File name: Pandora156s1_HamptonVA-HU_20230515_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T182404.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230515_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230515T112730.0Z 8535.477430 144 1 46.93 2 73.77 78.33 51.03 132.63 0.00 1 0.00 1 0 17 3.468e-01 1.439e-02 2.887e-01 1.106e-02 5.005403e-01 5.913882e-03 5.547898e-03 -6.000000e+00 2.045446e-01 231.26 -2.00 3.43 -2.00 320.65 0.00e+00 2.743672e-03 2.362993e-03 6.360615e-04 -6.000000e+00 9.306199e-03 285.92 -2.00 20.00 -2.00 319.97 0.00e+00 3.519 0.001 302.00 328.00 3 3.8892e+00 1.8792e-02 4.3777e-02 -6.0000e+00 5.1249e-01 7.2656e-02 2.3525e-02 2.5976e-02 -6.0000e+00 5.5557e-01 -2.0077e-02 2.0378e-02 1.3295e-02 -6.0000e+00 3.2995e-01 -5.5255e-03 1.0121e-02 4.8491e-03 -6.0000e+00 1.3715e-01 1.7109e-04 -1.6548e-04 3.4474e-04 5.8775e-05 -6.0000e+00 1.0016e-02 1.3882e-03 5.9507e-06 12 9 8 11 8 0 99.98 23.82 0.04 0.00139 0.00014 42 11 1 5 0 1117.230 26.62 20.00 23.82 22.94 14.0 1013.59 -54337 -85312 -85341 -108533 -34925 -82815 -49737 -152800 4604 900000 -68953 5964 -48471 149437 -6659 -1178 -26173 114199 -655 8890 23144 7370 29247 11206 28006 216698 1852 -41821 -30332 -7118 52924 -23108 -15414 -6230 -5805 5023 22953 11166 6426 5928 7574 2843 1540 3824 4900 1682 -3049 -1867 -529 4868 -3974 2529 -1524 1209 2960 1564 1011 1061 -4213 1403 2054 1441 1646 1540 4373 3934 4917 1388 962 -893 2362 1704 2261 7210 -2284 3957 1428 1060 -884 -3010 -5565 -663 -3640 -838 -2770 -2542 -948 -1591 1911 -1596 737 -1132 1164 -27 2698 3033 1297 -529 1572 270 -945 -942 -1598 6473 -687 -1535 -3325 -876 -2137 146 -268 132 -417 -129 -740 224 61 530 -360 1380 -115 459 307 1742 -51 1071 99 196 611 1076 927 62 10 -174 382 -26 -716 -467 -86 733 -793 -69 -253 -28 -622 -1461 -1570 -2478 -377 -1313 -637 -5815 50 900000 -1443 68 -1076 1611 -157 -29 -930 1231 -21 276 686 243 848 415 944 2336 82 -2812 -1770 -339 1641 -1671 -1173 -466 -427 325 1408 843 615 681 970 413 238 597 768 276 -532 -326 -93 843 -809 531 -363 302 770 429 287 303 -1248 387 573 433 548 568 1659 1480 1756 509 374 -398 1137 880 1177 3462 -1127 1771 597 426 -378 -1487 -3071 -396 -2470 -591 -2116 -2070 -805 -1415 1663 -1411 640 -929 871 -20 2024 2527 1251 -588 1775 320 -1167 -1075 -1681 6068 -722 -1737 -4036 -1096 -2885 210 -421 219 -709 -212 -1159 327 87 761 -549 2189 -191 751 488 2640 -75 1500 134 260 853 1644 1552 111 19 -343 791 -57 -1657 -1105 -206 1717 -1815 -150 -524 -58 SS 20230515T120350.3Z 8535.502665 167 1 46.91 2 66.61 83.38 46.09 142.52 0.00 1 0.00 1 0 17 9.100e-02 8.468e-03 6.297e-02 5.878e-03 3.581339e-01 3.057559e-03 4.028503e-03 -6.000000e+00 5.368256e-02 231.27 -2.00 3.43 -2.00 319.33 0.00e+00 -7.520227e-04 7.813430e-04 2.018162e-04 -6.000000e+00 2.374975e-03 285.92 -2.00 20.00 -2.00 318.54 0.00e+00 2.500 0.000 302.00 328.00 3 4.5808e+00 8.6509e-03 3.1101e-02 -6.0000e+00 1.3424e-01 3.9281e-02 1.0068e-02 1.8381e-02 -6.0000e+00 1.4539e-01 4.8019e-03 7.1804e-03 8.8931e-03 -6.0000e+00 8.6589e-02 -9.3774e-03 3.6960e-03 2.5034e-03 -6.0000e+00 3.6028e-02 2.7965e-04 1.5697e-04 1.8624e-04 2.9303e-05 -6.0000e+00 2.6277e-03 -1.4781e-03 1.4254e-04 11 9 0 11 8 0 99.95 23.81 0.74 -0.00148 -0.00030 22 6 1 5 0 2131.790 26.62 20.00 23.81 24.51 14.1 1026.54 10797 -13576 5423 -12128 -33591 -24649 18665 7204 -10871 80077 -10023 -16515 14403 -5705 7983 -4794 1597 2137 -10363 3653 5589 -2931 -10254 5636 -5336 -5779 -6688 2946 -28582 4743 4339 -3583 -1117 2304 -2240 397 -22 6454 -772 1665 -2110 457 -667 630 4217 -1424 1053 1720 1565 -2474 947 6056 -3420 2090 1226 1833 1330 701 411 2852 236 737 1531 1067 460 187 -1423 -472 -611 707 -758 -1462 1425 480 150 978 367 -2225 295 1041 -116 -1348 161 -606 -1629 -673 -296 436 -275 -68 524 693 194 382 1079 -1362 603 596 225 634 -74 -759 -1801 -900 -643 -1056 -89 -628 -141 -551 226 2 -465 -188 618 199 -164 -225 523 -394 351 296 679 58 250 886 309 906 -41 1605 197 81 -493 -588 -268 624 -230 910 -301 108 56 -821 -246 -444 266 -481 166 -429 -1348 -865 447 219 -447 1431 -453 -830 597 -339 482 -372 126 177 -1024 328 507 -292 -1124 561 -637 -731 -866 334 -4193 489 505 -470 -158 332 -331 59 -4 1101 -160 401 -595 134 -207 196 1271 -483 347 556 504 -839 326 2144 -1433 882 548 842 630 337 195 1303 112 368 827 628 283 112 -811 -258 -346 439 -533 -1103 1065 354 105 616 210 -1226 160 619 -79 -1047 135 -543 -1564 -685 -319 486 -314 -76 552 672 174 325 931 -1313 637 704 291 843 -96 -919 -2035 -982 -734 -1296 -114 -849 -200 -836 365 3 -796 -308 939 283 -224 -313 760 -614 566 481 1074 90 368 1234 413 1171 -55 2293 307 134 -844 -1040 -496 1210 -469 1884 -639 228 114 -1622 -465 -833 SS 20230515T121734.0Z 8535.512199 175 1 47.22 2 63.88 85.32 44.48 146.67 0.00 1 0.00 1 0 17 2.402e-02 5.132e-03 1.562e-02 2.136e-03 3.287046e-01 1.103889e-03 3.751819e-03 -6.000000e+00 1.416418e-02 231.27 -2.00 3.43 -2.00 318.99 0.00e+00 8.540374e-04 2.546479e-04 1.124374e-04 -6.000000e+00 6.266620e-04 285.92 -2.00 20.00 -2.00 318.19 0.00e+00 2.258 0.000 302.00 328.00 3 3.1271e+00 3.0687e-03 2.8301e-02 -6.0000e+00 3.5420e-02 4.0407e-02 3.5319e-03 1.6920e-02 -6.0000e+00 3.8364e-02 1.9837e-03 2.3932e-03 8.2060e-03 -6.0000e+00 2.2848e-02 -7.8923e-03 1.2289e-03 2.3906e-03 -6.0000e+00 9.5044e-03 1.5686e-03 -1.8969e-04 6.6861e-05 2.7270e-05 -6.0000e+00 6.9347e-04 -1.0440e-03 9.4694e-05 10 0 0 10 0 0 99.64 23.81 0.26 -0.00104 -0.00247 100 27 1 5 0 472.100 26.62 20.01 23.81 25.50 14.2 1035.96 2918 -1610 -9860 -4428 -10602 -13817 895 2132 -7928 -1531 53 685 -9177 -2459 -2530 762 -8859 458 -1095 234 -1547 -165 -418 -751 -2056 453 4767 2366 -735 -858 535 919 2638 -165 -354 -2173 2436 -1681 -437 -416 -712 -1201 -1296 -1090 -1125 -1234 -11 -1140 -773 163 718 1102 775 1608 623 663 901 1357 -501 565 1808 1366 1343 1080 1017 819 -891 -281 -286 1390 759 508 -426 213 273 115 -116 -382 215 931 -489 -712 -788 -1865 -1376 -1121 -377 -625 -39 -28 706 119 659 -476 1145 614 759 519 204 165 -271 -401 -446 -739 -471 -127 -741 -430 -537 -195 -189 232 -90 5 2 217 132 177 139 185 -102 -268 -134 179 604 665 114 668 924 314 256 477 -85 -17 -12 32 -520 128 -11 -87 -148 -13 -144 -452 110 -71 -496 -204 -472 -603 35 92 -424 -82 3 38 -628 -184 -221 73 -999 50 -127 28 -192 -20 -53 -100 -294 66 673 330 -100 -115 74 140 433 -29 -62 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