File name: Pandora105s1_Helsinki_20161104_L2Fit_fwvt1c2d20161104p1-8.txt File generation date: 20251122T203437.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20150702.txt Instrument calibration file used: Pandora105s1_CF_v2d20161104.txt Level 1 file used: Pandora105s1_Helsinki_20161104_L1_smca1c2d20161104p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20161104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0569 492.1776 492.2983 492.4190 492.5397 492.6603 492.7810 492.9016 493.0222 493.1428 493.2633 493.3839 493.5044 493.6249 493.7454 493.8659 493.9864 494.1069 494.2273 494.3477 494.4681 494.5885 494.7088 494.8292 494.9495 495.0698 495.1901 495.3104 495.4307 495.5509 495.6711 495.7914 495.9115 496.0317 496.1519 496.2720 496.3921 496.5122 496.6323 496.7524 496.8725 496.9925 497.1125 497.2325 497.3525 497.4725 497.5924 497.7123 497.8323 497.9522 498.0720 498.1919 498.3117 498.4316 498.5514 498.6712 498.7910 498.9107 499.0305 499.1502 499.2699 499.3896 499.5092 499.6289 499.7485 499.8682 499.9878 500.1073 500.2269 500.3464 500.4660 500.5855 500.7050 500.8245 500.9439 501.0634 501.1828 501.3022 501.4216 501.5410 501.6603 501.7797 501.8990 502.0183 502.1376 502.2568 502.3761 502.4953 502.6145 502.7337 502.8529 502.9721 503.0912 503.2104 503.3295 503.4486 503.5676 503.6867 503.8057 503.9248 504.0438 504.1628 504.2817 504.4007 504.5196 504.6385 504.7574 504.8763 504.9952 505.1140 505.2328 505.3517 505.4705 505.5892 505.7080 505.8267 505.9454 506.0642 506.1828 506.3015 506.4202 506.5388 506.6574 506.7760 506.8946 507.0132 507.1317 507.2502 507.3688 507.4873 507.6057 507.7242 507.8426 507.9611 508.0795 508.1978 508.3162 508.4346 508.5529 508.6712 508.7895 508.9078 509.0261 509.1443 509.2626 509.3808 509.4990 509.6171 509.7353 509.8535 509.9716 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161104T060037.0Z 6152.250428 2 1 32.00 2 89.91 122.76 118.11 79.90 0.00 1 0.00 1 0 15 9.395e-02 8.713e-02 9.087e-02 8.820e-02 6.340432e+03 5.797073e+03 9.898455e+02 -6.000000e+00 4.984023e+03 266.94 -2.00 20.00 -2.00 505.20 0.00e+00 6.536456e-03 2.336069e-03 2.912828e-04 -6.000000e+00 2.565576e-03 266.94 -2.00 20.00 -2.00 499.89 0.00e+00 -7.569898e-01 1.829868e+00 9.179763e-02 -6.000000e+00 1.866899e+00 220.12 -2.00 4.26 -2.00 501.52 0.00e+00 20.682 0.230 489.00 513.00 1 1.0395e+00 1.3929e-01 4.4466e-02 -6.0000e+00 1.4263e-01 2.2997e-01 3.5935e-02 2.4614e-03 -6.0000e+00 3.6675e-02 3.6108e-02 3.2440e-03 7.8498e-03 1.5138e-04 -6.0000e+00 8.9645e-03 2.9226e-02 -3.9014e-05 12 9 8 11 8 0 -293.58 17.38 6.69 0.02923 0.05173 8 2 1 5 0 4000.000 20.35 14.99 17.38 -257 6513 3588 -12661 -3796 4186 16036 3785 1208 -9566 -9495 -1877 4444 3640 6888 588 -2837 7559 11423 -10103 10137 7994 -17446 18949 -3502 11112 -4038 1085 -5590 11587 -939 2799 1053 -10027 15426 -6083 -9142 352 -4451 10999 8189 9559 -2926 -5692 -11229 -3617 -2253 13566 -8801 19138 2362 -917 -3552 32110 -12673 17843 -6874 7346 1225 -7051 2982 -2395 4066 -7690 -8140 -1735 3614 -4158 -3681 1006 4262 -313 2266 3831 2494 -4863 10340 23948 417 6259 -4578 17576 -9351 1289 -4927 -4379 1176 38032 6947 -1856 6349 21210 4025 3804 633 14674 -5968 10525 -1972 -2670 -11871 4136 4957 -7323 4472 -1190 6842 -13422 -8296 9390 2221 -19156 638 10434 -6607 -859 -12165 13387 -5337 -4342 -4588 6875 10930 5602 207 -5286 -2723 5093 -8700 2993 9516 -4209 -1430 -10302 -4182 698 -12313 1268 15949 20613 3599 8698 -2339 -608 4523 -6723 6694 8530 7946 -11802 616 -263 6388 3752 -15921 -4461 4620 16059 4258 1381 -11942 -11624 -2095 4577 3729 6783 618 -3133 7701 11403 -12452 10255 8179 -22874 17654 -4075 11174 -4702 1182 -6313 10642 -962 2781 1094 -11973 14721 -7140 -10928 378 -4967 10488 8077 9415 -3286 -6668 -14046 -4201 -2564 13116 -10369 16769 2360 -926 -3654 23635 -14822 15990 -7983 7502 1317 -8213 3150 -2688 4292 -9038 -9507 -1884 3657 -4452 -3873 1003 4076 -311 2218 3739 2480 -5146 9277 18416 399 5623 -4589 14288 -9825 1233 -5014 -4447 1126 25410 6241 -1805 5728 16904 3840 3645 616 12128 -5863 8600 -1781 -2375 -11374 3441 4221 -7262 4030 -1136 5950 -13975 -8163 7883 2042 -21866 610 9116 -6875 -848 -13452 11598 -5497 -4355 -4520 5979 9069 4928 192 -5193 -2605 4493 -8722 2686 7930 -3949 -1280 -9869 -3760 609 -12359 1127 12459 15477 3191 7335 -2189 -564 3978 -6501 5584 6798 6228 -11121 519 SO 20161104T060241.0Z 6152.251863 4 1 32.00 2 89.70 123.20 117.86 80.35 0.00 1 0.00 1 0 15 7.831e-02 7.533e-02 8.596e-02 8.380e-02 9.080280e+02 4.830719e+03 6.557124e+01 -6.000000e+00 4.157074e+03 266.94 -2.00 20.00 -2.00 505.20 0.00e+00 2.855396e-03 2.220510e-03 2.100175e-04 -6.000000e+00 2.139061e-03 266.94 -2.00 20.00 -2.00 499.84 0.00e+00 3.389590e+00 1.721556e+00 6.048986e-02 -6.000000e+00 1.563595e+00 220.12 -2.00 4.26 -2.00 501.50 0.00e+00 20.369 0.220 489.00 513.00 1 7.8816e-01 1.3115e-01 4.2652e-02 -6.0000e+00 1.1939e-01 1.3814e-01 3.3797e-02 2.4787e-03 -6.0000e+00 3.0836e-02 3.8101e-02 8.0636e-03 7.6456e-03 6.6773e-05 -6.0000e+00 7.5414e-03 5.0504e-02 -4.4648e-04 12 8 8 10 0 0 -957.10 17.40 6.68 0.05050 0.10644 8 2 1 5 0 4000.000 20.35 14.83 17.40 4530 -4272 1108 17645 -1931 16402 -5137 14268 -2864 288 2127 -5480 2677 -8978 5645 -8021 4730 4109 -4315 -6294 -6876 -11442 10500 8141 2703 -454 -5208 7622 3556 2285 1333 16908 -7015 -5886 -15328 5506 3922 16808 3023 5158 3971 14605 6636 -5075 -1142 -3785 -6223 -3499 4241 -2525 -1718 -7580 10816 -3670 7555 -4634 -1509 -13164 -592 -1060 -2663 -11215 7037 12823 -1151 3063 -2057 3408 -4015 2389 -6917 6932 840 19464 2186 -6843 3207 2307 -6322 -2963 2773 11487 25490 -9522 -1240 -3062 5442 5899 4004 1013 4420 -8205 3071 -2328 -6786 -11072 -1313 6258 -2038 8230 -9293 15284 3208 770 -770 1531 6281 -9396 -5828 -955 -12920 18564 -14634 1469 15659 -2144 5250 953 11884 -567 4210 -1609 7078 -6509 2873 11545 13034 -7933 -4244 -2615 -4933 -4194 -4862 14193 -5385 -2556 2833 7978 4105 3310 5546 -16268 -1622 -589 8198 10838 911 3353 4864 -4633 544 4328 -4528 1153 16190 -2186 15884 -6217 14299 -3358 325 2318 -6303 2819 -10416 5676 -9221 4869 4370 -5102 -7643 -8323 -14488 10780 8604 3007 -521 -6239 7983 3739 2352 1363 15024 -8065 -6942 -20178 5940 4247 15795 3223 5352 4179 13937 6879 -5984 -1305 -4443 -7365 -4004 4407 -2735 -1791 -8107 9599 -3805 7206 -5104 -1642 -16044 -639 -1144 -2921 -13357 7053 12092 -1224 3094 -2130 3320 -4125 2267 -7128 6221 809 15881 2116 -7172 2975 2118 -6262 -2805 2504 9559 18655 -9786 -1182 -2988 4874 5241 3614 943 4001 -8482 2902 -2315 -6994 -11713 -1235 5367 -1837 6599 -8731 11443 2767 705 -723 1413 5442 -9288 -5514 -867 -13449 14487 -15924 1386 12908 -2106 4852 913 10201 -538 3753 -1501 6034 -6397 2589 9567 10638 -7910 -4077 -2474 -4753 -3953 -4531 10871 -4964 -2318 2488 6789 3682 3021 4975 -17934 -1563 -565 7222 9247 843 2950 4120 -4288 483 SO 20161104T060440.0Z 6152.253241 6 1 32.00 2 89.49 123.64 117.63 80.79 0.00 1 0.00 1 0 26 7.675e-02 7.338e-02 8.318e-02 8.099e-02 -1.233503e+02 4.606552e+03 3.182026e+02 -6.000000e+00 4.073798e+03 266.94 -2.00 20.00 -2.00 505.18 0.00e+00 -2.877975e-04 2.172611e-03 4.361239e-05 -6.000000e+00 2.095924e-03 266.94 -2.00 20.00 -2.00 499.79 0.00e+00 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