File name: Pandora156s1_HamptonVA-HU_20230219_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T173824.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230219_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230219T134403.3Z 8450.572260 102 1 3.16 2 69.80 122.52 71.77 134.54 0.00 1 0.00 1 0 17 6.413e-02 1.190e-02 6.389e-02 1.068e-02 3.349917e-01 5.386084e-03 3.870940e-03 -6.000000e+00 3.694512e-02 225.36 -2.00 3.43 -2.00 318.56 0.00e+00 1.189058e-03 1.089960e-03 2.613399e-04 -6.000000e+00 1.622700e-03 278.73 -2.00 20.00 -2.00 317.89 0.00e+00 2.866 0.000 302.00 328.00 3 3.4324e+00 1.4555e-02 3.2970e-02 -6.0000e+00 9.1324e-02 7.3400e-02 1.6613e-02 1.6722e-02 -6.0000e+00 9.9527e-02 -2.5704e-02 1.1034e-02 8.2941e-03 -6.0000e+00 5.9291e-02 -7.3136e-04 5.6819e-03 2.5034e-03 -6.0000e+00 2.4749e-02 6.5388e-04 -4.4679e-04 3.2863e-04 2.9064e-05 -6.0000e+00 1.8493e-03 5.4906e-03 -7.3954e-05 12 9 9 12 1 1 999.00 22.86 2.55 0.00549 0.00213 1 9 1 5 0 1490.230 25.79 20.00 22.86 13.12 12.3 1005.05 30357 6927 -13294 -22443 -11259 -33621 -17125 -9681 1064 -14927 -6118 -7711 -849 -4334 -20240 15343 -4483 737 5686 9583 -5310 -5947 533 21363 8964 5493 749 -4995 -4331 -1040 -3496 -923 7194 -7503 5279 -10334 3242 -183 3845 -3608 -1541 931 -1893 992 -1377 -1095 5767 -1260 -3183 2932 -349 3149 1963 1437 -2303 448 1196 3241 817 -264 3249 502 1441 730 1299 1568 -321 -2865 691 4929 3288 637 -2228 -573 919 -1103 -573 3119 -1461 -2450 -1741 800 -854 -1406 -3110 -1907 -960 -152 663 831 -1362 -427 -1184 -190 1956 -324 1414 549 377 -572 486 863 -1514 284 -510 -358 -1554 -195 -755 392 -1135 448 -38 275 -418 -70 1249 -47 802 23 -564 874 450 392 1422 595 1317 -811 1171 549 490 -118 179 116 -270 437 -599 -1113 -442 102 -411 -164 -54 221 1075 346 -845 -1496 -610 -2171 -981 -575 63 -1104 -421 -562 -65 -406 -2593 1550 -593 98 752 1268 -835 -942 81 2759 1391 921 133 -900 -735 -169 -619 -176 1386 -1759 1056 -2347 682 -46 1109 -1319 -617 387 -764 397 -566 -450 2421 -560 -1433 1255 -162 1384 935 730 -1267 247 667 1777 452 -146 1763 297 924 510 931 1080 -211 -1867 451 3431 2581 545 -1992 -490 729 -813 -380 1876 -935 -1752 -1403 703 -831 -1338 -3191 -2069 -1095 -179 786 964 -1526 -437 -1226 -185 1915 -325 1558 680 510 -740 649 1064 -1773 320 -611 -459 -2118 -275 -1043 572 -1799 731 -63 430 -613 -95 1754 -68 1119 35 -886 1359 688 580 1996 869 1824 -1118 1640 835 740 -189 294 197 -483 761 -1099 -2107 -843 193 -756 -289 -100 400 SS 20230219T140021.9Z 8450.583587 111 1 47.30 2 67.10 125.70 69.54 137.70 0.00 1 0.00 1 0 17 1.401e-02 4.592e-03 7.045e-03 1.126e-03 2.996828e-01 5.657509e-04 3.485079e-03 -6.000000e+00 8.072901e-03 225.36 -2.00 3.43 -2.00 318.68 0.00e+00 1.665101e-04 1.184413e-04 1.008679e-04 -6.000000e+00 3.544729e-04 278.73 -2.00 20.00 -2.00 318.00 0.00e+00 2.550 0.000 302.00 328.00 3 1.9446e+00 1.5332e-03 2.9420e-02 -6.0000e+00 1.9955e-02 2.8704e-02 1.7547e-03 1.5079e-02 -6.0000e+00 2.1745e-02 3.3623e-03 1.1796e-03 7.4274e-03 -6.0000e+00 1.2955e-02 -9.4581e-03 6.1116e-04 2.0935e-03 -6.0000e+00 5.4093e-03 4.1978e-03 -1.9842e-04 3.5206e-05 2.5483e-05 -6.0000e+00 4.0385e-04 5.7745e-03 3.9312e-05 10 0 0 10 0 0 99.79 22.86 0.40 0.00577 0.00428 224 60 1 5 0 211.110 25.79 19.99 22.86 13.68 12.5 1011.61 3350 -5691 -4108 -451 -7151 -1341 -5969 -1719 2810 815 -2989 -2638 -2620 -2582 1493 -2023 -2181 -207 -1318 1680 -1599 -890 290 -2007 -358 -191 -639 -301 -1059 -966 1712 1172 475 810 -2331 -1095 -1698 -29 990 -185 -656 -910 -1214 -290 -863 -557 -741 -392 -1484 -36 244 957 1025 415 1166 570 978 787 -112 687 1155 1116 1783 1049 1000 296 -325 -81 125 676 527 232 148 370 70 409 270 69 -122 273 -232 -729 -1072 -1455 -1182 -1129 -394 -109 -241 -28 167 335 441 372 601 769 809 518 324 -33 -416 -318 -554 -131 -581 -341 -755 -574 -407 -154 -117 -18 -27 -152 70 100 231 79 128 91 13 -322 -115 97 478 608 733 824 767 613 204 374 -88 23 -80 -20 -122 62 -122 -130 -142 -69 -343 -412 149 -307 -226 -23 -352 -65 -290 -99 157 49 -190 -190 -211 -241 154 -242 -278 -27 -183 235 -237 -131 43 -321 -60 -33 -113 -51 -170 -151 274 206 92 163 -470 -211 -350 -7 274 -61 -243 -359 -498 -120 -359 -231 -306 -158 -598 -14 102 424 486 209 609 308 537 435 -62 371 630 646 1115 711 698 200 -205 -49 78 467 404 190 123 300 54 285 170 41 -73 179 -173 -608 -976 -1408 -1210 -1238 -455 -131 -295 -33 188 347 419 335 550 764 894 638 435 -45 -556 -394 -639 -148 -696 -436 -1021 -812 -604 -221 -178 -28 -42 -230 108 144 318 111 189 143 21 -488 -189 154 721 872 1000 1092 1049 902 323 618 -150 40 -134 -35 -225 118 -235 -251 -266 -123 -598 -714 SS 20230219T140548.6Z 8450.587368 114 1 47.24 2 66.22 126.79 68.83 138.79 0.00 1 0.00 1 0 17 1.488e-02 4.698e-03 4.633e-03 8.322e-04 2.903187e-01 4.213420e-04 3.353898e-03 -6.000000e+00 8.575694e-03 225.36 -2.00 3.43 -2.00 318.47 0.00e+00 1.666054e-04 8.227014e-05 9.148594e-05 -6.000000e+00 3.765507e-04 278.73 -2.00 20.00 -2.00 317.77 0.00e+00 2.462 0.000 302.00 328.00 3 1.5033e+00 1.1390e-03 2.8393e-02 -6.0000e+00 2.1198e-02 3.0773e-02 1.2986e-03 1.4488e-02 -6.0000e+00 2.3099e-02 -1.2466e-03 8.5679e-04 7.1494e-03 -6.0000e+00 1.3761e-02 -6.7374e-03 4.3747e-04 2.0392e-03 -6.0000e+00 5.7464e-03 7.2036e-03 -1.6036e-04 2.6107e-05 2.4309e-05 -6.0000e+00 4.2898e-04 5.6847e-03 5.1319e-05 10 0 0 10 0 0 99.94 22.86 0.30 0.00568 0.00448 346 93 1 5 0 136.490 25.79 20.00 22.86 13.84 12.5 1012.98 -4409 -1501 -3632 -4607 -5167 -8783 -4342 -822 -2413 1643 -2429 -4308 -5359 -1011 -1026 929 -686 -1438 -1434 -741 -648 596 576 718 671 -1192 -714 -845 -345 61 2286 192 452 505 -1787 -1407 -1185 -897 -74 9 -785 -421 -508 -767 -678 -502 -1146 -481 -655 -475 1216 728 797 872 643 737 1249 390 300 303 842 1122 1806 1116 1325 449 -572 -3 -3 738 608 410 -111 130 -165 277 192 -287 -378 26 -362 -996 -1078 -1502 -1190 -1005 -474 -271 112 -118 249 492 348 437 357 459 853 613 -48 -41 -283 -546 -490 -256 -529 -174 -713 -658 -386 -186 -140 84 -63 8 91 -11 348 150 191 52 -59 -224 -202 117 310 579 756 745 776 609 275 418 -22 -8 4 -2 -199 206 -174 -181 -142 -131 -335 -377 -248 -91 -232 -283 -289 -485 -240 -49 -163 113 -177 -329 -460 -96 -112 111 -88 -195 -203 -108 -97 88 95 125 124 -213 -141 -160 -61 11 402 38 96 112 -392 -298 -265 -231 -23 3 -316 -180 -225 -346 -306 -226 -514 -210 -283 -205 539 347 406 469 361 425 732 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