File name: Pandora37s1_HamptonVA_20240509_L2Fit_fout2c5d20210730p1-8.txt File generation date: 20250725T195358.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Timothy Berkoff Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 37 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora37_OF_v6d20200313.txt Instrument calibration file used: Pandora37s1_CF_v5d20210730.txt Level 1 file used: Pandora37s1_HamptonVA_20240509_L1_smca1c5d20210730p1-8.txt Full location name: Langley Research Center Short location name: HamptonVA Country of location: USA Location latitude [deg]: 37.1036 Location longitude [deg]: -76.3868 Location altitude [m]: 4 Local noon date: 20240509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 252 394 Nominal wavelengths inside fitting window [nm]: 305.1189 305.2594 305.3998 305.5402 305.6806 305.8210 305.9613 306.1017 306.2421 306.3824 306.5227 306.6630 306.8034 306.9436 307.0839 307.2242 307.3645 307.5047 307.6449 307.7852 307.9254 308.0656 308.2058 308.3459 308.4861 308.6263 308.7664 308.9065 309.0467 309.1868 309.3269 309.4670 309.6070 309.7471 309.8871 310.0272 310.1672 310.3072 310.4472 310.5872 310.7272 310.8672 311.0071 311.1471 311.2870 311.4269 311.5668 311.7067 311.8466 311.9865 312.1263 312.2662 312.4060 312.5459 312.6857 312.8255 312.9653 313.1050 313.2448 313.3846 313.5243 313.6640 313.8038 313.9435 314.0832 314.2229 314.3625 314.5022 314.6419 314.7815 314.9211 315.0607 315.2003 315.3399 315.4795 315.6191 315.7586 315.8982 316.0377 316.1772 316.3167 316.4562 316.5957 316.7352 316.8747 317.0141 317.1536 317.2930 317.4324 317.5718 317.7112 317.8506 317.9899 318.1293 318.2686 318.4080 318.5473 318.6866 318.8259 318.9652 319.1045 319.2437 319.3830 319.5222 319.6614 319.8006 319.9398 320.0790 320.2182 320.3574 320.4965 320.6357 320.7748 320.9139 321.0530 321.1921 321.3312 321.4703 321.6093 321.7484 321.8874 322.0264 322.1654 322.3044 322.4434 322.5824 322.7214 322.8603 322.9993 323.1382 323.2771 323.4160 323.5549 323.6938 323.8326 323.9715 324.1103 324.2492 324.3880 324.5268 324.6656 324.8044 324.9432 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240509T114156.0Z 8895.487453 73 1 50.13 2 71.71 81.46 81.68 64.86 0.00 1 0.00 1 0 25 6.051e-02 6.679e-03 2.052e-02 1.762e-03 4.603031e-01 9.005459e-04 5.261626e-03 -6.000000e+00 3.477025e-02 230.90 -2.00 3.43 -2.00 319.24 0.00e+00 1.394666e-03 2.303267e-04 1.800351e-04 -6.000000e+00 1.536077e-03 285.45 -2.00 20.00 -2.00 318.49 0.00e+00 3.145 0.000 302.00 328.00 3 3.5491e+00 2.5270e-03 3.9571e-02 -6.0000e+00 8.6982e-02 3.7654e-02 2.9494e-03 2.3799e-02 -6.0000e+00 9.4174e-02 -3.0528e-02 2.2277e-03 1.1640e-02 -6.0000e+00 5.6025e-02 5.2916e-03 1.1725e-03 3.5751e-03 -6.0000e+00 2.3832e-02 3.6783e-04 -4.5632e-04 4.9226e-05 3.5789e-05 -6.0000e+00 1.6158e-03 -9.1309e-03 0.0000e+00 11 8 0 10 0 0 99.99 21.50 0.22 -0.00913 -0.01256 67 13 1 5 0 748.150 25.39 20.01 21.50 29.52 31.6 1008.20 -19273 -41663 -12795 -14673 -13565 17821 -6247 -13628 -9652 -16267 -22650 19682 5814 -9524 -3769 -4922 4877 2822 -1418 -1468 -2750 971 -2971 -3959 -4452 3990 -7303 -991 -5610 -2475 2178 1992 -2190 -3188 -2236 -952 -2216 4535 2487 -1389 -196 -644 -569 -1108 -821 -830 1113 625 573 1563 1869 1084 1582 1797 1792 1563 402 -967 -390 557 1293 342 1271 1803 1549 -70 626 -3584 3175 214 -193 344 -236 -257 -573 -702 -820 559 -394 -1176 -796 -1470 -1997 -796 -913 -206 -625 -304 329 272 861 533 815 1542 341 966 365 -13 -394 -407 -588 -260 527 -19 -988 -586 -844 -385 167 841 -10 -201 292 337 426 721 841 302 -33 -855 -857 -147 241 -50 136 -222 1090 1097 -40 150 -31 -119 128 90 -366 -306 232 143 -61 -171 -127 -375 230 -505 -1459 -358 -392 -333 335 -158 -415 -313 -586 -880 585 231 -519 -229 -339 331 209 -115 -125 -240 82 -273 -395 -475 411 -831 -102 -585 -264 252 260 -329 -495 -327 -139 -363 822 550 -366 -56 -193 -176 -349 -260 -266 351 200 186 524 675 427 661 794 822 739 196 -473 -186 263 626 180 726 1100 957 -42 361 -2160 1955 150 -146 266 -182 -190 -399 -450 -494 330 -252 -849 -637 -1288 -1858 -763 -921 -217 -685 -339 366 294 879 515 751 1415 337 1037 430 -17 -531 -546 -756 -312 599 -22 -1217 -747 -1115 -526 238 1267 -16 -329 471 525 632 1032 1202 446 -51 -1376 -1386 -233 374 -76 201 -318 1503 1529 -59 238 -52 -204 224 163 -687 -594 456 286 -123 -336 -242 -697 417 SS 20240509T124919.2Z 8895.534250 113 1 49.96 2 58.31 91.26 69.49 73.27 0.00 1 0.00 1 0 25 9.078e-03 5.956e-03 9.297e-04 3.825e-04 2.872445e-01 1.950105e-04 3.384982e-03 -6.000000e+00 5.215977e-03 230.90 -2.00 3.43 -2.00 316.67 0.00e+00 3.216544e-04 2.395176e-05 5.124552e-05 -6.000000e+00 2.304672e-04 285.45 -2.00 20.00 -2.00 315.91 0.00e+00 1.897 0.000 302.00 328.00 3 2.2180e+00 5.1301e-04 2.4128e-02 -6.0000e+00 1.3048e-02 8.6806e-03 5.7380e-04 1.4650e-02 -6.0000e+00 1.4128e-02 -1.5147e-02 3.3517e-04 7.1288e-03 -6.0000e+00 8.4049e-03 2.7239e-03 1.5990e-04 1.9758e-03 -6.0000e+00 3.5747e-03 6.0161e-03 -4.0524e-04 1.0701e-05 2.2688e-05 -6.0000e+00 2.4243e-04 -8.1838e-03 0.0000e+00 10 0 0 10 0 0 97.25 21.51 0.30 -0.00818 -0.01123 382 77 1 5 0 130.780 25.39 20.01 21.51 30.71 31.5 1008.67 -947 -2703 -1892 -3757 -2289 -2146 -489 -539 -1381 -2049 -2365 -213 -684 700 142 33 412 970 643 1087 49 1129 1090 685 563 -242 -579 -638 -95 842 1343 1603 162 -2032 -1367 -1254 -729 335 -451 -799 -798 -436 -789 -318 -132 -622 -460 -433 -418 759 871 725 1067 577 883 849 391 436 596 900 1330 1238 1255 597 -410 21 -243 1003 1327 -42 -223 -253 -318 -139 -366 -82 -280 206 272 -902 -997 -1666 -1930 -1054 -894 -655 -486 -313 53 110 408 295 754 1393 674 312 445 294 -488 -548 -466 -208 642 315 -962 -693 -587 -440 323 207 1 -109 161 219 521 904 627 467 119 -476 -686 -283 -47 109 505 -50 778 1419 526 254 -43 -92 266 245 -126 -320 -26 -8 -332 -258 -246 -416 76 -143 -445 -309 -569 -307 -285 -70 -87 -248 -381 -435 -41 -140 163 38 9 116 285 197 344 16 357 358 240 208 -87 -206 -226 -31 279 478 581 65 -834 -518 -476 -306 155 -239 -466 -503 -285 -506 -204 -84 -398 -303 -280 -266 486 564 506 747 428 672 661 311 344 460 689 1052 1012 1068 545 -374 17 -199 796 1136 -38 -220 -249 -311 -135 -331 -72 -224 165 220 -802 -959 -1711 -2037 -1156 -1011 -763 -596 -381 64 133 471 323 783 1402 727 347 532 377 -646 -715 -588 -249 745 378 -1186 -900 -770 -605 449 298 2 -165 234 317 712 1194 826 622 165 -687 -1015 -412 -66 152 690 -65 992 1796 694 351 -64 -135 395 366 -196 -524 -43 -13 -560 -425 -401 -653 119 SS 20240509T130253.8Z 8895.543678 116 1 28.58 2 55.61 93.38 66.96 74.91 0.00 1 0.00 1 0 25 8.326e-03 5.924e-03 1.149e-03 5.412e-04 2.675318e-01 2.765272e-04 3.162322e-03 -6.000000e+00 4.784692e-03 230.90 -2.00 3.43 -2.00 316.33 0.00e+00 2.998317e-04 3.141224e-05 4.342818e-05 -6.000000e+00 2.113626e-04 285.45 -2.00 20.00 -2.00 315.59 0.00e+00 1.765 0.000 302.00 328.00 3 2.5194e+00 7.2307e-04 2.2454e-02 -6.0000e+00 1.1970e-02 9.4520e-03 8.0680e-04 1.3627e-02 -6.0000e+00 1.2959e-02 -1.3187e-02 4.6692e-04 6.6342e-03 -6.0000e+00 7.7095e-03 2.1765e-03 2.1918e-04 1.8397e-03 -6.0000e+00 3.2797e-03 5.2221e-03 -3.2358e-04 1.5096e-05 2.1562e-05 -6.0000e+00 2.2233e-04 -9.6245e-03 0.0000e+00 12 1 1 12 1 1 99.90 21.57 0.33 -0.00962 -0.01206 162 57 1 5 0 175.320 25.47 20.03 21.57 32.26 31.4 1008.60 -1877 -1496 -2354 -3068 -2021 -1774 271 -324 -276 -1815 -1666 -106 -72 66 152 -343 525 524 859 905 -93 1133 1210 908 215 -63 -503 -285 -204 1139 1161 1793 155 -1960 -1053 -1189 -582 283 -82 -855 -768 -465 -717 -651 -173 -594 -482 -562 -223 872 924 796 1006 627 832 829 397 494 468 934 1299 1215 1236 512 -392 -105 -160 252 1331 -49 -201 -215 -313 -104 -377 -30 -63 230 208 -666 -923 -1566 -1843 -988 -958 -638 -468 -433 23 -38 525 194 878 1296 649 299 497 198 -371 -512 -542 -178 624 397 -1018 -733 -641 -396 320 202 53 -104 86 264 518 865 696 493 97 -505 -659 -318 25 159 500 -11 796 1425 508 255 -70 -103 279 334 -129 -325 -79 20 -331 -237 -311 -438 10 -347 -294 -466 -556 -325 -281 46 -62 -58 -400 -361 -24 -17 18 44 -108 170 177 300 326 -34 408 450 337 85 -26 -201 -113 -76 419 458 715 68 -882 -436 -493 -266 143 -47 -541 -498 -313 -496 -452 -119 -410 -325 -370 -144 564 635 587 745 490 637 649 317 391 363 752 1031 1042 1102 467 -356 -91 -135 208 1121 -46 -196 -218 -315 -100 -352 -26 -52 189 173 -602 -901 -1630 -1969 -1096 -1097 -753 -562 -535 29 -46 613 215 920 1313 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