File name: Pandora156s1_HamptonVA-HU_20220421_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T150350.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20220421_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20220421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220421T110338.3Z 8146.460860 214 1 47.16 2 82.94 80.35 68.74 203.28 0.00 1 0.00 1 0 25 5.491e-01 3.219e-02 4.606e-01 2.833e-02 8.738674e-01 1.797727e-02 1.118546e-02 -6.000000e+00 3.553647e-01 229.48 -2.00 3.43 -2.00 322.45 0.00e+00 4.052278e-02 1.169932e-02 9.327015e-03 -6.000000e+00 1.987068e-02 283.51 -2.00 20.00 -2.00 321.98 0.00e+00 7.470 0.007 302.00 328.00 3 7.7686e-01 7.6524e-02 1.3398e-01 -6.0000e+00 8.9216e-01 1.2069e+00 9.9996e-02 1.6087e-01 -6.0000e+00 9.7991e-01 -1.3959e+00 8.1601e-02 3.0184e-02 -6.0000e+00 5.7130e-01 5.2173e-01 3.7312e-02 3.6163e-02 -6.0000e+00 2.3440e-01 4.6281e-05 -1.0762e-03 8.7331e-04 4.2864e-04 -6.0000e+00 1.7957e-02 6.5103e-03 2.9467e-05 12 8 8 10 0 0 -50.54 23.05 0.64 0.00651 -0.00158 41 11 1 5 0 1148.980 26.00 20.01 23.05 16.52 5.9 994.40 107998 900000 -160852 900000 -58927 900000 900000 900000 900000 900000 -170014 900000 -158547 -48222 -53961 -71415 900000 160048 900000 900000 900000 900000 900000 165700 900000 900000 -57347 900000 144867 900000 -75739 900000 -58536 900000 2920 900000 -31929 900000 34696 900000 900000 -47493 116877 65573 99799 59858 900000 78395 900000 34600 210535 49503 900000 42891 76719 5269 -8214 34108 76538 20973 900000 900000 -7658 15535 40943 73807 37463 52423 33217 88887 28976 38171 26948 20940 22199 31951 13199 2644 31034 -29050 7758 -8518 4224 -2230 439 -1728 5826 -4676 -3263 571 8846 888 6859 -1105 -5850 6301 -3344 -3150 -3663 2312 2813 -3972 -6518 519 -8085 -1938 2362 -5283 -1462 -2162 -199 386 -2409 -854 2854 -4044 302 -1494 483 -2155 792 -1991 206 2948 1309 3740 1469 1654 1389 2254 1843 2985 -508 90 -537 -821 -1344 2224 124 -465 1994 470 -2632 -2265 2965 900000 -8389 900000 -1618 900000 900000 900000 900000 900000 -4667 900000 -4581 -1324 -1481 -2373 900000 4393 900000 900000 900000 900000 900000 4548 900000 900000 -1574 900000 3977 900000 -3350 900000 -3392 900000 94 900000 -1315 900000 952 900000 900000 -3187 3208 1800 2739 1734 900000 2279 900000 1688 5779 2491 900000 2616 3592 466 -802 2203 3090 1456 900000 900000 -911 1706 4099 5482 3992 4910 4023 6889 4242 5609 4110 3347 3154 3663 1684 380 3808 -7487 1680 -2533 1237 -745 150 -635 2079 -1918 -1334 220 2981 303 2237 -398 -2329 2798 -1866 -2090 -2798 1770 2094 -2889 -4314 298 -5142 -1302 1614 -3972 -1173 -1998 -207 446 -3024 -1063 3339 -4909 349 -1825 613 -2947 1061 -2651 270 3623 1583 4281 1679 1915 1788 3356 3169 5650 -1018 191 -1235 -2014 -3446 5603 321 -1189 4993 1110 -6010 -5069 SS 20220421T111427.9Z 8146.468379 217 1 47.45 2 80.80 81.93 69.61 205.60 0.00 1 0.00 1 0 25 5.739e-01 1.756e-02 3.239e-01 8.274e-03 7.749650e-01 4.774390e-03 8.191385e-03 -6.000000e+00 3.408943e-01 229.48 -2.00 3.43 -2.00 321.94 0.00e+00 3.026071e-04 2.792380e-03 1.116884e-03 -6.000000e+00 1.670641e-02 283.51 -2.00 20.00 -2.00 321.42 0.00e+00 5.939 0.003 302.00 328.00 3 7.4592e-01 1.8648e-02 7.2456e-02 -6.0000e+00 8.5403e-01 3.7187e-01 2.6723e-02 4.2641e-02 -6.0000e+00 9.2962e-01 -5.0762e-01 2.6062e-02 2.2000e-02 -6.0000e+00 5.4680e-01 2.0395e-01 1.1781e-02 6.4835e-03 -6.0000e+00 2.2618e-01 3.0102e-04 -9.3920e-04 2.4723e-04 9.3058e-05 -6.0000e+00 1.7161e-02 6.1078e-03 -4.1004e-05 12 8 8 10 0 0 -28.26 23.05 0.52 0.00611 -0.00095 120 32 1 5 0 395.290 26.00 20.00 23.05 17.19 5.9 999.52 -240301 -211074 900000 -37609 -28262 -232124 -220710 900000 900000 900000 11375 -202704 -181122 -106088 -55744 52055 13945 -42162 2490 -54682 113478 -47866 -78261 -108496 -27774 900000 196076 900000 -57765 -56191 -40101 121690 2789 -13486 -14591 3792 -8797 79458 106808 11780 -57253 13618 24749 34863 18308 19394 -17152 17254 33019 35477 23575 238 6551 12072 26622 27556 22713 3092 3061 10243 18419 14052 7258 3789 14599 9032 20916 12628 33036 -2004 4420 5277 7091 3114 6745 788 936 3825 5411 1344 -3305 -2687 -4288 2967 3759 1786 -2085 433 -943 1438 336 -2376 -1906 -1637 178 577 -972 -1634 -2440 -2297 -927 197 -577 -1408 -3037 -2473 80 -500 -643 -1897 -1585 -1061 759 792 199 -140 -2683 2549 1024 49 164 32 55 563 2593 1545 1090 584 500 491 1122 750 14 106 225 498 369 -65 -1264 -226 -573 355 -332 -358 -4330 -3303 900000 -303 -228 -4073 -3663 900000 900000 900000 92 -4614 -4123 -1459 -582 420 112 -580 25 -959 915 -844 -1932 -3704 -490 900000 1581 900000 -1397 -1416 -1010 981 65 -401 -434 92 -257 1121 1399 481 -5023 679 1160 1511 941 997 -1296 956 1647 1859 1544 22 637 1216 2495 2693 2415 402 387 1166 1940 1657 1035 636 2398 1597 3267 2208 5127 -504 1169 1473 1958 855 1641 183 200 784 1191 362 -1111 -1044 -1906 1328 1779 919 -1177 247 -550 802 179 -1225 -937 -813 95 355 -712 -1397 -2363 -2334 -905 175 -466 -1087 -2460 -2123 71 -476 -668 -2243 -2111 -1546 1137 1185 290 -196 -3789 3502 1501 76 257 48 81 791 3451 2007 1378 744 693 777 1991 1466 30 238 539 1266 978 -176 -3494 -608 -1468 842 -746 -795 SS 20220421T112429.1Z 8146.475336 222 1 47.31 2 78.81 83.39 70.47 207.69 0.00 1 0.00 1 0 17 4.355e-01 1.073e-02 1.899e-01 3.860e-03 6.636667e-01 2.172377e-03 7.109594e-03 -6.000000e+00 2.580328e-01 229.48 -2.00 3.43 -2.00 321.51 0.00e+00 1.929204e-03 1.137324e-03 1.482636e-03 -6.000000e+00 1.178693e-02 283.51 -2.00 20.00 -2.00 320.94 0.00e+00 4.975 0.002 302.00 328.00 3 6.3628e-01 7.8017e-03 6.1617e-02 -6.0000e+00 6.4469e-01 1.3034e-01 1.0847e-02 3.8275e-02 -6.0000e+00 7.0136e-01 -1.5170e-01 1.0815e-02 1.8005e-02 -6.0000e+00 4.1360e-01 5.3871e-02 5.0420e-03 6.4111e-03 -6.0000e+00 1.7294e-01 9.5120e-04 -9.6358e-04 1.1867e-04 7.2622e-05 -6.0000e+00 1.2922e-02 6.1138e-03 -2.2829e-05 12 8 8 10 0 0 14.60 23.04 0.35 0.00611 -0.00113 231 62 1 5 0 204.760 26.00 20.01 23.04 17.89 5.9 1006.41 900000 -253416 900000 -60965 -121642 -201169 900000 -203597 900000 -133166 -100979 -67413 900000 -108283 -15666 -43627 27563 84499 -52453 -4514 36460 57669 -30741 69958 -66125 40994 -30348 -34181 -17299 41607 -45217 20493 15713 -20285 35872 -26714 560 3681 15745 -11046 24790 -7443 10146 14685 -15017 4576 9017 -4637 5299 9713 -4113 15036 1615 5902 7315 14321 648 8598 -449 10655 5278 4694 2994 8903 2913 3729 4921 -2949 3716 554 1749 1322 3052 -1612 2788 -2061 -2198 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