359146e-03 4.869905e-03 -6.000000e+00 3.659878e-02 226.93 -2.00 3.09 -2.00 318.95 0.00e+00 1.286884e-03 3.267571e-04 6.748731e-04 -6.000000e+00 1.655816e-03 286.45 -2.00 20.00 -2.00 318.17 0.00e+00 4.160 0.000 302.00 328.00 3 2.4969e+00 3.7659e-03 4.0585e-02 -6.0000e+00 9.0735e-02 -1.1888e-02 4.3864e-03 2.1482e-02 -6.0000e+00 9.8796e-02 4.2555e-03 3.2786e-03 1.0731e-02 -6.0000e+00 5.8978e-02 -5.6470e-03 1.7508e-03 3.2409e-03 -6.0000e+00 2.5400e-02 7.9937e-04 3.9543e-04 7.0521e-05 2.9039e-05 -6.0000e+00 1.6241e-03 1.9424e-02 0.0000e+00 12 9 1 12 1 1 99.99 24.33 0.35 0.01942 0.02240 19 10 1 5 0 590.490 32.00 19.99 24.33 23.34 2.5 958.34 -12341 -10292 -26449 -34839 6864 -26637 -6884 -28833 -33439 -7492 -11378 -11512 3371 -12253 -6848 -11602 -3404 5265 5575 -3558 -828 -2828 -7233 -990 -6741 -1385 -489 -4087 -5682 -565 -4307 1430 -1930 -2324 -9389 -3269 -4749 1626 1568 1315 467 -437 3085 1034 1215 1287 24 246 700 -485 947 1043 2214 733 7 626 1255 484 -349 -556 -13 1574 3199 3321 802 -370 -391 -1511 462 886 565 559 238 504 -36 -361 -2336 -1905 -2122 -1461 -1489 -1221 -1873 -1354 -265 -124 261 634 1329 1313 960 -280 -635 -1197 -741 -180 355 1136 803 -521 -912 -1535 -1711 -201 -682 -950 -1057 -419 111 1043 1150 1227 571 -69 -32 -521 -467 -372 35 395 370 396 896 239 447 -202 -652 -8 307 445 32 -350 -954 -356 76 137 573 809 349 -62 -279 -557 -828 -274 -248 -774 -1010 119 -664 -159 -961 -1314 -238 -379 -440 138 -720 -462 -930 -271 418 468 -345 -79 -273 -784 -110 -855 -175 -61 -494 -677 -69 -581 209 -332 -405 -1609 -541 -911 355 388 383 149 -149 1057 365 432 465 9 91 264 -180 385 466 1054 354 4 326 665 255 -180 -285 -7 923 1935 2208 546 -237 -242 -963 326 678 442 450 188 399 -26 -248 -1528 -1247 -1464 -1179 -1295 -1126 -1855 -1326 -277 -131 290 718 1483 1393 990 -270 -609 -1182 -774 -202 429 1478 1066 -679 -1149 -1825 -1996 -233 -872 -1213 -1422 -566 155 1591 1821 1914 905 -104 -46 -751 -656 -551 53 630 586 604 1376 355 660 -287 -882 -12 465 710 54 -601 -1640 -643 141 257 1091 1573 681 -116 -516 -1012 -1472
SS 20260708T134758.3Z 9685.574981 278 1 54.84 2 61.49 72.12 20.11 270.90 0.00 1 0.00 1 0 17 2.927e-02 1.170e-02 1.037e-02 3.637e-03 2.537684e-01 1.769110e-03 2.651504e-03 -6.000000e+00 1.600740e-02 226.93 -2.00 3.09 -2.00 317.00 0.00e+00 8.401791e-04 2.417708e-04 2.244123e-04 -6.000000e+00 7.241345e-04 286.45 -2.00 20.00 -2.00 316.21 0.00e+00 2.085 0.000 302.00 328.00 3 6.1645e+00 4.6456e-03 2.0685e-02 -6.0000e+00 3.9685e-02 5.2761e-02 5.2414e-03 1.1296e-02 -6.0000e+00 4.3209e-02 1.2126e-02 3.1157e-03 5.5565e-03 -6.0000e+00 2.5795e-02 -1.4066e-02 1.5440e-03 1.6109e-03 -6.0000e+00 1.1110e-02 1.4124e-04 3.5818e-04 9.4926e-05 1.4714e-05 -6.0000e+00 7.1023e-04 1.8551e-02 0.0000e+00 12 8 8 10 0 0 99.99 24.44 1.04 0.01855 0.02124 21 2 1 5 0 2611.280 32.25 20.01 24.44 25.08 2.5 966.46 -2491 12801 -12209 -5344 5766 -3333 9313 -9588 -4773 8813 -1628 -7157 309 -3183 567 -891 -2426 2888 3071 722 -230 6990 1295 4710 -795 1356 2068 -2244 -3403 862 -4997 6004 -1358 -2093 -6426 -2799 -7286 -1223 -562 113 -1794 18 714 763 -308 878 753 1550 452 -2143 120 756 1891 823 109 -474 875 1625 252 -149 211 2720 2503 3163 1427 -559 -1613 -2302 -79 -158 226 1291 760 688 -504 -563 -3058 -1226 131 -2519 -1797 -1356 -2436 -1803 -276 627 530 797 768 545 1770 -1677 -869 -1925 -1377 28 688 865 581 -383 -359 -2377 -1777 -474 217 -283 -1361 130 444 1408 606 1346 1531 -49 -1122 -621 -43 -646 594 624 182 663 573 -294 604 -104 -1209 -504 -101 -133 -574 176 -586 87 224 -94 1034 836 659 573 -331 -1067 -1402 -328 1535 -1875 -681 581 -368 994 -1411 -738 1207 -238 -1178 55 -671 131 -225 -639 753 828 207 -67 1850 378 1412 -264 456 671 -699 -1002 246 -1645 1915 -511 -782 -2257 -961 -2678 -504 -278 64 -1100 11 453 483 -197 554 462 920 265 -1306 77 515 1342 569 77 -345 638 1156 177 -105 155 2119 2126 2836 1260 -451 -1225 -1726 -64 -147 226 1317 766 663 -452 -447 -2460 -931 106 -2189 -1735 -1436 -2529 -1937 -316 760 677 1040 997 674 1976 -1756 -887 -1956 -1508 31 841 1090 771 -493 -459 -2821 -1991 -560 280 -382 -1803 177 633 2131 909 2148 2315 -69 -1458 -815 -57 -903 823 925 274 970 817 -403 838 -138 -1521 -642 -140 -183 -831 257 -872 134 370 -152 1685 1399 1109 935 -524 -1747 -2250
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