File name: Pandora133s1_Heidelberg_20250913_L2Fit_fout2c4d20240611p1-8.txt File generation date: 20250913T233027.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Andre Butz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 133 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora133_OF_v2d20240405.txt Instrument calibration file used: Pandora133s1_CF_v4d20240611.txt Level 1 file used: Pandora133s1_Heidelberg_20250913_L1_smca1c4d20240611p1-8.txt Full location name: Institute of Environmental Physics, Heidelberg University Short location name: Heidelberg Country of location: Germany Location latitude [deg]: 49.4173 Location longitude [deg]: 8.6746 Location altitude [m]: 144 Local noon date: 20250913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1331 305.2741 305.4152 305.5562 305.6973 305.8383 305.9793 306.1203 306.2613 306.4023 306.5432 306.6842 306.8251 306.9661 307.1070 307.2479 307.3888 307.5297 307.6705 307.8114 307.9523 308.0931 308.2339 308.3747 308.5155 308.6563 308.7971 308.9379 309.0787 309.2194 309.3601 309.5009 309.6416 309.7823 309.9230 310.0636 310.2043 310.3450 310.4856 310.6262 310.7669 310.9075 311.0481 311.1886 311.3292 311.4698 311.6103 311.7509 311.8914 312.0319 312.1724 312.3129 312.4534 312.5939 312.7343 312.8748 313.0152 313.1556 313.2960 313.4364 313.5768 313.7172 313.8576 313.9979 314.1383 314.2786 314.4189 314.5592 314.6995 314.8398 314.9801 315.1203 315.2606 315.4008 315.5410 315.6813 315.8215 315.9617 316.1018 316.2420 316.3822 316.5223 316.6624 316.8026 316.9427 317.0828 317.2229 317.3629 317.5030 317.6431 317.7831 317.9231 318.0631 318.2031 318.3431 318.4831 318.6231 318.7631 318.9030 319.0429 319.1829 319.3228 319.4627 319.6026 319.7424 319.8823 320.0222 320.1620 320.3018 320.4417 320.5815 320.7213 320.8611 321.0008 321.1406 321.2803 321.4201 321.5598 321.6995 321.8392 321.9789 322.1186 322.2583 322.3979 322.5376 322.6772 322.8168 322.9564 323.0960 323.2356 323.3752 323.5148 323.6543 323.7939 323.9334 324.0729 324.2124 324.3519 324.4914 324.6309 324.7703 324.9098 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250913T085741.3Z 9387.373394 311 1 5.13 2 54.96 134.41 59.42 275.21 0.00 1 0.00 1 0 17 1.800e-02 9.652e-03 8.963e-03 4.032e-03 2.260471e-01 2.063511e-03 2.823816e-03 -6.000000e+00 1.042124e-02 229.07 -2.00 3.74 -2.00 316.48 0.00e+00 9.072439e-04 2.404715e-04 1.711708e-04 -6.000000e+00 4.533322e-04 281.38 -2.00 20.00 -2.00 315.80 0.00e+00 1.737 0.000 302.00 328.00 3 4.8486e+00 5.3881e-03 2.1030e-02 -6.0000e+00 2.5983e-02 2.3355e-02 6.0183e-03 1.2206e-02 -6.0000e+00 2.8148e-02 3.0774e-03 3.5078e-03 5.9555e-03 -6.0000e+00 1.6731e-02 -6.8727e-03 1.6584e-03 1.7675e-03 -6.0000e+00 7.1496e-03 5.8074e-04 2.3060e-03 1.1656e-04 1.8805e-05 -6.0000e+00 4.9246e-04 -7.0106e-03 0.0000e+00 12 9 9 12 1 1 94.04 22.59 0.12 -0.00701 0.01032 3 10 1 8 0 1278.350 20.02 22.59 22.31 26.41 26.73 1.7 883.41 -1016 4247 -2377 5236 -5161 1175 -4530 3618 -426 -1751 -4497 -165 -1969 1719 -457 551 292 2473 934 1641 -10399 2855 1714 822 -1269 160 -2018 -399 -1006 4736 745 2948 -1051 -2847 -3673 -1843 -2096 68 534 -852 -1404 197 -331 -456 902 -104 -1135 -616 -624 1281 2023 1346 1583 -177 1267 1653 576 1270 482 1001 -67 2278 2500 1374 -148 -732 -1518 75 785 648 856 954 1047 224 -648 -835 -2088 -1938 -1614 -1405 -1779 -1933 -2023 -1554 -414 -562 416 776 964 335 530 -658 -370 -41 -646 -161 535 518 271 -276 -904 -1484 -701 -665 -1365 -634 -264 -415 582 666 1211 105 124 -590 -252 763 -358 752 1208 398 434 536 1221 380 598 -666 526 -104 525 -242 -210 -620 -346 526 42 -255 496 -116 344 -58 -576 -1228 -182 762 -439 815 -814 179 -792 645 -85 -354 -919 -35 -475 451 -134 168 91 791 311 558 -3866 961 601 302 -490 62 -772 -141 -346 1603 273 1134 -435 -1156 -1437 -743 -942 34 305 -536 -921 131 -224 -309 605 -70 -748 -398 -401 835 1369 954 1163 -136 972 1285 451 984 372 783 -55 1944 2238 1258 -130 -613 -1238 62 692 613 839 947 1023 211 -578 -692 -1660 -1548 -1382 -1298 -1770 -2025 -2179 -1742 -482 -679 511 965 1179 394 589 -694 -376 -42 -706 -188 663 674 352 -348 -1096 -1730 -820 -819 -1754 -835 -357 -579 833 984 1807 156 177 -802 -327 975 -470 1021 1716 577 631 771 1707 517 792 -862 671 -137 718 -343 -305 -912 -516 805 67 -413 814 -194 565 -94 -916 -1935 SS 20250913T090209.1Z 9387.376494 313 1 2.11 2 54.45 135.62 60.12 275.99 0.00 1 0.00 1 0 17 1.271e-02 8.347e-03 1.062e-02 4.936e-03 2.217680e-01 2.527952e-03 2.831567e-03 -6.000000e+00 7.340916e-03 229.06 -2.00 3.74 -2.00 316.42 0.00e+00 9.026699e-04 2.888097e-04 9.431598e-05 -6.000000e+00 3.201054e-04 281.38 -2.00 20.00 -2.00 315.73 0.00e+00 1.715 0.000 302.00 328.00 3 4.2871e+00 6.5921e-03 2.0816e-02 -6.0000e+00 1.8301e-02 1.8149e-02 7.3578e-03 1.2163e-02 -6.0000e+00 1.9841e-02 4.5121e-03 4.2784e-03 5.9430e-03 -6.0000e+00 1.1794e-02 -6.4654e-03 2.0150e-03 1.7356e-03 -6.0000e+00 5.0267e-03 1.0489e-03 -1.0487e-04 1.4258e-04 1.9802e-05 -6.0000e+00 3.4781e-04 9.5958e-03 0.0000e+00 12 9 1 12 1 1 999.00 22.60 0.24 0.00960 0.00881 2 19 1 8 0 698.520 20.01 22.60 22.65 26.51 26.73 1.6 884.76 -1728 3157 -940 -3679 -2626 159 2081 862 -1515 -2220 -2149 -3424 -233 270 -89 -169 85 623 1759 3354 288 1955 836 2010 -694 152 -514 -684 -2489 1746 -710 596 -51 -3506 -4455 -1891 -2151 -753 -697 401 -1913 -445 1123 641 882 -509 554 -827 -1536 321 530 251 2304 807 990 1053 194 686 -203 272 267 2547 1526 661 -1099 -1245 -1485 -56 1391 784 1084 708 541 1152 -160 -1319 -873 -1856 20 -1177 -876 -1250 -2240 -671 -842 -336 -97 905 712 687 817 -906 -702 -83 -457 419 1276 856 -143 -623 -355 -1860 -383 -1087 -1288 -950 -852 89 361 741 726 641 308 -279 263 -119 -61 389 587 73 17 421 603 303 1152 -272 773 380 -92 361 -440 -758 -634 378 2 -281 532 -164 280 206 -338 -1012 -323 595 -180 -647 -421 26 354 164 -316 -467 -449 -775 -57 74 -27 -54 27 208 599 1154 101 678 304 756 -273 61 -199 -248 -886 621 -271 238 -21 -1464 -1798 -779 -983 -388 -409 254 -1272 -301 762 435 597 -347 365 -542 -1007 213 366 181 1696 617 768 830 154 536 -159 215 220 2189 1379 610 -984 -1052 -1218 -47 1227 747 1068 705 533 1085 -142 -1106 -692 -1492 17 -1089 -870 -1306 -2422 -749 -988 -407 -120 1123 873 810 908 -958 -716 -86 -499 485 1575 1105 -186 -787 -429 -2174 -447 -1339 -1652 -1252 -1155 123 518 1093 1086 942 437 -376 340 -152 -80 526 832 105 24 603 844 413 1518 -350 981 499 -126 508 -637 -1104 -943 578 3 -455 871 -270 457 331 -536 -1579 SS 20250913T090710.5Z 9387.379983 316 1 46.49 2 53.89 137.00 60.90 276.86 0.00 1 0.00 1 0 17 1.126e-02 7.289e-03 6.474e-04 2.729e-04 2.206570e-01 1.398771e-04 2.815553e-03 -6.000000e+00 6.504050e-03 229.06 -2.00 3.74 -2.00 316.71 0.00e+00 6.452020e-04 1.707436e-05 1.372724e-04 -6.000000e+00 2.835404e-04 281.38 -2.00 20.00 -2.00 316.01 0.00e+00 1.692 0.000 302.00 328.00 3 1.8947e+00 3.6639e-04 2.0601e-02 -6.0000e+00 1.6215e-02 8.5661e-03 4.0986e-04 1.2084e-02 -6.0000e+00 1.7579e-02 -6.0223e-04 2.3987e-04 5.9127e-03 -6.0000e+00 1.0449e-02 -3.9072e-03 1.1399e-04 1.6812e-03 -6.0000e+00 4.4543e-03 1.1838e-02 1.6053e-04 7.9490e-06 1.9177e-05 -6.0000e+00 3.0809e-04 8.3187e-03 0.0000e+00 11 8 0 10 0 0 99.99 22.62 0.15 0.00832 0.00952 1575 455 2 8 0 29.510 20.01 22.62 22.90 26.51 26.73 1.6 886.93 209 495 -1533 -3942 -3744 -2111 -320 174 38 -2588 -2938 -1014 -1025 518 971 231 534 955 1273 1448 -2300 934 1110 736 448 690 -882 -1500 -556 984 705 1968 670 -3205 -3375 -2317 -2151 -405 88 -464 -735 -131 -519 -242 26 -136 -407 -491 -903 742 668 855 1198 858 863 1166 523 304 99 710 1200 1787 2209 1388 -495 -168 -1246 -77 1072 616 558 559 501 448 -345 -817 -1850 -1222 -1070 -1387 -1250 -1858 -2093 -1067 -570 -78 240 886 697 482 438 -504 -584 -87 -291 94 980 638 -11 -134 -952 -1397 -530 -502 -1208 -731 -735 -349 487 743 775 338 292 -270 -126 -40 -106 346 554 -42 349 577 595 632 599 -375 636 500 60 54 -324 -383 -319 99 102 -113 584 243 -94 -118 -411 -1004 34 83 -254 -593 -565 -320 -52 29 7 -473 -530 -194 -222 125 261 66 156 288 395 461 -755 297 369 257 163 255 -317 -498 -175 313 240 708 258 -1227 -1217 -874 -922 -202 47 -281 -470 -86 -348 -162 17 -89 -259 -304 -553 462 444 598 879 657 619 849 385 238 77 559 920 1474 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