File name: Pandora156s1_HamptonVA-HU_20220417_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T145506.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220417_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220417T114047.0Z 8142.486656 243 1 47.28 2 76.55 86.80 98.12 259.77 0.00 1 0.00 1 0 25 6.319e-01 7.567e-02 4.563e-01 6.194e-02 5.927795e-01 3.589654e-02 6.790078e-03 -6.000000e+00 3.863188e-01 229.18 -2.00 3.43 -2.00 320.98 0.00e+00 1.934011e-02 1.526871e-02 3.431776e-03 -6.000000e+00 2.427741e-02 283.11 -2.00 20.00 -2.00 320.38 0.00e+00 4.195 0.001 302.00 328.00 3 5.1406e+00 1.1673e-01 6.2808e-02 -6.0000e+00 9.6094e-01 6.0168e-01 1.3673e-01 6.3470e-02 -6.0000e+00 1.0530e+00 -7.7695e-01 8.7891e-02 1.5813e-02 -6.0000e+00 6.2211e-01 3.6768e-01 4.3765e-02 2.2863e-02 -6.0000e+00 2.6030e-01 1.8917e-05 -3.5738e-03 1.9883e-03 2.3308e-04 -6.0000e+00 2.0390e-02 -3.7747e-05 -5.3088e-06 12 8 8 10 0 0 88.40 23.50 3.07 -0.00004 -0.02689 22 6 1 5 0 2148.410 26.32 20.00 23.50 18.65 5.9 1001.08 -122370 900000 -127561 900000 900000 900000 -21304 900000 -86233 -30815 900000 900000 218264 244460 900000 -50126 900000 900000 131271 900000 900000 97250 298836 5016 900000 900000 900000 900000 118668 900000 900000 900000 66022 66142 -39782 900000 70590 900000 140048 96607 29403 -7840 139419 53280 55633 -21896 181868 92164 900000 83536 900000 36945 59588 13976 3362 -8335 62963 115671 52688 38772 57407 81606 6363 72472 50837 -310 33 16727 8288 32746 10434 18209 -9755 3305 -3533 -2006 -31119 12551 -14347 -20362 -1955 -17440 11057 -5350 67569 1469 -16777 -15965 -2587 -5298 6001 9945 -2201 7930 -2831 -7737 -1599 -4682 4210 -2543 12045 -2985 8036 17193 -949 -6688 -3972 -2545 320 -5583 -977 2309 12067 -3348 -1230 -10015 -255 1225 -6071 2531 1685 3293 1222 4769 -1123 8061 -4586 6958 2482 1079 5776 -221 2079 1989 -2087 3504 -916 -548 1933 -3337 -2881 -3509 8940 -4939 -13166 900000 -17761 900000 900000 900000 -1281 900000 -5185 -1853 900000 900000 13123 14698 900000 -4856 900000 900000 7893 900000 900000 5847 17968 319 900000 900000 900000 900000 7135 900000 900000 900000 3970 3977 -5581 900000 4244 900000 8420 5809 3120 -1276 8383 5088 5313 -4646 10935 6519 900000 6795 900000 5488 7587 2966 821 -2299 8462 9000 7454 6171 7715 9236 1710 11278 10608 -109 11 4674 2609 8918 3949 6762 -4830 1379 -1462 -738 -13868 3462 -5429 -9362 -878 -10486 5553 -3387 21747 972 -14063 -13834 -1994 -4141 3990 5909 -1378 4347 -1812 -5856 -1318 -4587 4244 -2905 11673 -3114 6793 12466 -843 -6694 -4088 -2736 359 -7286 -1348 3340 16389 -5234 -1796 -15089 -338 1620 -9062 3661 2533 4822 1763 6393 -1532 10208 -6324 8367 3274 1602 9072 -398 3632 3856 -4177 7001 -1988 -1282 4184 -7518 -6572 -7568 16024 -9874 SS 20220417T115130.4Z 8142.494102 246 1 19.01 2 74.41 88.39 100.18 261.24 0.00 1 0.00 1 0 17 2.395e-01 7.358e-03 2.155e-01 4.561e-03 5.410439e-01 2.424193e-03 5.965151e-03 -6.000000e+00 1.400907e-01 229.18 -2.00 3.43 -2.00 320.69 0.00e+00 1.335651e-03 9.951707e-04 3.710610e-04 -6.000000e+00 6.174335e-03 283.11 -2.00 20.00 -2.00 320.06 0.00e+00 3.654 0.001 302.00 328.00 3 2.1903e+00 7.6515e-03 4.6103e-02 -6.0000e+00 3.4889e-01 3.8995e-02 9.8126e-03 2.8267e-02 -6.0000e+00 3.7877e-01 -1.5820e-02 9.0948e-03 1.4009e-02 -6.0000e+00 2.2557e-01 -4.1181e-03 4.4814e-03 4.3851e-03 -6.0000e+00 9.3887e-02 8.0112e-04 -7.8122e-04 1.4006e-04 5.3084e-05 -6.0000e+00 6.9140e-03 2.3109e-03 8.4458e-06 12 9 1 12 1 1 99.96 23.49 0.24 0.00231 -0.00356 48 33 1 5 0 384.280 26.32 20.00 23.49 19.12 5.8 1004.43 89315 -110602 8955 -48793 145712 102459 -6300 -77265 616 -43287 -17969 -44924 -40750 -45009 -41345 -23042 -24900 23298 -16882 32510 -25145 23517 -18621 -1346 -20756 -1120 3064 32049 23009 -23449 11544 -15028 1769 -3508 3631 -12386 -3095 -12825 -1265 -2826 -1711 -4067 1433 -1580 2868 -2934 -1833 1897 -6431 21148 -2047 8437 -874 4061 408 2250 2527 151 2291 -2666 1268 1435 1250 957 3656 1003 1785 -3556 1447 -1054 3395 -1577 1209 2758 -791 243 187 -1620 -1574 1327 -1308 -954 -2056 -646 -1690 -85 -180 770 60 -413 -182 726 608 464 341 1083 1325 -186 282 -480 351 -528 -486 -778 -682 -426 -921 -948 -650 444 145 408 -387 -390 -201 461 159 339 178 94 -195 -30 127 344 206 234 176 602 477 160 279 292 438 -350 93 -1040 251 85 -134 426 -238 241 -377 -237 397 -1706 45 -434 648 456 -35 -1008 4 -501 -171 -613 -641 -921 -1006 -554 -687 435 -511 636 -910 530 -663 -44 -886 -42 113 865 662 -1106 431 -856 98 -222 212 -834 -203 -1080 -116 -315 -216 -570 201 -235 414 -456 -286 290 -1097 2866 -379 1556 -194 930 103 584 676 42 611 -734 340 411 399 341 1352 379 646 -1353 555 -467 1613 -841 637 1386 -384 106 74 -631 -643 598 -703 -584 -1410 -468 -1315 -69 -156 690 55 -372 -155 570 447 334 258 912 1271 -206 343 -613 432 -605 -508 -785 -714 -476 -1088 -1185 -865 638 214 645 -631 -621 -323 694 233 505 279 156 -334 -50 207 542 312 339 246 822 688 255 490 551 811 -684 191 -2297 571 197 -317 990 -535 513 -769 -478 SS 20220417T120129.8Z 8142.501040 249 1 47.28 2 72.41 89.89 102.10 262.61 0.00 1 0.00 1 0 25 1.080e-01 5.054e-03 8.995e-02 3.359e-03 4.867470e-01 1.778832e-03 5.421357e-03 -6.000000e+00 6.315167e-02 229.18 -2.00 3.43 -2.00 320.44 0.00e+00 5.270631e-04 6.557379e-04 6.587133e-04 -6.000000e+00 2.783229e-03 283.11 -2.00 20.00 -2.00 319.77 0.00e+00 3.263 0.001 302.00 328.00 3 2.2826e+00 5.4448e-03 4.1331e-02 -6.0000e+00 1.5727e-01 2.9270e-02 6.7380e-03 2.5552e-02 -6.0000e+00 1.7074e-01 -2.9534e-03 5.8742e-03 1.2398e-02 -6.0000e+00 1.0168e-01 -8.8439e-03 2.9520e-03 3.6257e-03 -6.0000e+00 4.2329e-02 1.1332e-03 -7.3862e-04 1.0574e-04 4.4409e-05 -6.0000e+00 3.1163e-03 1.5005e-03 1.5799e-05 10 0 0 10 0 0 99.92 23.49 0.15 0.00150 -0.00405 204 55 1 5 0 231.700 26.32 20.00 23.49 19.54 5.9 1009.21 -47629 -32759 -58291 -25294 -21292 10179 -13207 -29035 -64035 -13065 -10113 -28830 -3900 -15416 -6462 -16571 -19298 2342 3726 12075 7226 -6018 3898 -9556 -3839 -1145 -7979 -839 -4927 -7226 3102 -741 -4329 -299 -8152 -1282 -12230 4793 -2815 636 -1045 -590 -1709 -437 2003 -1521 683 -1326 6 -1301 2748 572 1592 830 1195 -1841 1479 1254 292 328 1904 1693 728 1700 995 2292 20 -608 -1213 888 412 444 1366 -110 630 356 207 -201 478 -245 -554 -573 -1320 -1412 -1388 -54 -330 -238 475 -1 880 584 695 626 865 501 526 519 228 374 -224 -217 -1383 -459 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