File name: Pandora156s1_HamptonVA-HU_20221130_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T165720.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20221130_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20221130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221130T151629.3Z 8369.636450 147 1 47.02 2 63.07 154.51 122.20 82.04 0.00 1 0.00 1 0 33 5.587e-01 2.067e-01 4.572e-01 1.822e-01 -6.595595e-02 9.198718e-02 3.011606e-03 -6.000000e+00 3.239123e-01 223.79 -2.00 3.43 -2.00 317.57 0.00e+00 1.601879e-02 1.462962e-02 2.071630e-03 -6.000000e+00 1.622701e-02 281.92 -2.00 20.00 -2.00 316.88 0.00e+00 2.196 0.000 302.00 328.00 3 9.3097e+00 2.4408e-01 2.4621e-02 -6.0000e+00 7.9975e-01 -6.3680e-01 2.7549e-01 2.2204e-02 -6.0000e+00 8.7536e-01 2.1890e-01 1.5726e-01 5.7584e-03 -6.0000e+00 5.2253e-01 3.1014e-02 7.1801e-02 1.1864e-02 -6.0000e+00 2.2103e-01 7.6549e-06 1.2381e-02 5.7031e-03 1.1705e-04 -6.0000e+00 1.6315e-02 -5.1063e-03 -3.6711e-04 12 8 8 10 0 0 98.67 23.17 4.61 -0.00511 0.08793 20 5 1 5 0 2350.710 26.11 20.00 23.17 19.28 11.8 1017.47 -89476 900000 256108 245250 39057 -50138 76715 42926 38 295136 900000 900000 71689 900000 41056 900000 147376 900000 22028 900000 -23223 25315 900000 83250 49098 38180 -13369 -6610 193289 -22143 900000 5353 -44146 5033 -37792 60456 58423 -10345 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-2271 29450 13765 13738 3865 -2892 -23725 -9626 15331 -27386 8306 -48504 7973 22488 -5343 -20511 9753 -14080 -8682 -8668 14188 22954 31299 7431 -13194 32724 39496 9444 -1162 6458 21262 4236 -22098 -17323 -7424 10414 10628 7586 -9151 8835 14948 17092 -30397 7011 327 13083 -47441 18080 33793 9899 8822 -19301 -33326 31173 14940 -21660 2383 1387 11394 -613 -24874 11471 23906 27842 -6389 -42508 2412 20582 32660 -24490 46649 45828 18447 856 -9864 16915 -10396 12575 -17890 -51188 12036 26920 8767 SS 20221130T182750.2Z 8369.769332 265 1 47.50 2 62.76 204.55 85.48 109.37 0.00 1 0.00 1 0 17 3.606e-02 9.677e-03 2.694e-02 5.984e-03 2.603457e-01 3.004759e-03 3.077898e-03 -6.000000e+00 2.068993e-02 223.79 -2.00 3.43 -2.00 318.31 0.00e+00 1.861230e-03 5.699961e-04 9.521936e-05 -6.000000e+00 9.255902e-04 281.91 -2.00 20.00 -2.00 317.58 0.00e+00 2.173 0.000 302.00 328.00 3 5.1681e+00 8.0532e-03 2.5188e-02 -6.0000e+00 5.0906e-02 5.2020e-02 9.1964e-03 1.3158e-02 -6.0000e+00 5.5476e-02 -1.5035e-03 5.7751e-03 6.5125e-03 -6.0000e+00 3.3158e-02 -5.9185e-03 2.9117e-03 2.4368e-03 -6.0000e+00 1.3950e-02 2.5057e-04 7.2612e-04 1.8725e-04 2.6662e-05 -6.0000e+00 1.0393e-03 2.5533e-03 2.4780e-04 12 8 8 10 0 0 99.95 23.21 0.51 0.00255 0.00801 18 5 1 5 0 2638.090 26.11 20.00 23.21 21.93 11.9 1040.83 12338 12015 -18934 -8148 -9741 1900 -535 -78 1839 44 -14517 -7050 180 13408 -3654 -14174 265 2660 5414 -4828 -63 1832 209 -2395 1227 -486 481 3880 -981 666 3479 -1860 4797 450 -1737 -4353 -143 300 2543 -3224 923 1602 -2439 -55 1400 -879 -125 -973 2762 -266 3320 1886 -1992 -1018 2606 1604 837 -3253 396 1869 -86 123 1702 2086 684 1752 37 -827 -877 1088 708 819 -194 852 -332 1800 -88 -95 -1081 1445 -664 -1754 -390 -1710 -1177 -1267 65 -296 -672 -1023 737 -1443 -66 42 965 2677 -130 1017 61 491 -837 -839 -1135 -1214 -1264 -148 -119 666 -612 -16 159 144 171 1575 580 -723 -312 -1263 403 -239 -904 434 175 118 555 344 34 3535 -135 783 -357 388 202 -212 -176 177 165 303 -339 702 -391 -636 -644 -417 758 872 -1820 -713 -782 128 -38 -6 155 4 -1525 -702 18 1389 -516 -2472 42 433 893 -912 -12 330 39 -472 245 -102 101 753 -188 122 647 -396 1033 105 -402 -997 -33 79 776 -1219 372 680 -1116 -25 630 -405 -57 -435 1165 -115 1438 883 -1031 -549 1407 894 478 -1939 224 1032 -53 80 1174 1441 491 1270 25 -543 -590 792 573 704 -171 728 -271 1315 -59 -59 -681 969 -512 -1519 -362 -1696 -1229 -1417 76 -363 -841 -1262 845 -1554 -64 38 880 2591 -144 1230 81 663 -1105 -1028 -1299 -1366 -1500 -186 -157 915 -893 -25 259 243 286 2469 850 -995 -411 -1703 563 -359 -1433 686 272 178 798 472 44 4326 -176 1079 -530 596 319 -345 -300 316 308 579 -663 1355 -742 -1168 -1143 -733 SS 20221130T184100.7Z 8369.778480 274 1 46.81 2 63.92 207.72 83.06 111.35 0.00 1 0.00 1 0 17 1.878e-01 3.390e-02 1.310e-01 1.917e-02 2.841918e-01 9.654576e-03 3.622684e-03 -6.000000e+00 1.077101e-01 223.79 -2.00 3.43 -2.00 318.35 0.00e+00 -4.845625e-04 1.874930e-03 1.113936e-03 -6.000000e+00 4.899778e-03 281.91 -2.00 20.00 -2.00 317.61 0.00e+00 2.261 0.000 302.00 328.00 3 6.3343e+00 2.5884e-02 2.6976e-02 -6.0000e+00 2.6485e-01 1.1697e-01 2.9635e-02 1.5715e-02 -6.0000e+00 2.8882e-01 -2.3597e-02 1.9244e-02 7.2968e-03 -6.0000e+00 1.7249e-01 6.5063e-03 9.9074e-03 2.0897e-03 -6.0000e+00 7.2495e-02 6.7299e-05 7.1883e-04 5.9672e-04 2.5829e-05 -6.0000e+00 5.4717e-03 5.7730e-03 -5.9143e-05 12 8 8 10 0 0 99.87 23.21 2.10 0.00577 0.01117 14 4 1 5 0 3342.770 26.11 19.99 23.21 22.22 11.9 1042.97 46138 52759 41944 170767 900000 -23479 4475 19094 -5124 11450 10664 16138 23800 -6116 39396 25407 2838 27407 -12940 8242 1899 12488 40385 2196 5824 -3257 2675 -4046 2391 -2539 9449 17519 -5689 -7028 10931 -4565 2124 -59291 -4606 1549 12408 1181 5379 7253 4930 3199 6943 7276 3859 486 -24 853 -1477 2917 274 3856 -2026 -2148 -5181 -261 5248 82 3568 95 1120 -4082 2891 807 1794 2939 1168 3707 -2783 4015 113 3527 1502 1921 2784 3114 338 2211 58 3142 -1335 -2432 -923 -2281 607 150 877 -7768 -4446 810 2480 2037 1543 -2561 745 -273 -1487 -1662 -2077 2807 622 180 -2623 -855 746 2202 1225 1527 2836 -381 -1292 -1134 2384 -958 -157 -837 1771 -2189 -279 -47 60 164 1132 -371 1571 -744 -1640 696 1 -876 48 -625 -2186 2239 -749 4241 -1053 36 1 -1278 2060 2410 2178 3192 900000 -1902 288 1190 -452 904 853 1331 2015 -756 3725 2876 424 3525 -2445 1301 325 2032 5062 425 1153 -734 568 -872 452 -491 1693 3139 -1389 -1800 2247 -1064 493 -29334 -1575 582 4638 522 2348 3142 2179 1432 2946 3008 1621 212 -11 413 -778 1549 155 2158 -1225 -1301 -3179 -150 2908 50 2306 68 809 -2953 1809 496 1130 2033 908 2971 -2408 3156 87 2529 992 1180 1714 2099 264 1880 55 3024 -1424 -2639 -1110 -2891 755 183 1000 -8874 -4498 736 2263 2025 1710 -3276 996 -376 -1984 -2056 -2402 3053 731 227 -3572 -1197 1078 3329 1983 2551 4628 -610 -1932 -1571 3075 -1299 -223 -1274 2734 -3534 -432 -71 85 222 1444 -467 2002 -1038 -2460 1063 1 -1432 81 -1126 -4154 4169 -1456 7784 -1975 65 2 -2218