File name: Pandora105s1_Helsinki_20161107_L2Fit_fwvt1c2d20161104p1-8.txt File generation date: 20251122T203657.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v1d20150702.txt Instrument calibration file used: Pandora105s1_CF_v2d20161104.txt Level 1 file used: Pandora105s1_Helsinki_20161107_L1_smca1c2d20161104p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20161107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0569 492.1776 492.2983 492.4190 492.5397 492.6603 492.7810 492.9016 493.0222 493.1428 493.2633 493.3839 493.5044 493.6249 493.7454 493.8659 493.9864 494.1069 494.2273 494.3477 494.4681 494.5885 494.7088 494.8292 494.9495 495.0698 495.1901 495.3104 495.4307 495.5509 495.6711 495.7914 495.9115 496.0317 496.1519 496.2720 496.3921 496.5122 496.6323 496.7524 496.8725 496.9925 497.1125 497.2325 497.3525 497.4725 497.5924 497.7123 497.8323 497.9522 498.0720 498.1919 498.3117 498.4316 498.5514 498.6712 498.7910 498.9107 499.0305 499.1502 499.2699 499.3896 499.5092 499.6289 499.7485 499.8682 499.9878 500.1073 500.2269 500.3464 500.4660 500.5855 500.7050 500.8245 500.9439 501.0634 501.1828 501.3022 501.4216 501.5410 501.6603 501.7797 501.8990 502.0183 502.1376 502.2568 502.3761 502.4953 502.6145 502.7337 502.8529 502.9721 503.0912 503.2104 503.3295 503.4486 503.5676 503.6867 503.8057 503.9248 504.0438 504.1628 504.2817 504.4007 504.5196 504.6385 504.7574 504.8763 504.9952 505.1140 505.2328 505.3517 505.4705 505.5892 505.7080 505.8267 505.9454 506.0642 506.1828 506.3015 506.4202 506.5388 506.6574 506.7760 506.8946 507.0132 507.1317 507.2502 507.3688 507.4873 507.6057 507.7242 507.8426 507.9611 508.0795 508.1978 508.3162 508.4346 508.5529 508.6712 508.7895 508.9078 509.0261 509.1443 509.2626 509.3808 509.4990 509.6171 509.7353 509.8535 509.9716 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20161107T060837.0Z 6155.255984 2 1 32.00 2 89.91 124.85 129.81 43.64 0.00 1 0.00 1 0 72 6.909e-01 3.703e-01 4.801e-01 3.193e-01 1.143315e+04 2.376518e+04 8.052298e+02 -6.000000e+00 3.694824e+04 266.40 -2.00 20.00 -2.00 505.48 0.00e+00 -8.990355e-03 8.921695e-03 3.906062e-04 -6.000000e+00 1.925167e-02 266.40 -2.00 20.00 -2.00 500.60 0.00e+00 5.797928e+00 6.552532e+00 5.311492e-02 -6.000000e+00 1.410721e+01 219.71 -2.00 4.26 -2.00 502.22 0.00e+00 20.698 0.230 489.00 513.00 1 1.9725e+00 4.9327e-01 4.4794e-02 -6.0000e+00 1.0699e+00 -5.6923e-02 1.2382e-01 2.5992e-03 -6.0000e+00 2.8332e-01 8.4111e-03 -4.8271e-03 2.6265e-02 1.7382e-04 -6.0000e+00 6.7150e-02 -9.1421e-02 1.8545e-03 12 9 8 11 8 0 -188.26 17.25 11.31 -0.09142 -0.12490 8 2 1 5 0 4000.000 20.25 15.08 17.25 -8399 24658 -16265 103844 14637 103919 -15159 -5694 -9937 29678 -17566 36379 31365 81007 -27258 -14726 -25843 30883 85882 1068 52148 -5487 900000 16123 43920 -18830 109383 -50465 72855 46481 900000 10397 89295 71197 83160 20818 31187 97699 4981 17337 -22656 17680 -16498 15220 -33619 50926 25146 4401 20811 40521 116083 61402 52692 -36043 27228 -12025 71304 -6744 -8634 30185 213153 -22159 26261 -37527 113686 34487 20576 97640 9528 31328 39656 114010 -17664 900000 15843 72934 -3726 52948 -22544 306391 -17518 22347 -8592 38937 48232 113137 7260 159960 66018 -5428 138424 -37385 28476 11475 163108 -17004 73280 -11784 36459 14479 104112 36091 -23766 57950 56444 8441 17104 82385 -20775 33935 -59396 24466 -31983 22843 18129 282578 4861 70894 15997 73532 85458 100121 21588 16598 20663 -43491 31109 -18998 136177 -21834 900000 63651 119748 6367 54602 8811 65494 20709 6669 26394 -18883 136306 -25263 96968 1417 71087 -23840 900000 14524 900000 900000 -8945 19868 -19910 41736 13959 43409 -19942 -6910 -12425 25453 -23429 28770 25894 41760 -39505 -19449 -39190 28143 47156 1322 39847 -7230 900000 17346 36301 -28080 47990 -99267 42996 34601 900000 11294 47405 46224 48214 21747 29003 47653 5817 17782 -34087 18133 -23563 16161 -56614 37993 23516 4928 19409 30294 41336 36273 33912 -55608 23565 -15464 41394 -8227 -10664 25656 66631 -31226 23147 -60531 42890 27085 18188 41218 9129 24361 28481 40818 -22485 900000 14696 38701 -4002 32693 -28584 95777 -21466 18912 -9906 29132 33367 42559 7444 50003 38886 -6353 43271 -59528 23904 10990 50987 -19996 35402 -12571 24369 12045 38015 26385 -32618 38292 38588 9068 16591 42429 -28615 27920 -119338 22094 -49446 20855 17313 88333 5426 42357 15986 41860 42351 42842 19554 15933 19124 -74203 25958 -25582 42568 -30241 900000 38203 42383 6650 36982 9501 42083 20776 7794 25968 -28977 48546 -42238 50681 1836 46892 -38214 900000 16030 900000 900000 SO 20161107T061040.0Z 6155.257407 4 1 32.00 2 89.70 125.30 129.63 44.21 0.00 1 0.00 1 0 63 3.124e-01 2.362e-01 3.371e-01 2.841e-01 -6.958940e+03 1.647731e+04 4.655163e+02 -6.000000e+00 1.652797e+04 266.40 -2.00 20.00 -2.00 505.29 0.00e+00 9.467293e-03 7.567646e-03 4.183892e-04 -6.000000e+00 8.529717e-03 266.40 -2.00 20.00 -2.00 499.73 0.00e+00 7.243849e+00 5.849486e+00 7.620296e-02 -6.000000e+00 6.240827e+00 219.71 -2.00 4.26 -2.00 501.40 0.00e+00 20.395 0.221 489.00 513.00 1 1.6417e+00 4.4380e-01 4.3705e-02 -6.0000e+00 4.7615e-01 7.3916e-02 1.1265e-01 2.4705e-03 -6.0000e+00 1.2365e-01 1.0375e-02 3.7605e-02 2.6081e-02 8.4520e-05 -6.0000e+00 2.9958e-02 1.2287e-01 -1.1945e-03 12 8 8 10 0 0 73.35 17.27 17.60 0.12287 0.38372 8 2 1 5 0 4000.000 20.25 14.73 17.27 3576 1798 13441 -4269 23114 10200 -12083 -5891 -19200 -8204 -2443 11832 5961 1735 11974 869 16033 -9020 60529 4208 49291 78778 18239 23861 -8820 20377 17403 -8494 16428 -11392 15462 68891 30539 -43210 -21604 -19462 -12298 11941 35045 12954 33370 -19932 -15042 10215 -17088 -6093 3115 40080 5874 57994 31465 8900 38347 -14711 572 33011 -10800 7593 29397 13080 -25087 -1004 -13853 -23238 33511 10252 -145 -26005 43264 7407 61723 14442 52486 -1070 109015 21825 13330 55933 -31873 26053 33632 24639 -20106 13328 4883 94997 3847 -6184 -9368 25475 7639 21358 -30770 17303 4866 -27409 35063 45187 59870 10414 14192 -26771 74120 2078 -5984 22122 75387 -34359 -32798 18591 -9475 19697 52649 8968 24455 17962 5259 12988 -16894 86269 39697 13530 8428 1019 68057 29825 -42538 39523 4901 33239 -3501 2895 -33441 -20831 -3077 -20213 23433 -10753 5791 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20161107T061240.0Z 6155.258796 6 1 32.01 2 89.50 125.73 129.46 44.77 0.00 1 0.00 1 0 43 3.548e-01 2.129e-01 2.925e-01 2.341e-01 3.921793e+04 2.064913e+04 2.009985e+03 -6.000000e+00 1.878766e+04 266.40 -2.00 20.00 -2.00 505.13 0.00e+00 5.481096e-04 6.158457e-03 1.912460e-04 -6.000000e+00 9.700289e-03 266.40 -2.00 20.00 -2.00 499.63 0.00e+00 -6.687241e+00 5.016005e+00 3.057949e-01 -6.000000e+00 7.144313e+00 219.71 -2.00 4.26 -2.00 501.31 0.00e+00 20.036 0.209 489.00 513.00 1 2.5793e+00 3.8000e-01 4.7890e-02 -6.0000e+00 5.4421e-01 3.0673e-01 9.8745e-02 6.8391e-03 -6.0000e+00 1.4284e-01 1.2658e-02 -1.6179e-02 1.6245e-02 1.2181e-04 -6.0000e+00 3.3682e-02 7.7119e-02 -1.2332e-03 12 8 8 10 0 0 -169.59 17.28 6.41 0.07712 -0.03510 8 2 1 5 0 4000.000 20.25 15.26 17.28 900000 -25711 54266 -6568 -5277 21547 -10232 -3278 -4238 31319 -4753 47244 -948 65256 -40966 19657 -3576 29976 -10564 -4850 6841 27026 -5900 -31500 11424 13824 -2723 -8663 3853 4014 42042 9962 5595 4126 -13081 35869 -8918 -5502 1783 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