File name: Pandora37s1_HamptonVA_20220312_L2Fit_fnvs5c5d20210730p1-8.txt File generation date: 20250725T135810.1Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v5d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20220312_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20220312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 950 1498 Nominal wavelengths inside fitting window [nm]: 400.1296 400.2610 400.3925 400.5239 400.6553 400.7867 400.9181 401.0495 401.1808 401.3122 401.4435 401.5748 401.7061 401.8374 401.9687 402.1000 402.2312 402.3624 402.4936 402.6248 402.7560 402.8872 403.0184 403.1495 403.2806 403.4117 403.5428 403.6739 403.8050 403.9361 404.0671 404.1981 404.3291 404.4601 404.5911 404.7221 404.8531 404.9840 405.1149 405.2458 405.3767 405.5076 405.6385 405.7693 405.9002 406.0310 406.1618 406.2926 406.4234 406.5542 406.6849 406.8157 406.9464 407.0771 407.2078 407.3385 407.4691 407.5998 407.7304 407.8610 407.9917 408.1222 408.2528 408.3834 408.5139 408.6445 408.7750 408.9055 409.0360 409.1665 409.2969 409.4274 409.5578 409.6882 409.8186 409.9490 410.0794 410.2098 410.3401 410.4704 410.6008 410.7311 410.8613 410.9916 411.1219 411.2521 411.3823 411.5126 411.6428 411.7729 411.9031 412.0333 412.1634 412.2935 412.4236 412.5537 412.6838 412.8139 412.9439 413.0740 413.2040 413.3340 413.4640 413.5940 413.7239 413.8539 413.9838 414.1138 414.2437 414.3736 414.5034 414.6333 414.7631 414.8930 415.0228 415.1526 415.2824 415.4121 415.5419 415.6717 415.8014 415.9311 416.0608 416.1905 416.3201 416.4498 416.5794 416.7091 416.8387 416.9683 417.0979 417.2274 417.3570 417.4865 417.6160 417.7455 417.8750 418.0045 418.1340 418.2634 418.3929 418.5223 418.6517 418.7811 418.9104 419.0398 419.1691 419.2985 419.4278 419.5571 419.6864 419.8156 419.9449 420.0741 420.2034 420.3326 420.4618 420.5910 420.7201 420.8493 420.9784 421.1075 421.2366 421.3657 421.4948 421.6239 421.7529 421.8820 422.0110 422.1400 422.2690 422.3979 422.5269 422.6558 422.7848 422.9137 423.0426 423.1715 423.3003 423.4292 423.5580 423.6868 423.8157 423.9444 424.0732 424.2020 424.3307 424.4595 424.5882 424.7169 424.8456 424.9743 425.1029 425.2316 425.3602 425.4888 425.6174 425.7460 425.8746 426.0031 426.1317 426.2602 426.3887 426.5172 426.6457 426.7741 426.9026 427.0310 427.1594 427.2878 427.4162 427.5446 427.6730 427.8013 427.9296 428.0580 428.1863 428.3145 428.4428 428.5711 428.6993 428.8275 428.9557 429.0839 429.2121 429.3403 429.4684 429.5966 429.7247 429.8528 429.9809 430.1089 430.2370 430.3651 430.4931 430.6211 430.7491 430.8771 431.0050 431.1330 431.2609 431.3889 431.5168 431.6447 431.7725 431.9004 432.0283 432.1561 432.2839 432.4117 432.5395 432.6673 432.7950 432.9228 433.0505 433.1782 433.3059 433.4336 433.5613 433.6889 433.8165 433.9442 434.0718 434.1994 434.3269 434.4545 434.5820 434.7096 434.8371 434.9646 435.0921 435.2195 435.3470 435.4744 435.6019 435.7293 435.8567 435.9840 436.1114 436.2388 436.3661 436.4934 436.6207 436.7480 436.8753 437.0025 437.1298 437.2570 437.3842 437.5114 437.6386 437.7658 437.8929 438.0200 438.1472 438.2743 438.4014 438.5284 438.6555 438.7825 438.9096 439.0366 439.1636 439.2906 439.4175 439.5445 439.6714 439.7984 439.9253 440.0522 440.1790 440.3059 440.4327 440.5596 440.6864 440.8132 440.9400 441.0667 441.1935 441.3202 441.4470 441.5737 441.7004 441.8270 441.9537 442.0804 442.2070 442.3336 442.4602 442.5868 442.7134 442.8399 442.9665 443.0930 443.2195 443.3460 443.4725 443.5989 443.7254 443.8518 443.9782 444.1047 444.2310 444.3574 444.4838 444.6101 444.7364 444.8628 444.9890 445.1153 445.2416 445.3678 445.4941 445.6203 445.7465 445.8727 445.9989 446.1250 446.2512 446.3773 446.5034 446.6295 446.7556 446.8817 447.0077 447.1337 447.2598 447.3858 447.5118 447.6377 447.7637 447.8896 448.0156 448.1415 448.2674 448.3932 448.5191 448.6450 448.7708 448.8966 449.0224 449.1482 449.2740 449.3997 449.5255 449.6512 449.7769 449.9026 450.0283 450.1540 450.2796 450.4053 450.5309 450.6565 450.7821 450.9076 451.0332 451.1587 451.2843 451.4098 451.5353 451.6608 451.7862 451.9117 452.0371 452.1625 452.2879 452.4133 452.5387 452.6641 452.7894 452.9147 453.0400 453.1653 453.2906 453.4159 453.5411 453.6664 453.7916 453.9168 454.0420 454.1671 454.2923 454.4174 454.5426 454.6677 454.7928 454.9178 455.0429 455.1680 455.2930 455.4180 455.5430 455.6680 455.7930 455.9179 456.0429 456.1678 456.2927 456.4176 456.5425 456.6673 456.7922 456.9170 457.0418 457.1666 457.2914 457.4162 457.5409 457.6656 457.7904 457.9151 458.0398 458.1644 458.2891 458.4137 458.5384 458.6630 458.7876 458.9122 459.0367 459.1613 459.2858 459.4103 459.5348 459.6593 459.7838 459.9082 460.0327 460.1571 460.2815 460.4059 460.5303 460.6547 460.7790 460.9033 461.0277 461.1520 461.2762 461.4005 461.5248 461.6490 461.7732 461.8974 462.0216 462.1458 462.2700 462.3941 462.5182 462.6423 462.7664 462.8905 463.0146 463.1386 463.2627 463.3867 463.5107 463.6347 463.7586 463.8826 464.0065 464.1305 464.2544 464.3783 464.5021 464.6260 464.7499 464.8737 464.9975 465.1213 465.2451 465.3688 465.4926 465.6163 465.7401 465.8638 465.9875 466.1111 466.2348 466.3584 466.4820 466.6057 466.7293 466.8528 466.9764 467.0999 467.2235 467.3470 467.4705 467.5940 467.7174 467.8409 467.9643 468.0878 468.2112 468.3345 468.4579 468.5813 468.7046 468.8279 468.9513 469.0746 469.1978 469.3211 469.4443 469.5676 469.6908 469.8140 469.9372 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-712: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 713-1261: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220312T183955.7Z 8106.777728 363 1 49.73 2 44.77 210.81 79.45 65.59 0.00 1 0.00 1 0 33 2.518e-03 2.443e-03 1.144e-03 1.126e-03 4.723639e+02 2.244192e+02 5.821242e+01 2.951650e+02 5.048627e+02 279.88 -2.00 20.00 -2.00 445.35 0.00e+00 4.043072e-04 1.241356e-04 1.970909e-06 1.155048e-05 2.759199e-04 279.88 -2.00 20.00 -2.00 454.93 0.00e+00 1.590527e-04 1.013955e-05 9.716234e-07 7.841720e-06 2.274226e-05 225.06 -2.00 2.11 -2.00 434.37 0.00e+00 1.980822e+06 1.606903e+05 1.692504e+04 1.813553e+05 3.634414e+05 261.49 -2.00 11.01 -2.00 458.12 0.00e+00 -1.915933e-01 3.220359e-02 9.213319e-04 7.802311e-03 7.850818e-02 226.47 -2.00 3.43 -2.00 454.29 0.00e+00 -7.987872e-06 4.118214e-06 3.792461e-07 9.094064e-07 9.619559e-06 279.88 -2.00 20.00 -2.00 455.73 0.00e+00 1.407 0.000 397.00 473.00 4 8.1251e+00 1.2016e-03 3.5866e-03 3.1003e-04 2.5561e-03 5.2081e-02 1.4207e-03 7.4887e-04 1.7869e-04 3.1664e-03 -1.8571e-02 8.3380e-04 9.8877e-05 7.1962e-05 1.8405e-03 -6.3638e-04 2.7364e-04 3.5638e-05 1.8624e-05 6.0984e-04 1.9779e-03 1.3899e-04 2.7003e-05 1.0592e-05 3.0705e-04 4.3212e-04 4.4107e-03 7.9900e-04 1.7661e-05 2.4958e-05 1.5672e-03 -3.7439e-05 1.2348e-05 2.6687e-07 2.6815e-07 2.6452e-05 -3.3499e-05 1.6013e-05 2.8380e-07 3.1665e-07 3.5609e-05 1.1655e-03 -1.7574e-04 1.0949e+00 1.1274e-01 1.2614e-03 1.3913e-03 2.3698e-01 12 9 8 11 32 0 99.90 20.15 2.16 0.00117 0.00319 14 3 1 4 0 3551.760 24.14 20.00 20.15 7.42 18.2 1000.83 386 54 99 -21 -375 275 137 313 -213 294 15 -41 240 -48 232 268 -95 -59 -153 -189 -88 278 -109 -183 -530 -136 770 -205 -119 45 -103 -384 -79 -70 -207 -464 40 181 -15 528 261 -55 285 571 411 -715 -84 337 -293 -266 217 155 -558 281 116 -427 -584 291 -385 -149 -225 -82 -57 113 -23 -201 -197 -55 122 110 151 -124 77 -232 -258 -242 147 -237 -194 -379 -404 165 145 -149 -46 333 -478 288 664 263 564 -221 37 103 190 -34 -105 53 -50 -250 -235 -406 -78 -68 91 132 -12 -205 126 31 -413 -219 -123 361 51 -328 194 103 -220 80 -36 103 292 -389 284 121 170 509 -203 -91 -6 377 119 -538 -164 -203 457 -348 -133 -185 93 -117 315 487 -14 252 2 -19 100 34 209 127 -385 -280 27 591 -80 13 248 141 85 21 61 19 75 -106 -190 17 -185 -123 -122 -549 -242 86 -19 -285 -54 -120 235 203 310 216 26 91 158 -163 339 111 70 -163 139 -210 361 -378 106 440 -27 -246 -44 39 68 -44 -154 231 -107 232 -347 414 273 -309 -64 -5 -277 39 329 267 106 156 -6 -28 311 118 356 131 -270 259 91 -127 514 50 166 -189 -38 295 34 -160 566 388 731 1 450 553 -305 -54 102 204 27 176 -488 71 524 -20 -465 65 -105 -100 129 566 -412 381 -502 -331 498 -396 -478 94 88 -280 391 -591 -211 128 -326 44 361 -362 46 -378 -585 -67 -351 -183 -3 -244 -491 -318 12 -357 -433 130 106 -135 -195 259 20 140 437 -699 -513 52 147 258 -235 -269 38 339 -292 -266 -192 282 -9 -577 73 -16 -265 626 360 -333 140 -52 155 115 -254 -188 -72 -316 -215 217 -35 -46 294 -178 315 -163 -233 -643 -26 -46 193 -145 -306 391 450 71 -23 -29 509 -139 -110 -254 -121 -239 9 -86 -198 -264 -54 330 183 86 192 273 -288 -689 0 -321 56 -117 76 411 11 262 -36 214 125 -203 240 34 121 383 104 53 -401 74 215 9 -145 203 107 360 -563 -27 30 36 -11 402 171 -61 199 119 254 3 43 371 -85 -3 475 121 111 57 129 -7 187 99 65 74 -190 331 65 38 150 272 -31 105 496 60 100 186 -102 -422 -200 -132 39 -98 -53 138 -144 -261 -215 49 36 202 16 28 -64 64 -197 44 -157 -337 -323 -57 -355 312 -273 -144 271 180 21 -123 -8 -206 -360 104 14 45 177 -213 -77 66 -168 -46 233 -234 54 64 104 -136 74 180 -176 146 -18 424 -17 -135 85 63 -60 -5 106 224 10 61 368 357 -196 -5 87 -267 -156 -29 -6 -288 5 -94 -264 -145 -191 18 16 -194 -104 197 93 252 -282 -202 365 -165 -83 -251 -83 -159 38 -3 -190 -134 163 -96 421 33 -13 340 -175 -200 264 11 142 369 -59 -202 322 -51 93 -250 -107 -45 24 366 50 89 -19 -340 245 128 300 -200 277 14 -40 232 -47 226 255 -91 -57 -146 -183 -85 267 -101 -166 -472 -124 713 -202 -117 44 -101 -375 -74 -63 -185 -428 38 178 -15 515 248 -53 267 535 391 -681 -78 312 -268 -245 204 151 -542 270 112 -408 -555 271 -356 -140 -221 -81 -56 112 -23 -205 -201 -57 126 112 155 -124 75 -226 -238 -217 130 -209 -171 -348 -398 162 144 -149 -47 332 -494 300 686 269 568 -222 37 104 192 -34 -105 55 -50 -245 -227 -393 -77 -68 95 136 -13 -208 126 30 -409 -216 -124 365 52 -327 189 103 -218 79 -35 104 294 -402 294 125 172 523 -207 -91 -6 367 114 -520 -156 -197 446 -342 -130 -181 91 -113 300 464 -13 249 2 -19 98 34 197 120 -361 -264 25 566 -77 13 252 145 88 21 62 19 74 -104 -186 18 -185 -126 -119 -508 -212 76 -17 -265 -52 -120 232 193 296 205 25 85 153 -162 329 108 69 -156 132 -198 342 -353 100 423 -26 -233 -41 37 62 -42 -149 229 -105 226 -320 366 239 -269 -55 -5 -261 38 317 255 100 147 -5 -26 284 105 313 117 -245 232 81 -112 433 40 127 -145 -29 222 25 -122 416 282 541 1 372 495 -288 -54 103 207 27 167 -441 63 452 -18 -428 62 -105 -98 126 560 -393 345 -432 -274 416 -337 -425 87 83 -275 383 -572 -198 120 -307 41 347 -355 45 -370 -581 -67 -349 -182 -3 -242 -481 -306 12 -343 -409 122 101 -128 -186 247 18 123 369 -604 -451 47 137 242 -223 -250 36 324 -284 -260 -186 267 -8 -535 67 -15 -246 583 343 -330 139 -51 149 109 -244 -186 -71 -315 -212 216 -35 -46 286 -175 307 -158 -228 -623 -25 -44 186 -143 -304 381 432 69 -22 -29 512 -138 -108 -253 -117 -224 9 -79 -180 -243 -50 308 169 82 180 259 -273 -656 0 -313 54 -115 75 409 11 252 -34 203 119 -195 235 33 119 368 99 50 -385 70 207 9 -142 201 106 362 -565 -28 31 37 -11 409 173 -61 203 120 254 3 44 373 -86 -3 470 120 108 55 122 -7 177 94 63 72 -183 325 65 39 154 279 -32 106 495 61 101 185 -101 -423 -201 -134 40 -102 -55 144 -152 -275 -230 51 38 212 17 30 -68 69 -211 47 -171 -367 -346 -62 -376 323 -283 -154 291 191 23 -134 -9 -222 -396 113 15 49 192 -233 -84 72 -185 -51 260 -266 62 74 119 -156 84 203 -200 165 -21 482 -19 -156 98 72 -69 -5 122 266 11 73 434 420 -229 -6 100 -308 -181 -33 -6 -332 6 -108 -301 -166 -222 21 19 -231 -124 234 109 298 -339 -242 427 -196 -95 -289 -94 -181 44 -3 -224 -161 195 -116 501 40 -15 394 -205 -237 315 13 171 442 -71 -241 384 -61 113 -294 -129 -53 28 SQ 20220312T221735.7Z 8106.928885 484 1 51.57 2 80.45 258.76 38.41 94.24 0.00 1 0.00 1 0 33 3.141e-03 2.905e-03 1.340e-03 1.265e-03 -1.621691e+02 2.460787e+02 1.746480e+01 2.952616e+02 6.310167e+02 279.88 -2.00 20.00 -2.00 447.57 0.00e+00 2.555965e-04 1.448312e-04 4.285733e-06 1.212561e-05 3.392310e-04 279.88 -2.00 20.00 -2.00 456.70 0.00e+00 6.016332e-04 1.137471e-05 3.879964e-06 7.841615e-06 2.842627e-05 225.23 -2.00 2.11 -2.00 438.72 0.00e+00 3.760274e+06 1.748911e+05 1.127822e+04 1.813057e+05 4.535501e+05 261.50 -2.00 11.01 -2.00 459.10 0.00e+00 5.282239e-01 3.333311e-02 3.707218e-03 7.697348e-03 9.758592e-02 226.48 -2.00 3.43 -2.00 455.99 0.00e+00 -1.444754e-05 4.318089e-06 6.945862e-07 9.156756e-07 1.199583e-05 279.88 -2.00 20.00 -2.00 456.97 0.00e+00 5.744 0.003 397.00 473.00 4 7.2654e+00 1.3798e-03 1.4664e-02 3.1408e-04 3.1864e-03 8.9795e-02 1.7282e-03 3.0620e-03 1.9059e-04 4.0576e-03 -2.7472e-02 9.3925e-04 4.0342e-04 7.4622e-05 2.1952e-03 2.9203e-03 3.2432e-04 7.1695e-05 1.8667e-05 7.6144e-04 6.3403e-04 1.6622e-04 4.8018e-05 1.1370e-05 3.8242e-04 3.4448e-04 -1.0176e-02 8.4142e-04 3.2231e-05 2.5085e-05 1.7943e-03 -8.3313e-05 1.3789e-05 6.2516e-07 2.7035e-07 3.2986e-05 5.5613e-06 1.8682e-05 6.2953e-07 3.4568e-07 4.4436e-05 5.1143e-03 -1.9722e-04 1.3583e+00 1.3162e-01 2.1130e-03 1.4355e-03 2.9305e-01 12 9 8 11 32 0 98.68 20.07 1.68 0.00511 0.00281 15 3 1 4 0 3437.040 24.14 20.00 20.07 6.48 18.0 1008.83 525 387 9 -355 -99 131 423 125 -176 496 -771 448 157 85 328 -113 -378 -323 -248 -77 -55 184 -174 162 -770 -511 988 -77 -131 -82 242 -458 -653 -182 -32 -561 -125 394 87 -34 605 -233 701 677 498 -493 227 520 -601 -389 600 225 -397 292 218 -65 -1069 372 -473 -62 -334 40 -28 475 29 54 -113 -153 -61 472 280 -168 283 -496 -117 125 -475 -262 -281 -336 -316 105 -77 41 -106 366 -1061 129 120 505 884 -227 -546 116 156 40 -29 128 -108 -311 -270 -96 -184 -342 14 -161 -83 -219 597 -3 -794 -588 7 400 92 -281 166 302 -237 269 28 174 588 -349 643 64 445 967 91 -291 344 60 -26 -430 -356 -91 243 -380 -388 -229 -209 -317 453 405 11 71 -30 -68 192 1150 257 -5 -240 674 223 520 -286 93 -50 259 -298 -376 209 228 44 140 -265 222 -234 289 -174 -392 -109 -16 -146 -84 -94 -63 -781 88 310 194 99 67 103 29 248 287 -28 -147 -82 -620 483 -762 157 573 85 -610 -141 260 -184 16 -18 -6 167 55 -336 -404 280 -170 -207 202 -305 -147 96 110 -161 208 386 90 168 205 61 120 -431 429 -125 -294 698 -484 -14 -504 303 -206 72 -333 578 553 423 -3 144 555 -121 -296 -48 474 -305 214 -395 -113 440 -11 -361 262 90 122 -96 209 -429 517 -592 -488 312 -373 -520 325 -14 -187 289 -367 99 153 -175 -237 473 -357 186 -398 -316 -125 -145 -233 -424 -29 -414 -299 56 -499 -457 286 98 -8 -169 175 208 458 721 -376 -307 72 185 204 -108 -196 280 292 -91 31 168 241 104 -469 464 104 -216 984 120 -77 349 -19 -46 205 -430 -37 -202 -368 -383 -89 181 -34 351 -173 64 40 68 -634 -58 268 125 -115 -152 22 -26 242 -149 -71 427 -4 22 -446 362 -112 -45 -192 -259 -325 -179 352 -398 216 213 -177 -577 1856 -260 -339 63 -61 75 210 -57 235 -214 49 -15 -693 -84 187 145 328 -119 92 -166 34 237 -342 -94 211 26 441 -215 75 -258 -144 -57 477 36 183 205 142 131 42 -50 -24 143 -57 121 327 257 -177 162 101 250 -35 305 -77 -342 307 -123 148 5 -118 137 211 485 -8 -10 88 305 -409 -66 -78 181 -303 -423 268 -277 -468 -176 -153 17 108 20 -48 -322 -67 -284 52 23 28 -73 -189 -290 599 -103 -232 84 120 -11 -84 69 -324 64 -69 -26 59 0 -415 229 -124 -379 -52 58 -180 134 -14 -29 -273 246 73 187 268 57 -4 8 -41 -18 233 -158 222 -19 163 -96 44 -76 537 -121 202 180 -288 70 5 76 -206 -82 -59 -344 -59 11 126 12 -41 -251 415 -143 134 -167 -161 235 -128 42 -238 52 172 -54 131 -2 -126 -43 -263 376 -82 90 337 -79 -216 91 80 -31 560 26 -168 31 -72 36 23 -271 -188 28 382 289 6 -252 -70 94 317 93 -133 375 -590 337 119 65 251 -88 -295 -251 -195 -61 -43 141 -133 118 -554 -377 761 -61 -107 -67 197 -359 -497 -135 -23 -425 -98 314 70 -27 486 -183 538 522 391 -387 173 402 -462 -302 468 183 -323 235 176 -52 -858 291 -369 -49 -277 33 -23 392 24 46 -100 -133 -53 417 243 -143 234 -415 -93 97 -354 -193 -216 -267 -258 88 -66 36 -93 315 -952 116 108 447 772 -198 -481 102 138 35 -25 110 -92 -269 -230 -81 -155 -302 13 -147 -75 -197 513 -2 -683 -520 6 363 83 -251 146 262 -205 235 25 154 534 -327 602 60 408 871 82 -256 304 52 -22 -370 -312 -79 211 -333 -340 -201 -182 -274 387 348 9 63 -27 -61 176 1013 219 -4 -205 575 189 455 -252 85 -46 241 -282 -357 196 211 40 126 -241 205 -214 270 -157 -337 -89 -13 -118 -74 -85 -57 -702 79 269 167 86 59 94 26 226 262 -25 -133 -72 -540 422 -683 142 509 76 -538 -125 227 -163 15 -17 -6 153 51 -291 -339 232 -139 -170 176 -271 -134 87 100 -144 185 341 78 147 174 52 103 -366 368 -108 -252 571 -372 -11 -367 220 -152 53 -241 403 381 299 -2 113 471 -111 -286 -47 467 -295 199 -351 -96 365 -10 -329 247 86 118 -93 198 -406 465 -509 -405 254 -308 -450 291 -13 -177 274 -343 93 140 -160 -222 442 -342 180 -392 -306 -124 -145 -234 -422 -28 -401 -285 54 -477 -430 267 93 -7 -161 167 191 403 612 -327 -271 64 172 191 -103 -188 263 280 -89 31 163 231 97 -441 429 97 -204 934 117 -77 355 -19 -45 200 -426 -38 -205 -377 -389 -89 180 -35 353 -175 65 40 67 -638 -58 263 126 -119 -157 22 -27 243 -153 -71 436 -5 23 -453 367 -110 -43 -181 -243 -308 -171 339 -384 212 213 -179 -569 1838 -259 -344 65 -62 78 218 -59 240 -215 49 -15 -714 -86 193 149 332 -120 93 -168 34 241 -353 -98 222 27 472 -229 80 -282 -158 -63 518 39 197 218 154 140 45 -55 -27 156 -62 130 343 269 -181 167 104 256 -36 318 -80 -361 331 -133 162 5 -130 150 234 533 -9 -11 94 326 -441 -71 -85 199 -340 -484 311 -317 -535 -203 -175 19 123 23 -56 -375 -78 -333 61 27 33 -87 -222 -334 694 -120 -271 99 143 -13 -100 83 -384 78 -82 -31 71 0 -500 276 -151 -461 -63 71 -226 169 -18 -37 -347 310 92 236 338 73 -5 10 -52 -23 301 -205 287 -25 211 -124 57 -101 707 -159 263 233 -375 91 7 100 -270 -106 -77 -448 -77 14 164 15 -54 -333 550 -193 183 -231 -221 318 -170 56 -307 66 219 -70 174 -3 -170 -58 -356 505 -109 119 441 -105 -290 123 109 -42 759 35 -228 42 -99 49 32 -371 -254 37