File name: Pandora133s1_Heidelberg_20250914_L2Fit_fwvt1c4d20240611p1-8.txt
File generation date: 20250914T232443.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c4p1-8
Local principal investigator: Andre Butz
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 133
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora133_OF_v2d20240405.txt
Instrument calibration file used: Pandora133s1_CF_v4d20240611.txt
Level 1 file used: Pandora133s1_Heidelberg_20250914_L1_smca1c4d20240611p1-8.txt
Full location name: Institute of Environmental Physics, Heidelberg University
Short location name: Heidelberg
Country of location: Germany
Location latitude [deg]: 49.4173
Location longitude [deg]: 8.6746
Location altitude [m]: 144
Local noon date: 20250914
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1646 1795
Nominal wavelengths inside fitting window [nm]: 492.1173 492.2384 492.3595 492.4806 492.6017 492.7227 492.8437 492.9648 493.0858 493.2067 493.3277 493.4487 493.5696 493.6905 493.8114 493.9323 494.0532 494.1740 494.2948 494.4157 494.5365 494.6572 494.7780 494.8988 495.0195 495.1402 495.2609 495.3816 495.5023 495.6229 495.7435 495.8641 495.9847 496.1053 496.2259 496.3464 496.4670 496.5875 496.7080 496.8285 496.9489 497.0694 497.1898 497.3102 497.4306 497.5510 497.6713 497.7917 497.9120 498.0323 498.1526 498.2729 498.3931 498.5134 498.6336 498.7538 498.8740 498.9942 499.1143 499.2345 499.3546 499.4747 499.5948 499.7149 499.8349 499.9550 500.0750 500.1950 500.3150 500.4350 500.5549 500.6748 500.7948 500.9147 501.0346 501.1544 501.2743 501.3941 501.5139 501.6337 501.7535 501.8733 501.9930 502.1128 502.2325 502.3522 502.4719 502.5915 502.7112 502.8308 502.9504 503.0700 503.1896 503.3092 503.4287 503.5482 503.6677 503.7872 503.9067 504.0262 504.1456 504.2650 504.3844 504.5038 504.6232 504.7426 504.8619 504.9812 505.1005 505.2198 505.3391 505.4584 505.5776 505.6968 505.8160 505.9352 506.0544 506.1735 506.2927 506.4118 506.5309 506.6500 506.7690 506.8881 507.0071 507.1261 507.2451 507.3641 507.4831 507.6020 507.7209 507.8399 507.9588 508.0776 508.1965 508.3153 508.4342 508.5530 508.6718 508.7905 508.9093 509.0280 509.1468 509.2655 509.3842 509.5028 509.6215 509.7401 509.8587 509.9773
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250914T070322.6Z 9388.294012 238 1 46.60 2 71.08 107.90 31.38 237.82 0.00 1 0.00 1 0 15 2.811e-03 2.802e-03 9.520e-04 9.508e-04 3.370355e+03 6.155839e+01 2.305100e+02 -6.000000e+00 1.649846e+02 281.30 -2.00 20.00 -2.00 505.28 0.00e+00 5.183961e-04 2.671437e-05 3.453013e-05 -6.000000e+00 8.047984e-05 281.30 -2.00 20.00 -2.00 500.53 0.00e+00 2.929495e-01 1.929709e-02 2.765393e-02 -6.000000e+00 5.735707e-02 228.96 -2.00 3.74 -2.00 502.11 0.00e+00 3.046 0.001 489.00 513.00 1 8.2894e+00 1.4847e-03 4.9330e-03 -6.0000e+00 4.4158e-03 7.0858e-03 3.7301e-04 6.7660e-04 -6.0000e+00 1.1184e-03 3.1086e-04 1.0078e-03 1.1334e-04 2.4365e-05 -6.0000e+00 3.4755e-04 1.2317e-02 -1.2489e-04 10 0 0 10 0 0 99.85 22.42 0.67 0.01232 0.01931 16 5 1 2 0 2912.290 19.99 22.42 19.73 26.32 26.51 1.7 865.08 -522 -257 -31 -118 193 415 404 408 406 438 268 -107 -142 -261 -289 -314 -184 268 94 -105 27 241 -73 411 412 -56 41 -124 -350 -496 -114 -268 15 366 -92 -66 78 -268 -55 265 108 -62 308 271 112 382 335 232 160 -364 -349 -468 -611 -643 -205 -178 -57 69 -49 -19 386 213 131 268 299 297 -119 85 -259 -253 -170 -238 -156 103 298 -276 -491 -276 -299 97 -479 -369 -307 -133 102 -228 -177 -109 477 -54 108 87 309 9 2 172 -152 -304 -344 8 -454 -214 -110 67 -18 -563 -288 -172 -214 160 -159 176 396 271 474 279 542 477 146 52 189 76 561 67 214 -299 -114 143 310 -34 -41 -481 47 -599 247 328 92 -61 120 87 75 236 524 57 32 -2 -249 -292 -172 -494 -508 -253 -31 -120 197 429 419 425 421 451 274 -109 -143 -261 -290 -318 -188 277 97 -110 28 253 -77 429 431 -58 42 -128 -356 -499 -115 -271 16 377 -96 -69 81 -278 -56 272 111 -64 318 282 116 397 345 237 161 -364 -343 -459 -600 -637 -204 -180 -58 71 -51 -19 394 218 133 273 301 297 -118 84 -255 -247 -165 -233 -154 102 293 -272 -478 -267 -288 93 -464 -357 -300 -130 100 -224 -174 -107 470 -54 107 87 309 9 2 168 -147 -290 -326 7 -430 -205 -107 66 -18 -561 -284 -170 -211 158 -158 176 397 274 478 283 548 481 147 52 187 75 551 66 210 -296 -112 140 304 -34 -40 -464 45 -573 238 318 89 -60 119 86 75 237 524 57 32 -2 -245 -285 -167 -481
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SQ 20250914T073539.4Z 9388.316428 252 1 5.94 2 66.20 114.79 35.90 247.28 0.00 1 0.00 1 0 15 2.307e-03 2.300e-03 7.951e-05 7.944e-05 2.285128e+03 4.967591e+00 1.664714e+02 -6.000000e+00 1.354091e+02 281.29 -2.00 20.00 -2.00 505.28 0.00e+00 4.570758e-04 2.230374e-06 2.855769e-05 -6.000000e+00 6.605204e-05 281.29 -2.00 20.00 -2.00 500.59 0.00e+00 1.288122e-01 1.603834e-03 1.773383e-02 -6.000000e+00 4.706701e-02 228.96 -2.00 3.74 -2.00 502.16 0.00e+00 2.459 0.000 489.00 513.00 1 2.5528e-01 1.2342e-04 3.8288e-03 -6.0000e+00 3.6237e-03 -1.3180e-03 3.1084e-05 4.6092e-04 -6.0000e+00 9.1756e-04 1.0569e+00 4.9152e-04 9.5215e-06 2.0586e-05 -6.0000e+00 2.8522e-04 1.2293e-02 -1.1203e-04 10 0 0 10 0 0 32.72 22.45 0.70 0.01229 0.01570 1244 359 3 2 0 4.630 20.02 22.45 21.87 26.32 26.51 1.7 880.60 -304 -86 83 28 99 360 491 456 323 236 209 30 -176 -152 -198 -262 -125 172 46 -69 48 113 189 364 306 189 258 76 -347 -301 -212 -294 40 298 -34 -261 -150 -40 -132 -100 -33 10 71 198 236 202 144 127 -69 -299 -416 -523 -558 -353 -158 -168 -202 -162 -56 121 310 317 243 241 139 58 53 99 -119 -226 -137 -131 -71 109 6 -293 -341 -177 -221 -244 -227 -302 -347 -108 -76 -211 -200 -83 -40 -67 64 348 316 169 160 139 -44 -206 -306 -364 -444 -352 -34 13 -274 -320 -273 -228 -16 153 79 86 192 240 259 404 477 314 201 186 76 74 267 248 89 175 125 21 211 163 -135 -206 -245 -408 -31 222 53 -41 100 131 163 258 295 249 184 30 -213 -317 -252 -220 -292 -84 83 28 101 374 498 464 328 245 213 30 -176 -151 -197 -263 -128 179 47 -71 50 117 197 378 318 196 264 76 -355 -302 -211 -297 41 302 -35 -272 -155 -41 -134 -101 -33 10 73 205 245 209 147 128 -69 -300 -408 -507 -541 -347 -159 -167 -203 -164 -57 122 315 322 247 244 139 58 53 99 -117 -222 -134 -129 -70 108 6 -290 -333 -171 -213 -235 -220 -295 -343 -108 -76 -206 -195 -81 -39 -66 64 349 318 170 158 136 -44 -199 -292 -345 -426 -344 -33 13 -275 -321 -272 -225 -16 151 80 87 192 241 261 409 482 317 201 183 77 74 266 248 90 175 125 21 209 161 -132 -199 -235 -391 -30 216 52 -41 98 130 163 259 297 251 184 30 -207 -314 -248 -217
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