File name: Pandora156s1_HamptonVA-HU_20230624_L2Fit_fout2c5d20220209p1-8.txt File generation date: 20240912T184259.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 156 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora156_OF_v2d20211021.txt Instrument calibration file used: Pandora156s1_CF_v5d20220209.txt Level 1 file used: Pandora156s1_HamptonVA-HU_20230624_L1_smca1c5d20220209p1-8.txt Full location name: Hampton University Short location name: HamptonVA-HU Country of location: United States Location latitude [deg]: 37.0203 Location longitude [deg]: -76.3366 Location altitude [m]: 19 Local noon date: 20230624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "AnaLab+Fld 1.8 VP 20220209" First and last pixel inside fitting window: 221 364 Nominal wavelengths inside fitting window [nm]: 305.0425 305.1828 305.3231 305.4633 305.6035 305.7438 305.8840 306.0242 306.1644 306.3045 306.4447 306.5849 306.7250 306.8651 307.0053 307.1454 307.2855 307.4256 307.5656 307.7057 307.8457 307.9858 308.1258 308.2658 308.4058 308.5458 308.6858 308.8258 308.9658 309.1057 309.2456 309.3856 309.5255 309.6654 309.8053 309.9452 310.0850 310.2249 310.3647 310.5046 310.6444 310.7842 310.9240 311.0638 311.2036 311.3433 311.4831 311.6228 311.7626 311.9023 312.0420 312.1817 312.3214 312.4611 312.6007 312.7404 312.8800 313.0196 313.1593 313.2989 313.4385 313.5780 313.7176 313.8572 313.9967 314.1363 314.2758 314.4153 314.5548 314.6943 314.8338 314.9732 315.1127 315.2521 315.3916 315.5310 315.6704 315.8098 315.9492 316.0885 316.2279 316.3673 316.5066 316.6459 316.7852 316.9246 317.0638 317.2031 317.3424 317.4817 317.6209 317.7601 317.8994 318.0386 318.1778 318.3170 318.4561 318.5953 318.7345 318.8736 319.0127 319.1518 319.2910 319.4301 319.5691 319.7082 319.8473 319.9863 320.1254 320.2644 320.4034 320.5424 320.6814 320.8204 320.9593 321.0983 321.2372 321.3762 321.5151 321.6540 321.7929 321.9318 322.0706 322.2095 322.3484 322.4872 322.6260 322.7648 322.9036 323.0424 323.1812 323.3200 323.4587 323.5975 323.7362 323.8749 324.0136 324.1523 324.2910 324.4297 324.5684 324.7070 324.8456 324.9843 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230624T141952.5Z 8575.597135 216 1 18.53 2 38.39 98.67 104.42 66.23 0.00 1 0.00 1 0 17 1.234e-02 6.757e-03 8.634e-03 3.865e-03 1.998768e-01 2.020991e-03 2.308419e-03 -6.000000e+00 7.324713e-03 232.74 -2.00 3.43 -2.00 316.54 0.00e+00 1.843556e-04 2.419568e-04 3.434189e-05 -6.000000e+00 3.273499e-04 289.67 -2.00 20.00 -2.00 315.69 0.00e+00 1.275 0.000 302.00 328.00 3 5.1872e+00 5.3268e-03 1.6433e-02 -6.0000e+00 1.8361e-02 5.3618e-02 5.9571e-03 1.0167e-02 -6.0000e+00 1.9844e-02 1.4754e-03 3.4181e-03 4.9079e-03 -6.0000e+00 1.1832e-02 -5.5597e-03 1.5613e-03 1.3430e-03 -6.0000e+00 4.9308e-03 6.4751e-04 5.5589e-04 1.1825e-04 1.6910e-05 -6.0000e+00 3.5651e-04 -3.9309e-03 2.2206e-04 12 9 1 12 1 1 99.97 24.01 0.36 -0.00393 0.00025 6 5 1 5 0 2620.830 26.73 20.00 24.01 33.43 15.5 1066.55 1799 -150 -541 -5807 -5702 -1472 -709 3148 -58 1800 -1594 -2251 -1336 2491 2242 -1721 1400 910 2319 1217 1245 -1449 -2548 -1453 20 379 337 1262 -295 244 1083 2555 762 295 -2074 -2353 -1148 684 -704 -86 1492 -1014 -1752 -478 -1752 -473 347 -367 -3 -1464 839 -394 1425 4 733 587 545 288 327 620 693 1160 1465 1856 1089 426 -329 -1362 -137 193 564 101 310 695 187 -151 -259 -496 345 16 -637 -1176 -1613 -2255 -1196 -1378 -371 -233 336 15 923 286 899 59 923 1292 376 511 -236 359 270 -152 -716 -649 -791 -449 -842 -653 -80 92 -362 538 -128 -382 50 -724 374 135 360 279 502 7 141 58 330 84 288 705 4 644 26 869 322 279 79 437 -397 35 21 121 -482 -364 -675 -213 294 -27 -101 -1082 -951 -233 -114 538 -11 365 -333 -473 -298 600 607 -529 435 291 754 411 430 -512 -915 -535 8 149 133 469 -103 81 361 889 287 116 -801 -873 -439 292 -361 -48 914 -672 -1204 -329 -1215 -322 230 -237 -2 -909 521 -262 980 3 550 449 423 225 252 470 533 932 1262 1691 1018 380 -270 -1065 -107 165 531 102 318 696 179 -133 -205 -383 260 13 -545 -1119 -1665 -2469 -1368 -1598 -453 -297 432 19 1100 333 944 58 895 1329 429 605 -305 471 342 -190 -844 -752 -968 -554 -1098 -887 -113 135 -563 854 -202 -572 69 -923 476 174 488 383 725 11 205 82 443 114 369 864 5 846 37 1178 448 395 117 680 -649 59 36 205 -805 -588 -1060 -330 SS 20230624T142349.0Z 8575.599872 219 1 3.12 2 37.61 99.42 103.73 66.89 0.00 1 0.00 1 0 17 7.762e-03 5.647e-03 2.912e-03 1.580e-03 1.940708e-01 8.283648e-04 2.264478e-03 -6.000000e+00 4.603328e-03 232.74 -2.00 3.43 -2.00 315.87 0.00e+00 2.621256e-04 8.636929e-05 3.103709e-05 -6.000000e+00 2.057740e-04 289.67 -2.00 20.00 -2.00 315.07 0.00e+00 1.261 0.000 302.00 328.00 3 2.2530e+00 2.1674e-03 1.6151e-02 -6.0000e+00 1.1539e-02 2.6892e-02 2.4152e-03 9.9089e-03 -6.0000e+00 1.2475e-02 1.1352e-03 1.3776e-03 4.7888e-03 -6.0000e+00 7.4375e-03 -4.0380e-03 6.1144e-04 1.3001e-03 -6.0000e+00 3.0968e-03 1.2621e-02 -1.1061e-04 4.7734e-05 1.7154e-05 -6.0000e+00 2.2426e-04 -2.1007e-03 7.2564e-05 12 1 1 12 1 1 95.62 24.01 0.29 -0.00210 -0.00293 15 69 1 5 0 183.590 26.73 19.99 24.01 33.74 15.5 1069.07 -1362 616 -1594 -1798 -3185 -2421 -1043 452 1420 -226 -858 -766 295 835 33 316 -404 520 72 908 422 220 585 379 463 165 61 -670 -292 834 1206 1140 1328 1031 -643 -1238 -1294 -886 -152 246 -107 -1106 -679 -1093 -1009 -754 -559 -1110 -595 -835 299 812 1192 888 1066 319 1264 590 214 500 1475 1060 1325 1145 684 326 -548 -188 -345 894 350 162 -6 -18 -246 88 -135 -25 -183 -85 -336 -1184 -1123 -1431 -1196 -1156 -438 -470 -177 -190 164 107 358 421 486 735 522 574 257 -19 -177 -417 -533 -350 -540 -41 -712 -474 -520 -158 63 -75 61 -39 -54 42 456 355 217 352 -22 -188 -170 222 601 869 890 916 803 571 453 499 -186 60 -333 -64 -284 123 -149 -132 -206 -339 -275 -581 -309 149 -402 -430 -693 -488 -213 100 345 -59 -224 -199 82 257 11 119 -147 192 28 353 168 87 233 157 201 74 27 -290 -128 343 501 502 569 458 -279 -565 -566 -439 -88 154 -75 -821 -516 -845 -777 -576 -418 -807 -416 -576 209 595 919 719 889 273 1089 513 184 425 1260 888 1190 1094 667 302 -469 -163 -302 787 343 169 -6 -19 -246 81 -119 -21 -147 -73 -299 -1174 -1203 -1512 -1332 -1379 -552 -581 -221 -234 203 121 395 431 495 795 580 702 319 -24 -218 -512 -613 -396 -646 -52 -903 -626 -716 -227 90 -110 88 -56 -72 56 569 448 289 471 -31 -271 -242 306 786 1149 1116 1105 984 741 620 665 -254 84 -484 -97 -428 189 -234 -208 -318 -506 -423 -888 SS 20230624T142817.6Z 8575.602981 222 1 48.53 2 36.73 100.30 102.94 67.64 0.00 1 0.00 1 0 17 7.954e-03 5.205e-03 6.364e-04 2.626e-04 1.934929e-01 1.362220e-04 2.251838e-03 -6.000000e+00 4.718319e-03 232.74 -2.00 3.43 -2.00 316.73 0.00e+00 1.224111e-04 1.709905e-05 3.929603e-05 -6.000000e+00 2.109032e-04 289.67 -2.00 20.00 -2.00 315.85 0.00e+00 1.247 0.000 302.00 328.00 3 5.7074e-01 3.6068e-04 1.6041e-02 -6.0000e+00 1.1827e-02 2.1088e-02 4.0390e-04 9.9129e-03 -6.0000e+00 1.2785e-02 5.5643e-04 2.3332e-04 4.7824e-03 -6.0000e+00 7.6227e-03 -4.7039e-03 1.0791e-04 1.2852e-03 -6.0000e+00 3.1750e-03 6.9163e-02 2.2648e-04 8.0749e-06 1.6359e-05 -6.0000e+00 2.2979e-04 -2.7495e-03 1.3098e-04 10 0 0 10 0 0 99.95 24.01 0.29 -0.00275 -0.00105 2647 712 1 5 0 17.680 26.73 20.00 24.01 34.22 15.5 1074.80 -580 -873 -2005 -2408 -3945 -2278 -1202 930 754 -126 -1009 -731 -642 68 224 97 -296 -505 273 386 354 -28 848 411 724 152 292 -498 -177 421 1194 1743 1327 594 -1194 -1356 -1324 -382 -191 302 -465 -581 -1083 -905 -964 -533 -734 -798 -643 -538 390 722 1137 1050 945 420 1100 503 375 397 1036 966 1533 961 900 271 -550 -250 -224 763 365 213 -60 279 -109 392 -123 -28 -148 -14 -430 -945 -1205 -1550 -1229 -1228 -379 -355 -75 -196 135 151 335 225 572 664 727 658 137 25 -265 -370 -531 -175 -513 -242 -686 -489 -426 -181 4 73 7 -62 -4 -22 326 67 360 166 50 -206 -183 195 501 633 837 804 813 635 345 436 -70 63 -120 -22 -141 168 -201 -214 -234 -166 -429 -469 -89 -147 -348 -397 -591 -313 -168 154 127 -23 -181 -143 -135 16 53 25 -80 -140 85 124 116 -9 277 140 258 56 108 -177 -58 131 374 573 466 217 -427 -466 -476 -155 -91 168 -289 -382 -735 -621 -660 -361 -489 -515 -400 -329 242 470 779 754 702 320 845 390 287 301 791 776 1316 881 839 241 -450 -192 -174 644 343 214 -62 280 -105 343 -97 -21 -105 -11 -368 -897 -1237 -1683 -1406 -1368 -446 -436 -93 -240 156 176 354 221 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