File name: Pandora156s1_HamptonVA-HU_20230609_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T183605.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230609_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230609T112709.6Z 8560.477195 233 1 48.28 2 72.13 74.36 56.17 201.94 0.00 1 0.00 1 0 17 3.243e-01 1.985e-02 2.422e-01 1.303e-02 5.065171e-01 7.005519e-03 5.698652e-03 -6.000000e+00 1.943938e-01 232.52 -2.00 3.43 -2.00 320.54 0.00e+00 4.276281e-03 2.650471e-03 1.089363e-03 -6.000000e+00 9.022891e-03 288.29 -2.00 20.00 -2.00 319.79 0.00e+00 3.214 0.001 302.00 328.00 3 4.7472e+00 2.1986e-02 4.1683e-02 -6.0000e+00 4.8676e-01 1.4228e-01 2.6864e-02 2.6179e-02 -6.0000e+00 5.2692e-01 -1.5861e-01 2.1642e-02 1.3664e-02 -6.0000e+00 3.1221e-01 5.6977e-02 1.0903e-02 5.3015e-03 -6.0000e+00 1.2928e-01 9.5403e-05 -3.1956e-04 4.0603e-04 7.0069e-05 -6.0000e+00 9.4559e-03 1.4670e-03 -1.7295e-05 12 8 8 10 0 0 86.66 23.70 0.84 0.00147 -0.00093 13 3 1 5 0 3713.390 26.51 20.00 23.70 23.20 14.7 1003.79 -89331 -54237 -75016 -24687 -139957 900000 900000 -61955 -55363 -34978 -28004 900000 62402 -18209 221349 -61248 -6980 -21787 3775 36557 -7935 -34100 37999 56064 80055 110812 -41747 18521 -574 -14385 24150 6135 19703 17306 -68418 -12797 16101 26031 17836 21179 -5817 7285 -12470 13765 -7184 4189 -2394 3999 4485 10664 8060 -533 3530 517 4624 12590 3656 24 11588 3150 5145 3730 3499 13195 7631 9123 2488 2415 4980 -184 2509 -2061 3033 4781 -5044 3420 2584 -1557 -8780 -3451 -407 -2782 -1714 -1692 -2719 -1412 -329 536 648 211 -3518 522 500 -3399 -136 -682 -774 -799 -3149 1197 -792 2136 -669 394 -1660 1222 -3015 1158 -2360 808 316 -862 678 950 -526 -806 -997 -70 -16 508 958 886 575 -709 1468 833 676 846 -110 808 700 666 1677 632 952 412 -1030 -936 36 -88 -738 -692 -618 90 -2136 -1054 -1906 -369 -6065 900000 900000 -1342 -1241 -680 -523 900000 793 -490 2812 -3615 -266 -1042 149 1161 -379 -2115 1237 1602 1907 2023 -3338 838 -31 -902 1150 404 1283 1237 -10633 -1179 1176 1984 1770 2404 -974 1151 -2515 2197 -1432 755 -466 737 837 1939 1612 -127 880 142 1289 3348 1088 7 3137 913 1487 1170 1220 4609 2981 3462 966 928 1965 -86 1269 -1160 1642 2460 -2671 1510 1046 -629 -3980 -1679 -222 -1767 -1188 -1252 -2157 -1181 -288 484 592 190 -3112 411 367 -2520 -102 -575 -745 -872 -3880 1465 -957 2317 -683 385 -1723 1316 -3568 1390 -3127 1128 483 -1423 1120 1523 -809 -1169 -1406 -99 -24 800 1548 1423 898 -1084 2107 1228 957 1175 -162 1300 1157 1177 3068 1219 1932 891 -2353 -2187 84 -203 -1657 -1476 -1257 181 SS 20230609T113255.1Z 8560.481193 236 1 47.80 2 71.02 75.13 56.58 203.49 0.00 1 0.00 1 0 17 2.789e-01 1.011e-02 2.419e-01 7.630e-03 4.888578e-01 4.061509e-03 5.427839e-03 -6.000000e+00 1.651905e-01 232.52 -2.00 3.43 -2.00 320.42 0.00e+00 1.466742e-04 1.507612e-03 8.440616e-04 -6.000000e+00 7.348108e-03 288.29 -2.00 20.00 -2.00 319.67 0.00e+00 3.038 0.000 302.00 328.00 3 4.1922e+00 1.2646e-02 3.9996e-02 -6.0000e+00 4.1405e-01 4.0777e-02 1.5647e-02 2.6136e-02 -6.0000e+00 4.4788e-01 -2.3417e-02 1.3024e-02 1.2404e-02 -6.0000e+00 2.6684e-01 2.7740e-04 6.5193e-03 3.5757e-03 -6.0000e+00 1.1095e-01 2.0610e-04 -4.1490e-04 2.3909e-04 4.1886e-05 -6.0000e+00 8.0562e-03 -4.9154e-04 4.6400e-05 12 8 8 10 0 0 56.47 23.70 0.65 -0.00049 -0.00361 23 6 1 5 0 2077.690 26.51 19.99 23.70 23.57 14.6 1006.59 90073 189454 -70088 96378 -52967 114241 -18179 -80589 -63609 4595 99020 51845 18803 -29125 -29530 -21928 -18660 -20608 2480 -20911 -20075 3189 26233 -11001 2641 10580 -4490 1989 2551 -20435 -9435 25139 -8297 22661 21521 22181 -3901 -5007 -23244 15482 3297 -1361 -9360 8701 -2280 3043 330 1423 -565 -4252 5847 -3669 128 96 4080 4255 1145 -18 4002 713 -1989 1105 936 1728 1160 4890 -1940 -975 1894 2385 1307 -1814 -1369 1431 1390 1705 1994 -632 616 -3822 1420 -418 -901 -1833 -3912 -1442 2152 633 810 1596 -1133 163 193 398 1168 122 -952 1497 -207 882 700 -294 -1241 -1414 -1573 -354 -677 -759 -464 68 -349 -394 -59 -952 562 47 447 -464 47 -77 710 -616 216 -112 903 131 23 1288 1036 1126 29 661 -269 323 -303 -23 -131 268 -85 72 -280 -487 -318 -101 670 1410 -1319 717 -813 850 -203 -1912 -1450 58 737 458 271 -826 -1016 -816 -746 -911 93 -1051 -1037 132 891 -583 133 522 -263 106 131 -1331 -606 1310 -683 1476 1401 1403 -341 -515 -3482 1887 517 -242 -1890 1506 -444 568 64 273 -112 -910 1213 -920 34 27 1181 1281 367 -6 1240 224 -650 373 349 705 503 2018 -819 -403 800 1125 697 -1066 -815 805 732 815 863 -267 266 -1941 790 -269 -644 -1413 -3270 -1258 1920 597 773 1485 -1026 135 149 297 900 106 -942 1634 -253 1109 855 -336 -1311 -1443 -1675 -398 -804 -953 -617 97 -547 -657 -100 -1578 867 68 627 -668 70 -122 1159 -1014 342 -172 1406 197 33 1792 1513 1801 49 1162 -499 620 -618 -50 -294 614 -197 167 -625 -1036 -647 -202 SS 20230609T113819.5Z 8560.484948 239 1 47.45 2 69.98 75.85 56.99 204.92 0.00 1 0.00 1 0 25 1.350e-01 7.738e-03 1.113e-01 5.127e-03 4.610139e-01 2.730106e-03 5.163534e-03 -6.000000e+00 8.032624e-02 232.52 -2.00 3.43 -2.00 320.22 0.00e+00 1.318981e-03 9.397646e-04 2.069825e-04 -6.000000e+00 3.607778e-03 288.29 -2.00 20.00 -2.00 319.45 0.00e+00 2.889 0.000 302.00 328.00 3 3.7526e+00 8.2833e-03 3.7699e-02 -6.0000e+00 2.0114e-01 4.9158e-02 1.0080e-02 2.3976e-02 -6.0000e+00 2.1759e-01 -3.7330e-02 8.0742e-03 1.1680e-02 -6.0000e+00 1.2942e-01 5.6614e-03 4.0839e-03 3.5477e-03 -6.0000e+00 5.3727e-02 3.8130e-04 -5.4435e-04 1.6197e-04 4.2563e-05 -6.0000e+00 3.9009e-03 -8.7244e-04 5.1941e-05 11 8 0 10 0 0 5.01 23.70 0.52 -0.00087 -0.00496 35 9 1 5 0 1355.500 26.51 20.00 23.70 23.75 14.6 1007.67 -27819 -55759 73389 5081 -55882 900000 -4943 -18831 -2094 -68248 9552 -63266 -26413 -14697 -4410 -2175 20689 -229 749 14245 4445 -10383 -9816 -12673 4534 -8353 -4794 -692 14773 -6696 -3791 5656 -7953 -16008 -8018 3163 -3639 -8217 -5135 2716 11001 2591 104 4855 -4786 -2116 3493 -3923 4227 -133 -1289 3710 2991 1918 2542 -1710 3967 1982 691 -851 1961 -446 3056 2940 863 1659 1215 -142 -1157 115 557 1490 -439 358 -269 1333 -253 -189 -2765 -952 -913 -873 -979 -2473 -1540 -1071 873 8 275 571 359 15 799 -855 -288 -121 849 1080 212 -90 -182 -496 -1066 -543 -1198 -791 -995 -180 -732 701 291 420 239 90 -74 161 -45 -453 -208 -41 108 408 -925 171 1029 -54 571 645 -299 303 557 433 940 35 -187 -126 -262 -34 -116 18 -397 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