File name: Pandora133s1_Heidelberg_20250913_L2Fit_fwvt1c4d20240611p1-8.txt
File generation date: 20250913T232803.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c4p1-8
Local principal investigator: Andre Butz
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 133
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora133_OF_v2d20240405.txt
Instrument calibration file used: Pandora133s1_CF_v4d20240611.txt
Level 1 file used: Pandora133s1_Heidelberg_20250913_L1_smca1c4d20240611p1-8.txt
Full location name: Institute of Environmental Physics, Heidelberg University
Short location name: Heidelberg
Country of location: Germany
Location latitude [deg]: 49.4173
Location longitude [deg]: 8.6746
Location altitude [m]: 144
Local noon date: 20250913
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1646 1795
Nominal wavelengths inside fitting window [nm]: 492.1173 492.2384 492.3595 492.4806 492.6017 492.7227 492.8437 492.9648 493.0858 493.2067 493.3277 493.4487 493.5696 493.6905 493.8114 493.9323 494.0532 494.1740 494.2948 494.4157 494.5365 494.6572 494.7780 494.8988 495.0195 495.1402 495.2609 495.3816 495.5023 495.6229 495.7435 495.8641 495.9847 496.1053 496.2259 496.3464 496.4670 496.5875 496.7080 496.8285 496.9489 497.0694 497.1898 497.3102 497.4306 497.5510 497.6713 497.7917 497.9120 498.0323 498.1526 498.2729 498.3931 498.5134 498.6336 498.7538 498.8740 498.9942 499.1143 499.2345 499.3546 499.4747 499.5948 499.7149 499.8349 499.9550 500.0750 500.1950 500.3150 500.4350 500.5549 500.6748 500.7948 500.9147 501.0346 501.1544 501.2743 501.3941 501.5139 501.6337 501.7535 501.8733 501.9930 502.1128 502.2325 502.3522 502.4719 502.5915 502.7112 502.8308 502.9504 503.0700 503.1896 503.3092 503.4287 503.5482 503.6677 503.7872 503.9067 504.0262 504.1456 504.2650 504.3844 504.5038 504.6232 504.7426 504.8619 504.9812 505.1005 505.2198 505.3391 505.4584 505.5776 505.6968 505.8160 505.9352 506.0544 506.1735 506.2927 506.4118 506.5309 506.6500 506.7690 506.8881 507.0071 507.1261 507.2451 507.3641 507.4831 507.6020 507.7209 507.8399 507.9588 508.0776 508.1965 508.3153 508.4342 508.5530 508.6718 508.7905 508.9093 509.0280 509.1468 509.2655 509.3842 509.5028 509.6215 509.7401 509.8587 509.9773
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250913T065757.4Z 9387.290248 244 1 46.80 2 71.67 106.46 40.94 251.07 0.00 1 0.00 1 0 15 2.358e-03 2.347e-03 3.781e-04 3.774e-04 3.660157e+03 2.460558e+01 2.601360e+02 -6.000000e+00 1.384135e+02 281.39 -2.00 20.00 -2.00 505.27 0.00e+00 5.774339e-04 1.061972e-05 3.688406e-05 -6.000000e+00 6.751144e-05 281.39 -2.00 20.00 -2.00 500.52 0.00e+00 1.882277e-01 7.654982e-03 2.751426e-02 -6.000000e+00 4.812372e-02 229.07 -2.00 3.74 -2.00 502.10 0.00e+00 3.139 0.001 489.00 513.00 1 6.4718e+00 5.8906e-04 5.0649e-03 -6.0000e+00 3.7048e-03 6.9866e-03 1.4789e-04 6.9919e-04 -6.0000e+00 9.3877e-04 1.9012e-03 9.8273e-04 4.4746e-05 2.9185e-05 -6.0000e+00 2.9152e-04 1.5910e-02 -1.7484e-04 10 0 0 10 0 0 99.97 22.37 0.63 0.01591 0.02273 98 28 1 2 0 477.430 20.01 22.37 20.54 26.32 26.51 1.7 870.43 -305 -68 91 4 -18 377 486 459 334 253 208 35 -187 -139 -242 -366 -129 228 68 -13 3 142 126 379 327 188 282 3 -298 -360 -230 -304 -11 348 -21 -216 -146 -98 -142 -77 -105 -17 157 239 236 233 121 109 -7 -268 -459 -486 -594 -371 -196 -160 -98 -124 -81 88 318 347 231 198 183 69 95 115 -152 -210 -121 -105 -148 149 53 -320 -395 -206 -254 -216 -296 -261 -307 -103 -45 -204 -240 -14 13 -33 83 280 316 162 95 129 -7 -238 -277 -301 -489 -319 -72 59 -253 -329 -295 -192 -91 144 51 81 159 268 263 377 490 363 185 185 45 107 276 216 94 132 72 40 268 153 -134 -243 -259 -397 -21 209 72 -1 103 158 82 284 357 233 169 55 -267 -311 -289 -212 -297 -68 93 4 -18 391 510 483 350 262 213 35 -187 -138 -240 -367 -132 236 71 -14 3 152 128 388 335 192 298 3 -304 -361 -229 -306 -12 365 -21 -220 -148 -103 -148 -80 -110 -18 159 244 241 238 123 113 -7 -268 -449 -469 -574 -363 -196 -163 -102 -130 -84 88 317 346 231 197 188 70 95 114 -149 -204 -117 -103 -147 147 52 -315 -385 -198 -243 -207 -284 -253 -300 -102 -45 -203 -240 -14 13 -33 84 274 310 159 96 127 -6 -226 -259 -280 -459 -306 -71 60 -247 -321 -287 -194 -92 140 49 80 159 269 266 383 498 368 186 183 45 104 267 209 92 129 70 39 259 147 -127 -240 -253 -388 -21 208 70 -1 102 158 83 287 362 236 170 55 -262 -301 -278 -204
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SQ 20250913T080951.5Z 9387.340179 287 1 46.11 2 61.05 122.29 51.96 266.48 0.00 1 0.00 1 0 15 2.874e-03 2.870e-03 8.919e-04 8.909e-04 3.087926e+03 5.725597e+01 2.035031e+02 -6.000000e+00 1.687684e+02 281.38 -2.00 20.00 -2.00 505.28 0.00e+00 5.048793e-04 2.502447e-05 3.355809e-05 -6.000000e+00 8.231063e-05 281.38 -2.00 20.00 -2.00 500.53 0.00e+00 1.011649e-01 1.807024e-02 2.725760e-02 -6.000000e+00 5.864047e-02 229.07 -2.00 3.74 -2.00 502.11 0.00e+00 2.056 0.000 489.00 513.00 1 8.3270e+00 1.3902e-03 3.7496e-03 -6.0000e+00 4.5149e-03 4.6874e-03 3.4967e-04 6.2579e-04 -6.0000e+00 1.1431e-03 3.4905e-04 3.6955e-04 1.0627e-04 2.1132e-05 -6.0000e+00 3.5535e-04 1.0024e-02 -9.1497e-05 10 0 0 10 0 0 99.86 22.52 0.63 0.01002 0.01259 14 4 1 2 0 3293.070 20.00 22.52 20.89 26.41 26.62 1.6 870.46 -404 -207 209 -30 -509 380 364 326 298 334 219 -24 -57 -412 -267 -409 -64 245 89 74 -90 199 15 463 241 -41 118 -72 -317 -342 -213 -72 -101 483 -93 -72 121 -311 -156 465 73 -205 651 158 204 292 432 249 -114 -230 -431 -496 -723 -453 -227 40 -115 -196 -50 177 490 495 315 129 307 188 -48 207 -334 -245 -123 -302 -350 187 146 -201 -466 -60 -74 -320 -241 -481 -418 -41 -71 -127 -176 -203 164 -8 50 86 230 -92 61 241 -172 -404 -331 131 -497 -152 -120 184 -119 -437 -321 -63 -26 173 -53 84 398 153 567 461 398 568 163 122 60 -39 605 81 148 -162 88 34 299 126 -213 -281 67 -672 107 29 -14 114 100 19 79 253 619 -82 181 80 -372 -440 -311 -424 -393 -204 208 -30 -523 392 378 339 308 343 223 -24 -58 -415 -269 -414 -66 252 93 77 -94 208 16 483 252 -43 122 -74 -322 -344 -213 -72 -103 498 -97 -75 124 -321 -160 474 75 -211 671 165 211 303 446 253 -115 -229 -426 -486 -706 -445 -226 41 -117 -200 -51 180 499 505 320 131 310 188 -47 204 -330 -239 -120 -297 -345 184 144 -197 -455 -58 -72 -308 -233 -468 -407 -41 -69 -126 -174 -200 162 -8 49 85 230 -92 61 237 -167 -386 -313 123 -473 -146 -117 182 -119 -435 -317 -62 -26 172 -52 84 399 155 572 467 404 573 163 122 59 -39 593 80 146 -159 86 34 292 122 -208 -272 64 -646 103 28 -13 112 99 19 79 253 618 -83 180 79 -365 -428 -302 -414
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