File name: Pandora156s1_HamptonVA-HU_20220306_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T142845.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220306_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220306T132714.0Z 8100.560579 102 1 10.24 2 68.24 115.54 93.55 74.49 0.00 1 0.00 1 0 17 6.893e-02 8.495e-03 3.494e-02 4.717e-03 3.312909e-01 2.387083e-03 3.772365e-03 -6.000000e+00 3.987974e-02 226.15 -2.00 3.43 -2.00 318.87 0.00e+00 5.519768e-04 5.279141e-04 1.784384e-04 -6.000000e+00 1.751292e-03 279.53 -2.00 20.00 -2.00 318.18 0.00e+00 2.674 0.000 302.00 328.00 3 3.3908e+00 6.5396e-03 3.1312e-02 -6.0000e+00 9.8729e-02 3.4381e-02 7.5151e-03 1.6630e-02 -6.0000e+00 1.0747e-01 -1.0162e-02 5.1709e-03 8.1435e-03 -6.0000e+00 6.4025e-02 -1.5016e-03 2.6750e-03 2.4248e-03 -6.0000e+00 2.6735e-02 8.3090e-04 5.2696e-04 1.4699e-04 2.8224e-05 -6.0000e+00 1.9874e-03 2.9772e-03 1.7312e-04 12 9 1 12 1 1 99.99 23.37 0.16 0.00298 0.00694 12 16 1 5 0 774.110 26.32 20.00 23.37 22.13 5.2 1088.74 45090 -10513 -10078 19140 -46048 -26645 -8721 -4043 4684 1647 -2628 5070 6344 -3037 386 5541 -11330 13764 -2184 5394 968 4670 -3298 6547 2032 2235 -9840 1576 1202 1609 -9128 -4800 4400 1549 -1744 -3109 -3926 1153 315 -1079 2586 -5150 82 19 -1412 -171 1255 -2309 1464 917 1527 2619 -588 2012 1981 553 -1754 228 598 1279 863 1800 828 2518 505 106 -985 -2191 1046 1548 617 992 1572 -95 443 1256 -961 2089 -1066 972 266 -1891 -3045 -1464 -1531 -1384 -173 -515 -644 772 218 1053 366 -769 1557 425 786 431 606 -497 171 -1097 -175 -468 -227 -329 -157 -1508 -668 293 -141 -146 -35 -183 413 234 126 562 -526 60 283 -363 18 203 288 549 583 819 896 947 282 387 222 -767 -55 245 -113 128 156 -130 155 -562 -397 -519 1162 -529 -525 716 -3008 -1365 -391 -193 230 89 -151 280 389 -239 34 525 -1366 1359 -266 634 122 569 -443 841 291 335 -1678 231 167 219 -1464 -813 745 284 -322 -564 -760 244 81 -331 856 -1965 31 7 -552 -66 476 -895 542 345 599 1094 -272 962 991 289 -959 123 316 663 457 1002 507 1641 347 71 -620 -1349 646 1057 472 755 1209 -77 338 867 -613 1213 -647 638 200 -1622 -2702 -1357 -1506 -1456 -191 -595 -755 877 235 1040 357 -720 1459 411 847 520 795 -678 223 -1347 -198 -519 -264 -411 -205 -2105 -974 425 -219 -237 -57 -286 634 335 174 785 -783 95 437 -568 28 318 432 783 793 1081 1223 1392 449 645 360 -1296 -97 455 -220 254 315 -262 302 -1059 -721 -936 SS 20220306T133633.3Z 8100.567052 105 1 46.86 2 66.57 117.29 91.78 75.84 0.00 1 0.00 1 0 17 1.544e-02 4.600e-03 4.043e-03 6.235e-04 3.107056e-01 3.156627e-04 3.574410e-03 -6.000000e+00 8.926177e-03 226.15 -2.00 3.43 -2.00 318.78 0.00e+00 1.577059e-04 6.769825e-05 1.045636e-04 -6.000000e+00 3.920414e-04 279.53 -2.00 20.00 -2.00 318.08 0.00e+00 2.496 0.000 302.00 328.00 3 8.4752e-01 8.6313e-04 2.9291e-02 -6.0000e+00 2.2099e-02 1.4802e-02 9.8916e-04 1.5582e-02 -6.0000e+00 2.4062e-02 -2.0688e-03 6.6883e-04 7.6852e-03 -6.0000e+00 1.4333e-02 -6.1171e-03 3.4409e-04 2.1720e-03 -6.0000e+00 5.9810e-03 1.3058e-02 -3.7485e-04 1.9470e-05 2.5067e-05 -6.0000e+00 4.4526e-04 3.9674e-03 1.6101e-05 10 0 0 10 0 0 97.64 23.37 0.26 0.00397 0.00115 685 184 1 5 0 68.400 26.32 20.00 23.37 22.51 5.2 1093.48 -3998 -2242 -4727 -8426 -6248 -6529 -1942 -3053 -3377 -2433 -3986 -3664 -2018 -1663 -634 -1007 -1554 -1055 -948 -873 -890 -161 141 -458 -332 -61 -609 -1104 -1304 -211 -44 1637 1206 51 -1775 -2182 -1852 -900 -122 126 -357 -295 -876 -830 -922 -563 -366 -678 -458 -400 340 826 1106 1314 995 517 1143 601 392 477 877 1277 1852 1202 1037 423 -525 -95 49 1121 612 228 128 203 -2 272 7 47 28 161 -326 -852 -1195 -1456 -1232 -1197 -414 -316 -97 -11 319 244 328 347 568 718 702 629 72 34 -204 -404 -504 -209 -517 -282 -680 -635 -497 -231 -69 -7 -75 -108 -26 -16 367 123 294 89 -57 -160 -196 205 408 597 716 760 678 511 276 322 -93 14 -171 -58 -119 191 -96 -193 -103 -118 -316 -398 -175 -108 -241 -428 -282 -309 -92 -164 -204 -155 -262 -248 -150 -144 -63 -112 -185 -131 -124 -118 -124 -22 20 -68 -53 -10 -102 -179 -200 -31 -7 275 222 10 -343 -411 -368 -204 -33 40 -127 -112 -347 -335 -373 -227 -146 -267 -178 -156 138 359 513 644 511 275 617 328 211 253 472 726 1139 802 715 282 -329 -57 31 765 467 186 106 165 -1 190 5 28 17 105 -243 -713 -1092 -1416 -1267 -1318 -481 -348 -108 -12 362 256 315 316 525 721 786 784 90 43 -251 -510 -591 -240 -627 -366 -931 -830 -682 -337 -107 -12 -121 -166 -38 -24 517 176 445 131 -87 -247 -298 332 631 876 1002 1034 951 772 447 549 -149 24 -296 -106 -227 373 -191 -384 -199 -218 -567 -709 SS 20220306T135121.2Z 8100.577328 116 1 46.91 2 63.98 120.17 88.96 77.96 0.00 1 0.00 1 0 17 1.277e-02 4.648e-03 3.337e-03 6.153e-04 2.811933e-01 3.085241e-04 3.274512e-03 -6.000000e+00 7.381701e-03 226.15 -2.00 3.43 -2.00 318.51 0.00e+00 2.712367e-04 6.111974e-05 8.193377e-05 -6.000000e+00 3.242003e-04 279.53 -2.00 20.00 -2.00 317.80 0.00e+00 2.266 0.000 302.00 328.00 3 1.0243e+00 8.3407e-04 2.6590e-02 -6.0000e+00 1.8275e-02 1.0554e-02 9.5271e-04 1.4166e-02 -6.0000e+00 1.9897e-02 2.1637e-04 6.2195e-04 6.9454e-03 -6.0000e+00 1.1852e-02 -6.5272e-03 3.1805e-04 1.9402e-03 -6.0000e+00 4.9469e-03 1.4311e-02 -1.3721e-04 1.9282e-05 2.3835e-05 -6.0000e+00 3.6812e-04 3.4311e-03 5.4857e-05 10 0 0 10 0 0 99.78 23.37 0.27 0.00343 0.00240 831 224 1 5 0 56.310 26.32 19.99 23.37 23.88 5.3 1100.00 -1413 -3501 -3987 -5803 -4978 -5358 -1807 -2417 -902 -3419 -2910 -4209 -1718 -979 -615 138 -661 -622 -588 -114 -968 -337 -44 775 164 342 -713 -1075 -656 -367 29 1639 938 225 -1267 -2185 -1122 -736 -182 143 -264 -834 -1042 -941 -754 -509 -547 -631 -362 -457 471 841 1289 1161 829 524 1226 591 481 573 1030 1083 1714 1037 957 299 -421 10 -74 963 486 336 114 355 -45 359 76 166 42 230 -419 -870 -1322 -1570 -1260 -1144 -392 -202 -78 -35 141 202 416 345 524 638 772 645 139 -51 -293 -474 -472 -266 -401 -286 -744 -581 -416 -167 -48 34 62 -46 -60 -45 246 141 279 150 -14 -155 -252 248 486 622 732 813 686 561 301 365 -89 48 -120 -75 -117 136 -112 -110 -165 -118 -318 -375 -79 -222 -263 -372 -287 -294 -100 -150 -61 -254 -217 -359 -159 -94 -68 17 -86 -84 -91 -18 -161 -56 -7 135 30 66 -140 -204 -116 -63 5 313 196 49 -274 -461 -248 -186 -55 50 -104 -351 -456 -418 -335 -225 -240 -272 -153 -193 205 391 637 607 453 294 699 341 274 322 586 651 1112 728 691 208 -274 6 -47 675 380 280 97 294 -35 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