File name: Pandora94s1_GuatemalaCity_20260723_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20260724T062802.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Daniel Alvarez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 94 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora94_OF_v3d20240409.txt Instrument calibration file used: Pandora94s1_CF_v4d20250225.txt Level 1 file used: Pandora94s1_GuatemalaCity_20260723_L1_smca1c4d20250225p1-8.txt Full location name: Ciudad de Guatemala Short location name: GuatemalaCity Country of location: Guatemala Location latitude [deg]: 14.6192 Location longitude [deg]: -90.4838 Location altitude [m]: 1547 Local noon date: 20260723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0974 305.2379 305.3785 305.5190 305.6596 305.8001 305.9406 306.0812 306.2217 306.3621 306.5026 306.6431 306.7836 306.9240 307.0644 307.2049 307.3453 307.4857 307.6261 307.7665 307.9068 308.0472 308.1875 308.3279 308.4682 308.6085 308.7488 308.8891 309.0294 309.1697 309.3099 309.4502 309.5904 309.7307 309.8709 310.0111 310.1513 310.2915 310.4316 310.5718 310.7120 310.8521 310.9922 311.1323 311.2725 311.4126 311.5526 311.6927 311.8328 311.9728 312.1129 312.2529 312.3929 312.5329 312.6729 312.8129 312.9529 313.0929 313.2328 313.3728 313.5127 313.6526 313.7925 313.9324 314.0723 314.2122 314.3521 314.4919 314.6318 314.7716 314.9114 315.0512 315.1910 315.3308 315.4706 315.6104 315.7501 315.8898 316.0296 316.1693 316.3090 316.4487 316.5884 316.7281 316.8677 317.0074 317.1470 317.2867 317.4263 317.5659 317.7055 317.8451 317.9847 318.1242 318.2638 318.4033 318.5429 318.6824 318.8219 318.9614 319.1009 319.2403 319.3798 319.5193 319.6587 319.7981 319.9375 320.0769 320.2163 320.3557 320.4951 320.6345 320.7738 320.9131 321.0525 321.1918 321.3311 321.4704 321.6097 321.7489 321.8882 322.0274 322.1667 322.3059 322.4451 322.5843 322.7235 322.8627 323.0019 323.1410 323.2802 323.4193 323.5584 323.6975 323.8366 323.9757 324.1148 324.2539 324.3929 324.5320 324.6710 324.8100 324.9490 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260723T132557.0Z 9700.559687 99 1 53.14 2 67.18 74.12 170.76 169.17 0.00 1 0.00 1 0 17 3.674e-02 1.000e-02 1.241e-02 2.937e-03 3.079858e-01 1.424911e-03 3.220189e-03 -6.000000e+00 2.006980e-02 226.66 -2.00 3.09 -2.00 317.72 0.00e+00 4.620923e-04 2.369250e-04 3.327384e-04 -6.000000e+00 9.083983e-04 286.33 -2.00 20.00 -2.00 316.92 0.00e+00 2.559 0.000 302.00 328.00 3 5.3927e+00 3.7947e-03 2.5342e-02 -6.0000e+00 4.9727e-02 1.5869e-02 4.3119e-03 1.3843e-02 -6.0000e+00 5.4155e-02 2.3884e-02 2.7028e-03 6.7976e-03 -6.0000e+00 3.2334e-02 -1.5156e-02 1.3957e-03 1.9135e-03 -6.0000e+00 1.3933e-02 1.9347e-04 6.1257e-04 7.6414e-05 1.7735e-05 -6.0000e+00 8.9134e-04 1.8615e-02 0.0000e+00 12 9 8 11 8 0 100.00 24.31 0.56 0.01862 0.02322 22 2 1 5 0 2415.050 32.00 20.00 24.31 24.27 2.5 961.93 -4451 23530 -2113 -15385 -10586 -4677 1375 -4454 -8584 18127 4852 -2250 633 -3838 -4331 621 -1319 922 4379 500 -1137 2377 -986 4874 -1085 323 -51 -1020 -3610 1562 -3127 9154 -1182 -4545 -7261 909 -7218 -232 -922 -209 -754 202 633 -602 224 1354 328 1135 -395 207 -182 993 1151 928 832 -1236 546 1469 -406 -241 -67 2130 2083 3356 788 -1098 -1475 -1901 797 20 622 1574 6 510 799 -239 -2578 -2000 -476 -2234 -1024 -1774 -2674 -1424 4 -4 473 617 969 764 1657 -587 -1036 -1099 -335 -187 674 1239 706 -111 -801 -1263 -1558 -704 -541 -1358 -594 -424 420 1335 1360 1189 889 136 -444 -1100 183 -595 101 748 156 322 234 -54 883 103 -1400 -222 -4 -101 61 -406 -882 -33 92 305 483 555 332 253 -102 -801 -723 -357 1530 -179 -1326 -776 -327 100 -397 -885 1464 436 -236 76 -562 -738 110 -246 178 850 105 -245 487 -220 1101 -250 84 -13 -242 -829 351 -813 2310 -333 -1313 -1949 252 -2237 -80 -392 -102 -363 100 322 -310 114 686 164 606 -211 103 -99 576 707 603 555 -863 382 1001 -275 -162 -47 1604 1589 2708 635 -815 -1121 -1439 604 18 586 1513 5 464 663 -193 -1941 -1456 -372 -1890 -963 -1729 -2771 -1522 5 -5 564 750 1168 876 1849 -609 -1065 -1126 -346 -216 804 1641 927 -151 -1012 -1554 -1820 -871 -685 -1805 -820 -573 597 2029 2062 1817 1381 198 -630 -1485 248 -852 146 1140 241 483 342 -75 1239 139 -1799 -290 -6 -146 93 -632 -1406 -51 153 532 855 1006 604 444 -173 -1302 -1148 SS 20260723T134138.3Z 9700.570582 106 1 41.78 2 63.53 74.65 169.46 150.63 0.00 1 0.00 1 0 17 1.211e-02 8.006e-03 1.485e-03 6.588e-04 2.691090e-01 3.212911e-04 2.833313e-03 -6.000000e+00 6.617202e-03 226.66 -2.00 3.09 -2.00 316.47 0.00e+00 6.347417e-04 3.855281e-05 1.120465e-04 -6.000000e+00 2.995194e-04 286.33 -2.00 20.00 -2.00 315.70 0.00e+00 2.231 0.000 302.00 328.00 3 2.7818e+00 8.3607e-04 2.2078e-02 -6.0000e+00 1.6395e-02 -4.6908e-03 9.4143e-04 1.2011e-02 -6.0000e+00 1.7856e-02 9.6194e-03 5.4908e-04 5.9030e-03 -6.0000e+00 1.0661e-02 -7.6263e-03 2.6365e-04 1.6995e-03 -6.0000e+00 4.5938e-03 3.7064e-03 5.1752e-04 1.6934e-05 1.6829e-05 -6.0000e+00 2.9390e-04 1.8922e-02 0.0000e+00 12 9 1 12 1 1 100.00 24.36 0.26 0.01892 0.02281 332 45 1 5 0 125.450 32.25 20.00 24.36 24.67 2.5 963.68 -773 253 -1218 -4140 -3632 -3570 -1664 -1158 -404 -1726 -3590 -2418 -732 6 1337 283 365 1014 1471 1554 887 877 597 1141 484 917 144 -614 -1548 231 218 1334 1229 -2059 -3547 -3710 -2794 -1318 -161 -74 -630 -264 8 -221 735 232 -301 -178 -505 -107 842 583 1164 1014 697 1062 972 324 172 111 985 1418 1891 2328 318 -330 -1159 -1046 340 508 719 505 487 492 -21 -607 -1836 -1885 -1577 -1721 -1449 -1490 -2214 -1580 -785 -146 229 668 1095 676 665 -119 -637 -752 -333 -107 425 1136 635 -63 -521 -1269 -1612 -241 -897 -842 -571 -296 323 961 1326 945 725 184 -478 -547 -425 -239 244 445 41 324 619 224 603 -156 -349 129 282 259 8 -207 -530 -187 158 25 243 517 374 56 -251 -733 -807 -130 45 -219 -682 -528 -521 -263 -208 -80 -350 -717 -512 -162 2 385 89 118 314 471 517 298 289 207 419 189 368 57 -224 -535 80 82 541 509 -871 -1478 -1575 -1232 -638 -93 -46 -398 -172 5 -148 488 155 -196 -113 -337 -68 573 427 845 776 546 849 792 261 136 88 804 1192 1640 2143 290 -286 -947 -841 299 489 707 513 487 470 -20 -527 -1550 -1538 -1314 -1567 -1406 -1524 -2400 -1699 -905 -172 282 807 1311 806 756 -129 -665 -778 -356 -121 513 1457 827 -83 -635 -1474 -1862 -281 -1113 -1089 -741 -401 441 1400 1961 1405 1067 261 -645 -698 -549 -325 343 643 61 462 858 309 818 -204 -445 167 383 363 11 -300 -783 -277 241 40 397 833 607 92 -393 -1147 -1237 SS 20260723T135633.5Z 9700.580943 118 1 6.17 2 60.05 75.09 167.42 137.96 0.00 1 0.00 1 0 17 1.149e-02 8.290e-03 1.194e-03 7.105e-04 2.432838e-01 3.483515e-04 2.583728e-03 -6.000000e+00 6.279021e-03 226.66 -2.00 3.09 -2.00 315.63 0.00e+00 5.319941e-04 3.469137e-05 6.895396e-05 -6.000000e+00 2.842040e-04 286.33 -2.00 20.00 -2.00 314.92 0.00e+00 1.994 0.000 302.00 328.00 3 1.3305e+00 8.9591e-04 1.9808e-02 -6.0000e+00 1.5558e-02 -4.3992e-03 1.0040e-03 1.0856e-02 -6.0000e+00 1.6943e-02 6.7406e-03 5.7698e-04 5.3280e-03 -6.0000e+00 1.0116e-02 -6.3464e-03 2.6558e-04 1.5183e-03 -6.0000e+00 4.3591e-03 2.0031e-02 5.1055e-04 1.8139e-05 1.5974e-05 -6.0000e+00 2.7887e-04 1.8702e-02 0.0000e+00 12 9 1 12 1 1 99.95 24.42 0.30 0.01870 0.02254 88 82 1 5 0 69.280 32.25 20.00 24.42 25.14 2.5 965.92 226 903 -749 -3139 -3880 -2758 -1191 168 283 -1673 -2936 -1433 -784 315 1273 319 680 1033 1555 1484 984 555 1113 946 613 1005 106 -584 -1227 535 609 1197 1363 -1957 -3962 -3581 -2864 -1206 -254 -262 -644 -383 -16 72 579 174 -116 -339 -732 -208 919 712 1108 1062 780 942 848 490 210 295 1107 1421 1871 2133 327 -320 -1141 -1251 429 552 741 660 486 656 -22 -793 -1705 -1864 -1580 -1780 -1440 -1503 -2230 -1590 -704 -168 48 732 1071 591 531 -257 -695 -641 -273 -263 487 1227 665 -70 -534 -1210 -1586 -304 -806 -808 -566 -231 360 878 1342 893 744 171 -323 -417 -372 -270 169 412 139 320 678 196 726 -15 -254 88 274 252 47 -194 -578 -261 160 96 321 416 300 -18 -226 -738 -861 58 242 -203 -825 -909 -639 -299 44 82 -502 -857 -438 -257 110 502 129 279 440 647 642 429 238 494 448 291 490 50 -271 -535 232 286 572 711 -990 -1931 -1766 -1506 -709 -164 -179 -471 -278 -12 53 426 128 -83 -247 -522 -149 676 541 882 859 644 793 727 414 174 244 949 1237 1709 2000 311 -283 -978 -1091 381 529 740 681 495 656 -21 -722 -1468 -1544 -1358 -1698 -1440 -1561 -2383 -1761 -813 -196 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