File name: Pandora156s1_HamptonVA-HU_20230331_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T175917.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230331_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230331T120739.2Z 8490.505315 178 1 48.25 2 75.92 95.47 118.22 343.11 0.00 1 0.00 1 0 25 3.325e-01 1.460e-02 2.918e-01 1.149e-02 5.937291e-01 6.294515e-03 6.612994e-03 -6.000000e+00 1.951596e-01 227.86 -2.00 3.43 -2.00 321.00 0.00e+00 3.085298e-04 2.775005e-03 2.166661e-03 -6.000000e+00 8.901993e-03 281.49 -2.00 20.00 -2.00 320.41 0.00e+00 4.020 0.001 302.00 328.00 3 3.7943e+00 2.0517e-02 5.1827e-02 -6.0000e+00 4.8450e-01 1.2417e-01 2.6697e-02 3.4577e-02 -6.0000e+00 5.2742e-01 -1.1260e-01 2.5101e-02 1.5902e-02 -6.0000e+00 3.1304e-01 3.8942e-02 1.2180e-02 4.6195e-03 -6.0000e+00 1.3233e-01 1.0568e-04 -4.8829e-04 3.5638e-04 6.3052e-05 -6.0000e+00 9.8777e-03 3.9639e-03 6.6417e-05 12 8 8 10 0 0 92.54 23.07 0.00 0.00396 0.00029 18 5 1 5 0 2680.090 26.00 20.00 23.07 16.63 13.0 1016.74 900000 900000 -195735 900000 -109915 -82139 900000 -144907 -118502 -40201 -18968 -82469 -85180 -23875 900000 -10731 -56203 -46922 -7527 -47268 1207 86931 61832 55999 56500 32108 13311 -34249 -9355 44971 -46732 2631 16602 -15077 -9041 27268 -8960 -10043 -15321 -5965 3534 7429 -5080 -9822 28174 -580 15926 2753 24702 13260 1265 -2230 16735 13683 13851 1391 6273 3100 10044 5010 -4819 979 -1372 4163 901 4311 -6577 3533 1689 789 3609 -2618 2465 -675 5412 694 1365 2321 5093 -1282 -2480 -3907 -1103 -4083 -472 521 -3203 896 -1084 -342 1012 434 -1238 766 -2415 29 630 -1376 -1073 2387 -351 609 648 -4309 -1333 2282 -285 -1576 1854 1098 -110 -582 353 -75 953 -1557 507 -252 -513 -263 56 -291 -526 -507 826 634 -451 1940 428 186 651 1678 342 -221 449 -223 496 -340 -895 -124 286 280 -355 -702 900000 900000 -5968 900000 -1376 -920 900000 -3055 -2186 -450 -212 -1358 -1740 -330 900000 -191 -1777 -1484 -174 -1713 28 974 866 902 989 719 368 -1489 -308 944 -2617 106 667 -904 -506 1042 -525 -695 -1363 -582 359 788 -643 -1339 2654 -74 1742 350 2604 1651 193 -392 2679 2452 2646 315 1401 721 2137 1096 -1175 241 -385 1234 296 1366 -2258 1101 572 305 1517 -1249 1132 -308 2164 263 470 765 1725 -530 -1211 -2216 -676 -2771 -328 383 -2585 721 -900 -276 762 306 -836 499 -1726 23 565 -1435 -1237 2769 -405 643 622 -4164 -1298 2286 -309 -1832 2234 1463 -164 -937 577 -120 1449 -2294 711 -363 -778 -418 91 -467 -818 -760 1174 866 -599 2485 591 286 1104 3036 660 -450 963 -511 1175 -830 -2216 -301 660 610 -741 -1454 SS 20230331T121802.4Z 8490.512528 181 1 47.05 2 73.86 97.09 118.78 345.64 0.00 1 0.00 1 0 17 1.602e-01 5.341e-03 8.550e-02 2.679e-03 5.265419e-01 1.423978e-03 5.832801e-03 -6.000000e+00 9.318788e-02 227.86 -2.00 3.43 -2.00 320.71 0.00e+00 3.556004e-04 5.705383e-04 8.556628e-04 -6.000000e+00 4.100062e-03 281.49 -2.00 20.00 -2.00 320.09 0.00e+00 3.537 0.001 302.00 328.00 3 1.8886e+00 4.4662e-03 4.4704e-02 -6.0000e+00 2.3147e-01 3.2172e-02 5.6522e-03 2.7796e-02 -6.0000e+00 2.5165e-01 -2.0808e-02 5.1818e-03 1.3566e-02 -6.0000e+00 1.4988e-01 -1.1665e-03 2.5705e-03 3.9545e-03 -6.0000e+00 6.2429e-02 1.2510e-03 -7.1700e-04 8.3424e-05 5.0476e-05 -6.0000e+00 4.6216e-03 4.5322e-03 2.4829e-06 10 0 0 10 0 0 91.29 23.07 0.36 0.00453 -0.00086 157 42 1 5 0 299.570 26.00 20.00 23.07 17.19 13.0 1021.49 -85953 -68542 -39125 -31930 -36101 -9910 -70240 -32951 -45779 -2376 -52150 -41463 -57251 -24271 -25386 -9038 -7345 -19665 -18466 -18895 -10054 -8772 -7346 -176 579 -6002 5249 -9554 6588 -3644 800 -5303 -2948 -10455 -6560 6913 -2753 -2031 -2366 1085 -1248 -332 -1347 2881 -2772 109 -542 2086 -2234 618 644 4746 2538 9 2566 832 1463 916 -264 1108 2649 1522 2872 324 1650 654 743 906 246 1147 -290 1069 698 903 -611 1115 -220 -545 -380 -756 -771 -872 -1657 -1608 -1288 -1152 -250 -365 -106 -318 362 49 1343 799 1026 356 644 677 574 514 55 -269 -1366 -505 -274 -100 -774 -482 -659 -287 -272 252 -75 239 -374 -151 300 55 309 -7 -168 -226 -257 -159 629 646 666 648 537 470 276 291 -120 -27 -278 34 -279 99 -300 462 -88 -28 -55 -386 -1033 -806 -368 -275 -302 -62 -863 -319 -574 -21 -804 -628 -1212 -457 -590 -210 -188 -622 -623 -676 -342 -298 -255 -6 22 -259 207 -427 243 -152 36 -292 -181 -749 -447 405 -190 -162 -231 123 -165 -47 -204 430 -443 17 -87 329 -377 106 119 933 558 2 650 224 404 257 -74 300 715 444 918 118 629 250 273 331 96 499 -143 556 370 462 -297 483 -88 -210 -153 -347 -410 -529 -1121 -1165 -989 -944 -215 -327 -96 -283 303 39 967 565 761 297 611 728 682 635 66 -300 -1406 -497 -280 -110 -896 -587 -860 -407 -421 415 -127 392 -584 -222 425 80 468 -12 -278 -371 -409 -244 920 905 896 858 751 727 469 530 -231 -55 -591 75 -655 236 -727 1100 -204 -61 -114 -800 SS 20230331T122754.2Z 8490.519378 184 1 46.66 2 71.91 98.66 119.23 348.06 0.00 1 0.00 1 0 17 8.035e-02 4.431e-03 3.335e-02 1.331e-03 4.743161e-01 6.932381e-04 5.313908e-03 -6.000000e+00 4.675098e-02 227.86 -2.00 3.43 -2.00 320.28 0.00e+00 6.191071e-04 2.449279e-04 4.177520e-04 -6.000000e+00 2.056896e-03 281.49 -2.00 20.00 -2.00 319.63 0.00e+00 3.177 0.000 302.00 328.00 3 1.1595e+00 2.0758e-03 4.0023e-02 -6.0000e+00 1.1613e-01 2.7135e-02 2.5479e-03 2.4496e-02 -6.0000e+00 1.2624e-01 -7.4637e-03 2.2049e-03 1.2024e-02 -6.0000e+00 7.5189e-02 -7.6652e-03 1.1165e-03 3.5315e-03 -6.0000e+00 3.1323e-02 3.8789e-03 -4.3969e-04 4.1161e-05 4.3853e-05 -6.0000e+00 2.3183e-03 4.0189e-03 1.4772e-05 10 0 0 10 0 0 83.28 23.07 0.33 0.00402 0.00071 347 93 1 5 0 134.450 26.00 20.00 23.07 17.86 13.0 1027.77 -11025 -23489 -30460 2357 -41180 25922 -29693 -25186 -24219 -23559 -21325 -20476 -21900 -14581 455 -10793 -851 -8981 5369 -3908 -235 -6427 630 -4702 3272 425 -4098 -6393 -6395 -191 -10411 -2119 -338 94 -4331 -225 -6244 -387 -1418 125 -497 -546 49 -101 -1069 -952 -24 -2032 -34 -1933 736 751 1475 762 1054 73 723 529 399 769 1455 3443 2274 1382 913 699 -389 718 -578 1358 600 334 153 -4 -424 351 -171 -87 312 -138 673 -553 -996 -1445 -1017 -1226 -135 -233 133 270 275 474 374 205 555 857 761 733 125 406 -414 -390 -603 -326 -674 -411 -675 -567 -483 -367 -33 -297 -95 25 143 89 463 13 267 -111 -11 -331 -228 277 518 536 655 731 434 410 73 422 -166 23 -216 45 -288 204 -160 -102 2 7 -114 -231 -107 -299 -443 24 -604 188 -401 -369 -399 -419 -387 -399 -509 -384 12 -385 -30 -378 210 -177 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